Abstract
The present research study aims at studying the influence of the additions of Ce and La elements (0.2–1.0%) on room temperature tensile properties of Al–1.2Si–2.4Cu and Al–8.0Si–2.4Cu-alloys, with relatively low and high Si, respectively. The results showed that T6-treated alloys, Sr-modified alloys or those containing Ce/La exhibited UTS values comparable to the solution heat-treated, T5 and T7-treated alloys. The influence of 0.2 wt% RE (Ce/La) on tensile properties is similar to that caused by adding 150 ppm Sr. The strengthening behavior of addition of 0.2%RE is attributed to the size and distribution of RE intermetallics coupled with their low volume fraction. Under these conditions, the alloys act as composite materials. Stabilization at 250 °C for 200 h produces a marked decrease in the alloy strength, with an increase in ductility values. Additions of 0.2 wt% Ce or La marginally improved the strength of the B0 and D0 alloys (10–15 MPa) following 1 h of stabilization at 250 °C. The fracture surfaces were examined using scanning electron microscopy, whereas the longitudinal sections beneath the fractures surfaces were examined using optical microscopy.
Similar content being viewed by others
References
A. Knuutinen, K. Nogita, S. McDonald, A. Dahle, Modification of Al–Si alloys with Ba, Ca, Y and Yb. J. Light Met. 1, 229–240 (2001)
K. Nogita, A. Knuutinen, S. McDonald, A. Dahle, Mechanisms of eutectic solidification in Al–Si alloys modified with Ba, Ca, Y and Yb. J. Light Met. 1, 219–228 (2001)
F.H. Spedding, A.H. Daane (eds.), The Rare Earths (Wiley, Hoboken, 1961)
M.F. Ibrahim, M.H. Abdelaziz, A.M. Samuel, H.W. Doty, F.H. Samuel, Effect of rare earth metals on the mechanical properties and fractography of Al–Si-based alloys. Int. J. Metalcast. (2019). https://doi.org/10.1007/s40962-019-00336-x
M. Li, H. Wang, Z. Wei, Z. Zhu, The effect of Y on the hot-tearing resistance of Al–5wt.% Cu based alloy. Mater. Des. 31, 2483–2487 (2010)
B. Li, H. Wang, J. Jie, Z. Wei, Effects of yttrium and heat treatment on the microstructure and tensile properties of Al–7.5 Si–0.5 Mg alloy. Mater. Des. 32, 1617–1622 (2011)
J.H. Li, P. Schumacher, Effect of Y addition and cooling rate on refinement of eutectic Si in Al–5 wt%Si alloys. Int. J. Cast Met. Res. 25, 347–357 (2012)
B. Wan, W. Chen, L. Liu, X. Cao, L. Zhou, Z. Fu, Effect of trace yttrium addition on the microstructure and tensile properties of recycled Al–7Si–0.3 Mg–1.0Fe casting alloys. Mater. Sci. Eng. A 666, 165–175 (2016)
M.O. Shabani, A. Mazahery, Automotive copper and magnesium containing cast aluminium alloys: report on the correlation between Yttrium modified microstructure and mechanical properties. Russ. J. Non Ferrous Met. 55, 436–442 (2014)
M. Sheng, Z. Tao, P. Jia, J. Leng, H. Geng, Effects of Y and Y combined with Al–5Ti-1B on the microstructure and mechanical properties of hypoeutectic Al–Si alloy. JOM 67, 330–335 (2015)
K. Nogita, H. Yasuda, M. Yoshiya, S.D. McDonald, K. Uesugid, A. Takeuchi, Y. Suzuki, The role of trace element segregation in the eutectic modification of hypoeutectic Al–Si alloys. J. Alloys Compd. 489, 415–420 (2010)
Z.R. Nie, T. Jin, J. Fu, G. Xu, J. Yang, J.X. Zhou, T.Y. Zuo, Research on rare earth in aluminum. Mater. Sci. Forum 396–402, 1731 (2002)
