Skip to main content

Advertisement

Log in

Effect of Cu on the Microstructure, Hardness and Tensile Property of 15 wt.%Mg2Si/Al-La Composites

  • Technical Paper
  • Published:
International Journal of Metalcasting Aims and scope Submit manuscript

Abstract

The effect of different Cu contents (0~5%) on the microstructure and mechanical properties of 15wt.%Mg2Si/Al-La composite was investigated in the present work. The results show that Cu addition had a refining effect on the primary Mg2Si particles. The smallest particle size was acquired when 2% Cu was added. The UTS exhibited a parabolic tendency, which increased from 173 MPa to 227 MP by 31.21% and then decreased with further increasing Cu content. The UTS enhancement could be attributed to the appropriate content of Cu (2%) addition, which led to the formation of Cu-rich phases. When the Cu content was further increased, the UTS of the composite decreased for the coarsening of the Mg2Si particles and the increasing fraction of hard brittle phases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3
Figure 4
Figure 5
Figure 6
Figure 7
Figure 8
Figure 9
Figure 10
Figure 11
Figure 12
Figure 13

Similar content being viewed by others

References

  1. H. Nami, A. Halvaee, H. Adgi, Transient liquid phase diffusion bonding of Al/Mg2Si metal matrix composite. Mater. Des. 32(7), 3957–3965 (2011)

    Article  CAS  Google Scholar 

  2. N.M. Emamy, M. Malekan, M.H. Norouzi, Microstructure and tensile properties of cast Al-15%Mg2Si composite: effects of phosphorous addition and heat treatment. Mater. Sci. Eng., A 556, 446–453 (2012)

    Article  Google Scholar 

  3. N. Soltani, A. Bahrami, M. Pech-Canul, The effect of Ti on mechanical properties of extruded in-situ Al-15pct Mg2Si composite. Metall. Mater. Trans. A. 44(9), 4366–4373 (2013)

    Article  CAS  Google Scholar 

  4. P. Biswas, M.K. Mondal, H. Roy et al., Microstructural evolution and hardness property of in situ Al-Mg2Si composites using one-step gravity casting method. Can. Metall. Q. 56(3), 1–9 (2017)

    Article  Google Scholar 

  5. M.M. Barzani, S. Farahany, V. Songmene, Machinability characteristics, thermal and mechanical properties of Al-Mg2Si in-situ composite with Bismuth. Measurement 110, 263–274 (2017)

    Article  Google Scholar 

  6. M. Azarbarmas, M. Emamy, M. Karamouz et al., The effects of boron additions on the microstructure, hardness and tensile properties of in situ Al-15%Mg2Si composite. Mater. Des. 32(10), 5049–5054 (2011)

    Article  CAS  Google Scholar 

  7. S.E.V. Yeganehl, A. Razaghianl, M. Emamy, The influence of Cu-15P master alloy on the microstructure and tensile properties of Al-25wt% Mg2Si composite before and after hot-extrusion. Mater. Sci. Eng., A 566, 1–7 (2013)

    Article  Google Scholar 

  8. Z. Li, L. Chong, Z. Gao et al., Corrosion behavior of Al-Mg2Si alloys with/without addition of Al-P master alloy. Mater. Charact. 110, 170–174 (2015)

    Article  CAS  Google Scholar 

  9. M. Azarbarmas, M. Emamy, M. Alipour, Study on fracture behaviour of Al-15%Mg2Si metal matrix composite with and without beryllium additions. J. Mater. Sci. 46(21), 6856–6862 (2011)

    Article  CAS  Google Scholar 

  10. M.R. Ghorbani, M. Emamy, R. Khorshidi et al., Effect of Mn addition on the microstructure and tensile properties of Al-15%Mg2Si composite. Mater. Sci. Eng., A 550, 191–198 (2012)

    Article  CAS  Google Scholar 

  11. A. Bahrami, H. Nodooshan, W. Liu et al., Mechanical and tribological characterization of Al-Mg2Si composites after yttrium addition and heat treatment. J. Mater. Eng. Perform. 23(4), 1146–1156 (2014)

    Article  Google Scholar 

  12. Y.Y. Ren, T.Y. Liu, Y.M. Li et al., Effect of La inoculation on composition, content, granularity and mechanical properties of in-situ Al-30wt%Mg2Si composite. Mater. Sci. Eng., A 704, 119–127 (2017)

    Article  CAS  Google Scholar 

  13. X.F. Wu, G.G. Zhang, F.F. Wu, Microstructure and dry sliding wear behavior of cast Al-Mg2Si in-situ metal matrix composite modified by Nd. Rare Met. 3, 74–79 (2013)

