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Effect of Rare Earth Metals on the Mechanical Properties and Fractography of Al–Si-Based Alloys

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Abstract

The present study was performed on A356 and A413 alloys in non-modified and Sr-modified conditions. To these alloys, pure rare earth (RE) metals, mainly lanthanum (La) and cerium (Ce), were added in the amount of 1 wt% each, individually or combined. The results showed that the addition of 2% RE leads to a significant reduction in the grain size (~ 60%) compared to the base alloy. However, it also leads to precipitation of a large amount of insoluble intermetallics (~ 10% in volume fraction). These intermetallics cause a significant decrease in the alloy ductility and hence deteriorate the tensile properties and impact energies. In addition, Sr may also cause destabilization of the RE intermetallics with possibility of partial dissolution during solution heat treatment. The RE metals have an affinity to react with Sr leading to partial demodification of the eutectic Si. They also react with Cu, diminishing the alloy response to age hardening. The RE intermetallics act as crack initiation sites, leading to premature failure of the sample. The combined occurrence of these various effects complicates the prediction of the alloy behavior.

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References

  1. A.I. Ibrahim, E.M. Elgallad, A.M. Samuel, H.W. Doty, F.H. Samuel, Effects of heat treatment and testing temperature on the tensile properties of Al–Cu and Al–Cu–Si based alloys. Int. J. Mater. Res. 109, 314–331 (2018)

    Article  CAS  Google Scholar 

  2. A.M. Samuel, S.S. Mohamed, H.W. Doty, S. Valtierra, F.H. Samuel, Effect of melt temperature on the effectiveness of the grain refining in Al–Si castings. Adv. Mater. Sci. Eng. 2018, 7626219 (2018). https://doi.org/10.1155/2018/7626219

    Article  CAS  Google Scholar 

  3. G.H. Garza-Elizondo, A.M. Samuel, S. Valtierra, F.H. Samuel, Effect of Ni, Mn, Sc, and Zr addition on the tensile properties of 354-type alloys at ambient temperature. Int. J. Metalcast. 11, 396–412 (2017)

    Article  CAS  Google Scholar 

  4. M.H. Abdelaziz, M. Paradis, A.M. Samuel, H.W. Doty, F.H. Samuel, Effect of aluminum addition on the microstructure, tensile properties, and fractography of cast Mg-based alloys. Adv. Mater. Sci. Eng. 2017, 10p (2017)

    Article  Google Scholar 

  5. H. Ye, An overview of the development of Al–Si alloy based material for engine applications. J. Mater. Eng. A. 12, 288–297 (2003)

    CAS  Google Scholar 

  6. F.H. Samuel, A.M. Samuel, H.W. Doty, Factors controlling the type and morphology of Cu-containing phases in 319 Al alloy. AFS Trans. 104, 893–901 (1996)

    CAS  Google Scholar 

  7. R.A. Colás, J. Rodríguez, J. Talamantes, S. Valtierra, Solidification analysis of aluminium engine block. Int. J. Cast Metals Res. 17, 332–338 (2004)

    Article  Google Scholar 

  8. X.P. Niu, B.H. Hu, S.W. Hao, Effect of iron on the microstructure and mechanical properties of Al die-casting alloys. J. Mater. Sci. Lett. 17, 1727–1729 (1998)

    Article  CAS  Google Scholar 

  9. O. Elsebaie, A.M. Samuel, F.H. Samuel, H.W. Doty, The effects of mischmetal, cooling rate and heat treatment on the eutectic Si particle characteristics of A319.1, A356.2 and A413.1 Al–Si casting alloys. Mater. Sci. Eng., A 480, 342–355 (2008)

    Article  Google Scholar 

  10. O. Elsebaie, A.M. Samuel, F.H. Samuel, H.W. Doty, The effects of mischmetal, cooling rate and heat treatment on the hardness of A319.1, A356.2 and A413.1 Al–Si casting alloys. Mater. Sci. Eng., A 486, 241–252 (2008)