Z. Nie, J. Fu, J. Zou, T. Jin, J. Yang, G. Xu, H. Ruan, T. Zuo, Advanced aluminum alloys containing rare-earth erbium. Mater. Forum 28, 197–201 (2004)
G.F. Xu, S.Z. Mou, J.J. Yang, T.N. Jin, Z.R. Nie, Z.M. Yin, Effect of trace rare earth element Er on Al–Zn-Mg alloy. Trans. Nonferrous Met. Soc. China 16, 598–603 (2006)
Y.T. Li, Z.Y. Liu, Y.B. Liu, P. Dang, Q.K. Xia, R.C. Yu, Alloying behavior of rare-earth Er in Al–Cu–Mg–Ag alloy. Mater. Sci. Forum 546–549, 941–946 (2007)
S.P. Wen, Z.B. Xing, H. Huang, B.L. Li, W. Wang, Z.R. Nie, The effect of erbium on the microstructure and mechanical properties of Al–Mg–Mn–Zr alloy. Mater. Sci. Eng. A 516, 42–49 (2009)
X. Pengfei, G. Bo, Y. Zhuang, L. Kaihua, T. Ganfeng, Effect of erbium on properties and microstructure of Al–Si eutectic alloy. J. Rare Earths 28, 927–930 (2010)
C. Booth-Morrison, D.N. Seidman, D.C. Dunand, Effect of Er additions on ambient and high-temperature strength of precipitation-strengthened Al–Zr–Sc–Si alloys. Acta Mater. 60, 3643–3654 (2012)
X.W. Hu, F.G. Jiang, F.R. Ai, H. Yan, Effects of rare earth Er additions on microstructure development and mechanical properties of die-cast ADC12 aluminum alloy. J. Alloys Compd. 538, 21–27 (2012)
X.D. Wang, S.P. Lin, J.J. Yang, Z.L. Tang, Z.R. Nie, Microstructure and mechanical properties of Al–Mg–Mn alloy with erbium. Rare Met. 31, 237–243 (2012)
Z.M. Shi, Q. Wang, G. Zhao, R.Y. Zhang, Effects of erbium modification on the microstructure and mechanical properties of A356 aluminum alloys. Mater. Sci. Eng. A 626, 102–107 (2015)
M. Colombo, E. Gariboldi, A. Morri, Er addition to Al–Si–Mg-based casting alloy: effects on microstructure, room temperature mechanical properties. J. Alloys Compd. 708, 1234–1244 (2017)
M. Colombo, E. Gariboldi, A. Morri, Influences of different Zr additions on the microstructure, room temperature mechanical properties of an Al–7Si–0.4 Mg alloy modified with 02.5% Er. Mater. Sci. Eng. A 713, 151–160 (2017)
Q.L. Li, B.Q. Li, J.B. Li, C.F. Zhang, Y.F. Lan, Effect of rare earth Er on microstructure and mechanical properties of cast Al–Si–Mg alloy. Mater. Sci. Forum 893, 202–206 (2017)
C. Xu, H. Wang, Y. Yang, Q. Jiang, Effect of Al–P–Ti–TiC–Nd2O3 modifier on the microstructure and mechanical properties of hypereutectic Al–20wt.% Si alloy. Mater. Sci. Eng. A 452, 341–346 (2007)
W.X. Shi, B. Gao, G.F. Tu, S.W. Li, Effect of Nd on microstructure and wear resistance of hypereutectic Al–20%Si alloy. J. Alloys Compd. 508, 480–485 (2010)
S. Weixi, G. Bo, T. Ganfeng, L. Shiwei, H. Yi, Y. Fuxiao, Effect of neodymium on primary silicon and mechanical properties of hypereutectic Al–15% Si alloy. J. Rare Earths 28, 367–370 (2010)
X. Ren, L. Peng, G. Huang, R. Zong, H. Xie, J. Li, Effect of Nd on microstructure and properties of 2A70 alloy. J. Alloys Compd. 731, 1014–1021 (2018)
R. Ahmad, M. Asmael, M. Amzar, Effect of ytterbium addition on microstructure and hardness of Al–6.5Si–1Zn secondary cast alloy. J. Eng. Appl. Sci. 11(16), 10123–10127 (2006)
X.M. Zhang, W.T. Wang, M.A. Chen, Y.Z. Jia, L.Y. Ye, D.W. Zheng, L. Liu, X.Y. Kuang, Effects of Yb addition on microstructures and mechanical properties of 2519A aluminum alloy plate. Trans. Nonferrous Met. Soc. China 20, 727–731 (2010)
B. Li, H.W. Wang, J.C. Jie, Z.J. Wei, Microstructure evolution and modification mechanism of the ytterbium modified Al–7.5%Si–0.45%Mg alloys. J. Alloys Compd. 509, 3387–3392 (2011)
