Abstract
Alloy development can simplify low-cost gas metal arc weld (GMAW)-based 3-D printing by making it easier to print quality parts with minimal metallurgical or welding experience. Previous work found good properties in aluminum alloys, particularly in the aluminum–silicon 4943 (Al–5.5%Si–0.4%Mg) and 4047 (Al–11.6%Si) alloys. These alloys were easy to print, but could benefit from alloying to increase ductility and to minimize or redistribute porosity. The purpose of this study was to modify 4943 and 4047 alloys and rapidly screen their performance for use as feedstock for improved 3-D printability. The 4047- and 4943-based alloys were modified with additions of magnesium, strontium, titanium boride, and combinations thereof. Wedge-shaped castings were used to efficiently screen alloying additions over the same ranges of solidification rates as those observed in GMAW-based 3-D printing. The alloying additions were most effective at modifying the high-silicon 4047 alloy, whereas no change in microstructure was observed in the low-silicon 4943 alloy. Strontium was an effective modifier of the high-silicon alloy. Titanium boride was not observed to have a grain-refining effect on aluminum dendrites on its own, although the combination of strontium and titanium boride produced the most refined eutectic structure in the high-silicon alloy. Future work should evaluate the singular effects of strontium, titanium boride, and the combination of strontium and titanium boride additions in weld-based 3-D printing.
This is a preview of subscription content, access via your institution.














References
L.E. Murr, E. Martinez, K.N. Amato, S.M. Gaytan, J. Hernandez, D.A. Ramirez, R.B. Wicker, Fabrication of metal and alloy components by additive manufacturing: examples of 3D materials science. J. Mater. Res. Technol. 1(1), 42–54 (2012)
T. Wohlers, T. Caffrey, Wohlers Report 2014 Annual Worldwide Progress Report (Wohlers Associates, Inc., Fort Collins, CO, 2014)
W.E. Frazier, Metal additive manufacturing: a review. J. Mater. Eng. Perform. 23(6), 1917–1928 (2014)
T.J. Horn, O.L.A. Harrysson, Overview of current additive manufacturing technologies and selected applications. Sci. Prog. 95(3), 255–282 (2012)
T. Wohlers, T. Caffrey, Wohlers Report 2015 Annual Worldwide Progress Report (Wohlers Associates, Inc., Fort Collins, CO, 2015)
L.E. Murr, S.M. Gaytan, D.A. Ramirez, E. Martinez, J. Hernandez, K.N. Amato, R.B. Wicker, Metal fabrication by additive manufacturing using laser and electron beam melting technologies. J. Mater. Sci. Technol. 28(1), 1–14 (2012)
K. M. B. Taminger, R.A. Hafley, Electron beam freeform fabrication: a rapid metal deposition process, in Presented at the 3rd annual automotive composites conference, Troy, MI: Society of Plastics Engineers, Inc (2003)
J.P. Kruth, Material incress manufacturing by rapid prototyping techniques. CIRP Ann. Manuf. Technol. 40(2), 603–614 (1991)
J. Peels, Metal 3D printing: From lab to fab. Inside 3DP, (2014), www.inside3dp.com/metal-3d-pinting-lab-fab/. Last Accessed 22 Mar 2016
G.C. Anzalone, C. Zhang, B. Wijnen, P.G. Sanders, J.M. Pearce, A low-cost open-source metal 3-D printer. IEEE Access 1, 803–810 (2013)
A. Pinar, B. Wijnen, G.C. Anzalone, T.C. Havens, P.G. Sanders, J.M. Pearce, Low-cost open-source voltage and current monitor for gas metal arc weld 3D printing. J. Sens. 876714, 2015 (2015). doi:10.1155/2015/876714
Y. Nilsiam, A. Haselhuhn, B. Wijnen, P. Sanders, J.M. Pearce, Integrated voltage–current monitoring and control of gas metal arc weld magnetic ball-jointed open source 3-D printer. Machines 3(4), 339–351 (2015)
B. Wijnen, G.C. Anzalone, A.S. Haselhuhn, P.G. Sanders, J.M. Pearce, Free and open-source control software for 3-D motion and processing. J. Open Res. Softw. 4(1), 4:e2 (2016). doi:10.5334/jors.78
Sciaky, Inc. Advantages of wire AM vs. powder AM, (2016), http://www.sciaky.com/additive-manufacturing/wire-am-vs-powder-am. Last Accessed 22 Mar 2016
A. Ujiie, U.S. Patent No. 3,665,143. (Published May 23, 1972). Washington, DC: U.S. Patent and Trademark Office (1972)
H.T. Brandi, H. Luckow, U.S. Patent No. 3,985,995, (Published October 12, 1976). Washington, DC: U.S. Patent and Trademark Office (1976)
D. Ding, Z. Pan, D. Cuiuri, H. Li, A multi-bead overlapping model for robotic wire and arc additive manufacturing (WAAM). Robot. Comput. Integr. Manuf. 31, 101–110 (2015)
J.F. Lancaster, Metallurgy of Welding (Chapman & Hall, London, 1993)