    Google Scholar 

  14. L.L. Rokhlin, N.R. Bochvar, N.P. Leonova et al., Effect of additional doping with scandium and scandium with zirconium on strength properties of the alloys of Al-Mg2Si system. Inorg. Mater. 52(15), 1467–1471 (2016)

    Article  CAS  Google Scholar 

  15. M. Azarbarmas, M. Emamy, J. Rassizadehghani et al., The influence of beryllium addition on the microstructure and mechanical properties of Al-15%Mg2Si in-situ metal matrix composite. Mater. Sci. Eng., A 528(28), 8205–8211 (2011)

    Article  CAS  Google Scholar 

  16. R. Khorshidi, A.H. Raouf, R. Mahmudi, Effect of minor Gd addition on the microstructure and creep behavior of a cast Al-15Mg2Si in situ composite. Mater. Sci. Eng., A 718, 9–18 (2018)

    Article  CAS  Google Scholar 

  17. R. Khorshidi, A.H. Raouf, M. Emamy et al., The study of Li effect on the microstructure and tensile properties of cast Al-Mg2Si metal matrix composite. J. Alloy. Compd. 509(37), 9026–9033 (2011)

    Article  CAS  Google Scholar 

  18. M.R. Li, Y.L. Sun, C. Li et al., Effect of Cu addition on precipitation and age-hardening response of an Al-15%Mg2Si alloy. Mater. Charact. 169, 110611 (2020)

    Article  CAS  Google Scholar 

  19. J.K. Sunde, C.D. Marioara, R. Holmestad, The effect of low Cu additions on precipitate crystal structures in overaged Al-Mg-Si(-Cu) alloys. Mater. Charact. 160, 110087 (2020)

    Article  CAS  Google Scholar 

  20. W. Feng, M. Jian, C.F. Liu et al., Effect of trace elements La, Ti and homogenization on electrical properties of Pure Aluminum. Rare Metal Mater. Eng. 47(11), 3257–3263 (2018)

    Article  Google Scholar 

  21. J. Zhang, Z. Fan, Y.Q. Wang et al., Equilibrium pseudobinary Al-Mg2Si phase diagram. Mater. Sci. Technol. 17(5), 494–496 (2001)

    Article  CAS  Google Scholar 

  22. M. Emamy, S.E. Vaziri Yeganeh, A. Razaghian et al., Microstructures and tensile properties of hot-extruded Al matrix composites containing different amounts of Mg2Si. Mater. Sci. Eng., A 586, 190–196 (2013)

    Article  CAS  Google Scholar 

  23. G.S. Mousavi, M. Emamy, J. Rassizadehghani, The effect of mischmetal and heat treatment on the microstructure and tensile properties of A357 Al-Si casting alloy. Mater. Sci. Eng., A 556, 573–581 (2012)

    Article  CAS  Google Scholar 

  24. B. Pourbahari, M. Emamy, Effects of La intermetallics on the structure and tensile properties of thin section gravity die-cast A357 Al alloy. Mater. Des. 94, 111–120 (2016)

    Article  CAS  Google Scholar 

  25. M.A. Liping, E.J. Guo, B.X. Ma, Modification effect of lanthanum on primary phase Mg2Si in Mg-Si alloys. J. Rare Earths 26(1), 105–109 (2008)

    Article  Google Scholar 

  26. J.G. Li, Y.W. Liu, G.F. Jiang, X.R. Zhang, Vapour-to-liquid nucleation in cone pores. Mol. Simul. 4(1), 1–8 (2016)

    Article  CAS  Google Scholar 

  27. Q.J. Zheng, J. Wu, H.X. Jiang, L.L. Zhang, J.Z. Zhao, J. He, Effect of micro-alloying element La on corrosion behavior of Al-Mg-Si alloys. Corros. Sci. 179, 109113 (2021). https://doi.org/10.1016/j.corsci.2020.109113

    Article  CAS  Google Scholar 

  28. V. Deev, E. Prusov, P. Shurkin et al., Effect of La addition on solidification behavior and phase composition of cast Al-Mg-Si alloy. Metals-Open Access Metall. J. 10(12), 1673 (2020)

    CAS  Google Scholar 

  29. H.C. Yu, Crystallization of primary Mg2Si in Al-20Mg2Si alloy with various molar ratios of Ca/Sb. J. Alloy. Compd. 787, 872–881 (2019)

    Article  CAS  Google Scholar 

  30. P. Xiao, Y.M. Gao, P. Mao et al., Revealing modification mechanism of Mg2Si in Sb modified Mg2Si/AZ91 composites and its effect on mechanical properties AZ91 composites and its effect on mechanical properties. J. Alloy. Compd. 850, 156877 (2021)