J.H. Li, S. Suetsugu, Y. Tsunekawa, P. Schumacher, Refinement of eutectic Si phase in Al–5Si alloys with Yb additions. Metall. Mater. Trans. A 44, 669–681 (2013)
J. Xiong, H. Yan, S. Zhong, M. Bi, Effects of Yb addition on the microstructure and mechanical properties of as-cast ADC12 alloy. Metals 9, 108 (2019)
Q. Li, J. Li, B. Li, Y. Zhu, D. Liu, Y. Lan, S. Wang, Mechanical properties and microstructural evolution of Yb-modified Al–20%. J. Mater. Eng. Perform. 27, 3498–3507 (2018)
Z.W. Chen, P. Chen, C.Y. Ma, Microstructures and mechanical properties of Al–Cu-Mn alloy with La and Sm addition. Rare Met. 31, 332–335 (2012)
H. Qiu, H. Yan, Z. Hu, Effect of samarium (Sm) addition on the microstructures and mechanical properties of Al–7Si–0.7 Mg alloys. J. Alloys Compd. 567, 77–81 (2013)
R. Yuansheng, Y. Hong, H. Zhi, Modification of eutectic silicon and β-Al5FeSi phases in as-cast ADC12 alloys by using samarium addition. J. Rare Earths 31, 916–922 (2013)
H. Zhi, Y. Hong, Y.S. Rao, Effects of samarium addition on microstructure and mechanical properties of as-cast Al–Si–Cu alloy. Trans. Nonferrous Met. Soc. China 23, 3228–3234 (2013)
H.X. Qiu, H. Yan, Z. Hu, Modification of near-eutectic Al–Si alloys with rare earth element samarium. J. Mater. Res. 29, 1270–1277 (2014)
Q. Li, J. Li, B. Li, Y. Lan, T. Xia, Effect of samarium (Sm) addition on the microstructure and tensile properties of Al–20% Si casting alloy. Int. J. Metalcast. 12(3), 554–564 (2018)
V.V. Zakharov, T.D. Rostova, Effect of scandium, transition metals, and admixtures on strengthening of aluminum alloys due to decomposition of the solid solution. Met. Sci. Heat Treat. 49, 435–442 (2007)
M.S. Kaiser, S. Datta, A. Roychowdhury, M.K. Banerjee, Effect of scandium on the microstructure and ageing behaviour of cast Al–6 Mg alloy. Mater. Charact. 59, 1661–1666 (2008)
W. Prukkanon, N. Srisukhumbowornchai, C. Limmaneevichitr, Influence of Sc modification on the fluidity of an A356 aluminum alloy. J. Alloys Compd. 487, 453–457 (2009)
D. Emadi, A.K.P. Rao, M. Mahfoud, Influence of scandium on the microstructure and mechanical properties of A319 alloy. Mater. Sci. Eng. A 527, 6123–6132 (2010)
W. Zhang, Y. Liu, J. Yang, J. Dang, H. Xu, Z. Du, Effects of Sc content on the microstructure of as-cast Al–7wt.% Si alloys. Mater. Charact. 66, 104–110 (2012)
J.H. Li, X.D. Wang, T.H. Ludwig, Y. Tsunekawa, L. Arnberg, J.Z. Jiang, P. Schumacher, Modification of eutectic Si in Al–Si alloys with Eu addition. Acta Mater. 84, 153–163 (2015)
F. Mao, G.Y. Yan, J.Q. Li, T.M. Wang, Z.Q. Cao, The interaction between Eu and P in high purity Al–7Si alloys. Mater. Charact. 120, 129–142 (2016)
F. Mao, G. Yan, Z. Xuan, Z. Cao, T. Wang, Effect of Eu addition on the microstructures and mechanical properties of A356 aluminum alloys. J. Alloys Compd. 650, 896–906 (2015)
W.Y. Liu, W.L. Xiao, C. Xu, M.W. Liu, C.L. Ma, Synergistic effects of Gd and Zr on grain refinement and eutectic Si modification of Al–Si cast alloy. Mater. Sci. Eng. A 693, 93–100 (2017)
S.A. Alkahtani, E.M. Elgallad, M.M. Tash, A.M. Samuel, F.H. Samuel, Effect of rare earth metals on the microstructure of Al–Si based alloys. Materials 9(1), 45 (2016). https://doi.org/10.3390/ma9010045.