    Article  Google Scholar 

  11. G.S. Mousavi, M. Emamyn, J. Rassizadehghani, The effect of mischmetal and heat treatment on the microstructure and tensile properties of A357 Al–Si casting alloy. Mater. Sci. Eng., A 556, 573–581 (2012)

    Article  CAS  Google Scholar 

  12. R.S. Rana, R. Purohit, S. Das, Reviews on the influence of alloying elements on the microstructure and mechanical properties of aluminium alloys and aluminium alloy composites. Int. J. Sci. Res. Publ. 2, 01–07 (2012)

    Google Scholar 

  13. M.G. Mahmoud, E.M. Elgallad, M.F. Ibrahim, F.H. Samuel, Effect of rare earth metals on porosity formation in A356 alloy. Int. J. Metalcast. 12, 251–265 (2018)

    Article  CAS  Google Scholar 

  14. A.M. Samuel, H.W. Doty, S. Valtierra, F.H. Samuel, Intermetallic precipitation in rare earth-treated A413.1 alloy: a metallographic study. Int. J. Mater. Res. 109, 157–171 (2018)

    Article  CAS  Google Scholar 

  15. Z.Y. Ouyang, X.M. Mao, M. Hong, Multiplex modification with rare earth elements and P for hypereutectic Al–Si alloys. J. Shanghai Univ. Engl. Ed. 11, 400–402 (2007)

    Article  CAS  Google Scholar 

  16. H. Zhang, H. Duan, G. Shao, L. Xu, J. Yin, B. Yan, Modification mechanism of cerium on the Al–18Si alloy. Rare Met. 25, 11–15 (2006)

    Article  Google Scholar 

  17. X. Ao, S. Xing, B. Yu, Q. Han, Effect of Ce addition on microstructures and mechanical properties of A380 aluminum alloy prepared by squeeze-casting. Int. J. Miner. Metall. Mater. 25, 554–562 (2018)

    Article  Google Scholar 

  18. X. Song, H. Yan, X. Zhang, Microstructure and mechanical properties of Al–7Si–0.7 Mg alloy formed with an addition of (Pr + Ce). J. Rare Earths 35, 412–418 (2017)

    Article  CAS  Google Scholar 

  19. Y. Tsai, C. Chou, R. Jeng, S. Lee, C. Lin, Effect of rare earth elements addition on microstructures and mechanical properties of A356 alloy. Int. J. Cast Met. Res. 24, 83–87 (2011)

    Article  CAS  Google Scholar 

  20. M. Drouzy, S. Jacob, M. Richard, Interpretation of tensile results by means of quality index and probable yield strength. AFS Int. Cast Metals J. 5, 43–50 (1980)

    CAS  Google Scholar 

  21. S. Jacob, Quality index in predicting of properties of aluminum castings—a review. AFS Trans. 108, 811–818 (2000)

    CAS  Google Scholar 

  22. A.M. Nabawy, A.M. Samuel, S.A. Alkahtani, K.A. Abuhasel, F.H. Samuel, Role of cerium, lanthanum, and strontium additions in an Al–Si–Mg (A356) alloy. Int. J. Mater. Res. 107(5), 446–458 (2016)

    Article  CAS  Google Scholar 

  23. M.G. Mahmoud, A.M. Samuel, H.W. Doty, S. Valtierra, F.H. Samuel, Effect of rare earth metals, Sr, and Ti addition on the microstructural characterization of A413.1 alloy. Adv. Mater. Sci. Eng. 2017, 4712946 (2017). https://doi.org/10.1155/2017/4712946

    Article  CAS  Google Scholar 

  24. L.A. Narayanan, F.H. Samuel, J.E. Gruzleski, Dissolution of iron intermetallics in Al–Si alloys through nonequilibrium heat treatment. Metall. Mater. Trans. A 26(8), 2161–2174 (1995)