    Article  CAS  Google Scholar 

  31. A.M. Samuel, E.M. Elgallad, M.G. Mahmoud et al., Rare earth metal-based intermetallics formation in Al-Cu-Mg and Al-Si-Cu-Mg alloys: a metallographic study. Adv. Mater. Sci. Eng. 2018, 1–15 (2018)

    Google Scholar 

  32. M. Emamy, N. Nemati, A. Heidarzadeh, The influence of Cu rich intermetallic phases on the microstructure, hardness and tensile properties of Al-15%Mg2Si composite. Mater. Sci. Eng., A 527(12), 2998–3004 (2010)

    Article  Google Scholar 

  33. S. Farahany, H. Ghandvar, M. Bozorg et al., Role of Sr on microstructure, mechanical properties, wear and corrosion behaviour of an Al-Mg2Si-Cu in-situ composite. Mater. Chem. Phys. 239, 121954 (2019)

    Article  Google Scholar 

  34. M. Emamy, A.R. Emami, K. Tavighi, The effect of Cu addition and solution heat treatment on the microstructure, hardness and tensile properties of Al-15%Mg2Si-0.15%Li composite. Mater. Sci. Eng. A 576, 36–44 (2013)

    Article  CAS  Google Scholar 

  35. A.H. Shafieizad, A. Zarei-Hanzakia, H.R. Abedi et al., The Mg2Si phase evolution during thermomechanical processing of in-situ aluminum matrix macro-composite. Mater. Sci. Eng., A 644, 310–317 (2015)

    Article  CAS  Google Scholar 

  36. Y. Zheng, W.L. Xiao, S.J. Ge et al., Effects of Cu content and Cu/Mg ratio on the microstructure and mechanical properties of Al-Si-Cu-Mg alloys. J. Alloy. Compd. 649, 291–296 (2015)

    Article  CAS  Google Scholar 

  37. Q.J. Zheng, L.L. Zhang, H.X. Jiang et al., Effect mechanisms of micro-alloying element La on microstructure and mechanical properties of hypoeutectic Al-Si alloys. J. Mater. Sci. Technol. 47, 142–151 (2020)

    Article  CAS  Google Scholar 

  38. M. Emamy, K. Tavighi, B. Pourbahari et al., Improvement in tensile and wear properties of as-cast Al-15%Mg2Si composite modified by Zn and Ni. Int. J. Metalcast. 11(4), 790–801 (2017)

    Article  Google Scholar 

  39. S.Q. Zhang, T.J. Chen, F.L. Cheng et al., Effects of mould temperature on microstructure and tensile properties of thixoforged Mg2Sip/AM60B in-situ composites. J. Alloy. Compd. 657, 582–592 (2016)

    Article  CAS  Google Scholar 

  40. D.F. Xu, K.H. Chen, Y.Q. Chen et al., Evolution of the second-phase particles and their effect on tensile fracture behavior of 2219 Al-xCu alloys. Metals-Open Access Metall. J. 10(2), 197 (2020)

    CAS  Google Scholar 

  41. K.S. Hu, C.M. Zou, H.W. Wang et al., Influence of Ti elements on the evolution of microstructure, mechanical properties and thermal stability of Al-Cu alloy. J. Alloy. Compd. 952, 169860 (2023)

    Article  CAS  Google Scholar 

  42. M.Q. Gao, H.J. Kang, Z.N. Chen et al., Effect of reinforcement content and aging treatment on microstructure and mechanical behavior of B4Cp/6061Al composites. Mater. Sci. Eng., A 744, 682–690 (2018)

    Article  Google Scholar 

  43. X.F. Wu, Z.C. Wang, K.Y. Wang et al., Microstructural refinement and tensile properties enhancement of Al-10Mg2Si cast alloys by copper addition. J. Alloy. Compd. 896, 163058 (2022)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Thanks to the financial supports from the Scientific Research Fund project of Liaoning Education Department in 2021 (No. LJKZ0121), Research capacity cultivation Fund of Shenyang University of Technology (No. 200005742) and Enterprise Cooperation Projects (No. 2021-0-43-188).

Funding

This work was supported by Scientific Research Fund project of Liaoning Education Department in 2021 (No. LJKZ0121), Research capacity cultivation Fund of Shenyang University of Technology (No. 200005742) and Enterprise Cooperation Projects (No. 2021-0-43-188).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Xue Zou or Chao Yang.

Ethics declarations

Conflict of interest

The authors declare no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liu, T., Zou, X., Yang, C. et al. Effect of Cu on the Microstructure, Hardness and Tensile Property of 15 wt.%Mg2Si/Al-La Composites. Inter Metalcast 18, 1496–1507 (2024). https://doi.org/10.1007/s40962-023-01094-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40962-023-01094-7

Keywords

Navigation