R. Ahmad, M.B.A. Asmael, Influence of cerium on microstructure and solidification of eutectic Al–Si piston alloy. Mater. Manuf. Process. 31, 1948–1957 (2015)
T. Lu, Y. Pan, J.L. Wu, S.W. Tao, Y. Chen, Effects of La addition on the microstructure and tensile properties of Al–Si–Cu–Mg casting alloys. Int. J. Min. Metall. Mater. 22, 405–410 (2015)
C. Qiu, S. Miao, X. Li, X. Xia, J. Ding, Y. Wang, W. Zhao, Synergistic effect of Sr and La on the microstructure and mechanical properties of A356.2 alloy. Mater. Des. 114, 563–571 (2016)
E.M. Elgallad, Effect of additives on the mechanical properties and machinability of a new aluminum-copper base alloy. PhD Thesis, Université du Québec à Chicoutimi, 2010
L. Alyaldin, Effects of alloying elements on room and tensile properties of Al–Si–Cu–Mg base alloys. Master Thesis, Université du Québec à Chicoutimi, 2017
Z. Ma, A.M. Samuel, H.W. Doty, F.H. Samuel, On the Fractography of Impact-Tested Samples of Al–Si Alloys for Automotive Alloys. Fracture Mechanics—Properties, Patterns and Behaviours (InTech, Rijeka, 2016)
G. Zhang, J. Zhang, B. Li, W. Cai, Double-stage hardening behavior and fracture characteristics of a heavily alloyed Al–Si piston alloy during low-cycle fatigue loading. Mater. Sci. Eng. A 561, 26–33 (2013)
G.F. Van der Voort, Visual examination and light microscopy. ASM Handb. 12, 91–165 (1987)
G.S. Mousavi, M. Emamy, J. Rassizadehghani, The effect of mischmetal and heat treatment on the microstructure and tensile properties of A357 Al–Si casting alloy. Mater. Sci. Eng. A 556, 573–581 (2012)
M. Zhu, Z.Y. Jian, L.J. Yao, C.X. Liu, G.C. Yang, Y.H. Zhou, Effect of mischmetal modification treatment on the microstructure, tensile properties and fracture behavior of Al–7.0%Si–0.3%Mg foundry aluminum alloys. J. Mater. Sci. 46, 2685–2694 (2011)
M. Zhu, Z.Y. Jian, G.C. Yang, Y.H. Zhou, Effects of T6 heat treatment on the microstructure, tensile properties, and fracture behavior of the modified A356 alloys. Mater. Des. 36, 243–249 (2012)
B. Dang, Z.Y. Jian, J.F. Xu, Effects of rare-earth element addition and heat treatment on the microstructures and mechanical properties of Al–25% Si alloy. Int. J. Mater. Res. 108, 269–274 (2017)
Acknowledgements
The authors would like to thank Amal Samuel for enhancing the quality of the artwork used in the present article.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Mahmoud, M.G., Samuel, A.M., Doty, H.W. et al. Role of Heat Treatment on the Tensile Properties and Fractography of Al–1.2Si–2.4Cu and Al–8.0Si–2.4Cu Cast Alloys Modified with Ce, La and Sr Addition. Inter Metalcast 14, 218–242 (2020). https://doi.org/10.1007/s40962-019-00350-z
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40962-019-00350-z