    Article  Google Scholar 

  25. A.M. Samuel, F.H. Samuel, Modification of iron intermetallics by magnesium and strontium in Al–Si alloys. Int. J. Cast Met. Res. 10(3), 147–157 (1997)

    Article  CAS  Google Scholar 

  26. E.M. Elgallad, M.F. Ibrahim, H.W. Doty, F.H. Samuel, Microstructural characterisation of Al–Si cast alloys containing rare earth additions. Phil. Mag. 98, 1337–1359 (2018)

    Article  CAS  Google Scholar 

  27. K.A. Abuhasel, M.F. Ibrahim, E.M. Elgallad, F.H. Samuel, On the impact toughness of Al–Si cast alloys. Mater. Des. 91, 388–397 (2016)

    Article  CAS  Google Scholar 

  28. S.A. Alkahtani, E.M. Elgallad, M.M. Tash, A.M. Samuel, F.H. Samuel, Effect of rare earth metals on the microstructure of Al-Si based alloys. Materials 9(1), 45 (2016). https://doi.org/10.3390/ma9010045

    Article  CAS  Google Scholar 

  29. K. Bisaka, I.C. Thobadi, C. Pawlik, Extraction of rare earths from iron-rich rare earth deposits. J. S. Afr. Inst. Min. Metall. 117, 731–739 (2017)

    Article  CAS  Google Scholar 

  30. A.M. Samuel, H.W. Doty, S. Valtierra, F.H. Samuel, Influence of oxides on porosity formation in Sr-treated alloys. Int. J. Metalcast. 11, 729–742 (2017)

    Article  CAS  Google Scholar 

  31. F. Paray, J.E. Gruzleski, Microstructure-mechanical property relationship in a 356 alloy. Part 1: microstructure. Cast Metals 7(1), 29–40 (1994)

    Article  CAS  Google Scholar 

  32. S. Hotta, K. Saruki, M. Nakamura, Effects of T6 heat treatment on the impact strength of AC4C and AC2B aluminum alloy castings solidified for a long time. J. Jpn. Inst. Light Metals 37, 478–482 (1987)

    Article  CAS  Google Scholar 

  33. K.G. Basavakumar, P.G. Mukunda, M. Chakraborty, Influence of grain refinement and modification on microstructure and mechanical properties of Al7Si and Al–7Si–2.5Cu cast alloys. Mater. Charact. 59, 283–289 (2008)

    Article  CAS  Google Scholar 

  34. K.G. Basavakumar, P.G. Mukunda, M. Chakraborty, Impact toughness in Al–12Si and Al–12Si–3Cu cast alloys—part 1: effect of process variables and microstructure. Int. J. Impact Eng 35, 199–205 (2008)

    Article  Google Scholar 

  35. K.G. Basavakumar, P.G. Mukunda, M. Chakraborty, Effect of melt treatment on microstructure and impact properties of Al–7Si and Al–7Si–2.5Cu cast alloys. Bull. Mater. Sci. 30, 439–445 (2007)

    Article  CAS  Google Scholar 

  36. O. Elsebaie, A.M. Samuel, H.W. Doty, S. Valtierra, F.H. Samuel, On the impact properties and fractography of Al–11%Si casting alloy. Int. J. Metalcast. 12, 36–54 (2018)

    Article  CAS  Google Scholar 

  37. F.J. Tavitas-Medrano, H.W. Doty, S. Valtierra, F.H. Samuel, On the enhancement of the impact toughness of A319 alloys: role of Mg content and melt treatment. Int. J. Metalcast. 11, 536–551 (2017)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors would like to thank Amal Samuel for enhancing the quality of the figures and images used in the present study.

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Ibrahim, M.F., Abdelaziz, M.H., Samuel, A.M. et al. Effect of Rare Earth Metals on the Mechanical Properties and Fractography of Al–Si-Based Alloys. Inter Metalcast 14, 108–124 (2020). https://doi.org/10.1007/s40962-019-00336-x

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