A.S. Haselhuhn, E.J. Gooding, A.G. Glover, G.C. Anzalone, B. Wijnen, P.G. Sanders, J.M. Pearce, Substrate release mechanisms for gas metal arc weld 3D aluminum metal printing. 3D Print. Addit. Manuf. 1(4), 204–209 (2014)
A.S. Haselhuhn, B. Wijnen, G.C. Anzalone, P.G. Sanders, J.M. Pearce, In situ formation of substrate release mechanisms for gas metal arc weld metal 3-D printing. J. Mater. Process. Technol. 226, 50–59 (2015)
A.S. Haselhuhn, M.W. Buhr, B. Wijnen, P.G. Sanders, J.M. Pearce, Structure-property relationships of common aluminum weld alloys utilized as feedstock for GMAW-based 3-D printing. Mater. Sci. Eng. A 673, 511–523 (2016)
A.K. Dahle, K. Nogita, S.D. McDonald, C. Dinnis, L. Lu, Eutectic modification and microstructure development in Al–Si Alloys. Mater. Sci. Eng. A 413–414, 243–248 (2005)
A. Pacz, U.S. Patent No. 1387900A. (Published August 16, 1921). Washington, DC: U.S. Patent and Trademark Office (1920)
S.C. Flood, J.D. Hunt, Modification of Al–Si eutectic alloys with Na. Met. Sci. 15(7), 287–294 (1981)
C.E. Cross, D.L. Olson, Modification of eutectic weld metal microstructure. Weld. J. 61, 381s–387s (1982)
S.-Z. Lu, A. Hellawell, The mechanism of silicon modification in aluminum–silicon alloys: impurity induced twinning. Metall. Trans. A 18(10), 1721–1733 (1987)
Liu Qiyang, Li Qingchun, Liu Qifu, Modification of Al–Si alloys with sodium. Acta Metall. Mater. 39(11), 2497–2502 (1991)
S.-Z. Lu, A. Hellawell, Modification of Al–Si alloys: microstructure, thermal analysis, and mechanisms. JOM 47(2), 38–40 (1995)
H. Liao, G. Dong, G. Sun, Investigation on influence of sodium- or strontium-modification on corrosion-resistance of Al–11.7%Si alloy. J. Mater. Sci. 42(13), 5175–5181 (2007)
L. Lu, K. Nogita, A.K. Dahle, Combining Sr and Na additions in hypoeutectic Al–Si foundry alloys. Mater. Sci. Eng. A 399(1–2), 244–253 (2005)
N.S. Tiedje, J.A. Taylor, M.A. Easton, Feeding and distribution of porosity in cast Al–Si alloys as function of alloy composition and modification. Metall. Mater. Trans. A 43(12), 4846–4858 (2012)
S.-S. Shin, E.-S. Kim, G.-Y. Yeom, J.-C. Lee, Modification effect of Sr on the microstructures and mechanical properties of Al–10.5Si–2.0Cu recycled alloy for die casting. Mater. Sci. Eng. A 532, 151–157 (2012)
C.M. Dinnis, A.K. Dahle, J.A. Taylor, M.O. Otte, The influence of strontium on porosity formation in Al–Si alloys. Metall. Mater. Trans. A. 35(11), 3531–3541 (2004)
P. Srirangam, M.J. Kramer, S. Shankar, Effect of strontium on liquid structure of Al–Si hypoeutectic alloys using high-energy X-ray diffraction. Acta Mater. 59(2), 503–513 (2011)
P. Srirangam, S. Chattopadhyay, A. Bhattacharya, S. Nag, J. Kaduk, S. Shankar, T. Shibata, Probing the local atomic structure of Sr-modified Al–Si alloys. Acta Mater. 65, 185–193 (2014)
D.L. Zhang, B. Cantor, Heterogeneous nucleation of solidification of Si by solid AI in hypoeutectic Al-Si alloy. Metall. Trans. A 24(5), 1195–1204 (1993)
N. Fatahalla, M. Hafiz, M. Abdulkhalek, Effect of microstructure on the mechanical properties and fracture of commercial hypoeutectic Al–Si alloy modified with Na, Sb and Sr. J. Mater. Sci. 34(14), 3555–3564 (1999)
M. Zarif, B. McKay, J. Li, P. Schumacher, Study of the effect of strontium (Sr) on the nucleation of eutectic silicon (Si) in high purity hypoeutectic Al–5Si alloys. BHM Berg-Huettenmaenn. Monatsh. 155(11), 506–511 (2010)
M. Zarif, B. Mckay, P. Schumacher, Study of heterogeneous nucleation of eutectic Si in high-purity Al–Si alloys with Sr addition. Metall. Mater. Trans. A 42(6), 1684–1691 (2011)
L. Liu, A.M. Samuel, F.H. Samuel, H.W. Doty, S. Valtierra, Characteristics of α-dendritic and eutectic structures in Sr-treated Al–Si casting alloys. J. Mater. Sci. 39(1), 215–224 (2004)
S. Nafisi, R. Ghomashchi, H. Vali, Eutectic nucleation in hypoeutectic Al–Si alloys. Mater. Charact. 59(10), 1466–1473 (2008)
G. Heiberg, L. Arnberg, Investigation of the microstructure of the Al–Si eutectic in binary aluminium–7 wt% silicon alloys by electron backscatter diffraction (EBSD). J. Light Met. 1(1), 43–49 (2001)
S.S. Sreeja Kumari, R.M. Pillai, T.P.D. Rajan, B.C. Pai, Effects of individual and combined additions of Be, Mn, Ca and Sr on the solidification behaviour, structure and mechanical properties of Al–7Si–0.3Mg–0.8Fe alloy. Mater. Sci. Eng. A 460–461, 561–573 (2007)
S.S.S. Sreeja Kumari, R.M. Pillai, B.C. Pai, Structure and properties of calcium and strontium treated Al–7Si–0.3Mg alloy: a comparison. J. Alloys Compd. 460(1–2), 472–477 (2008)
G. Heiberg, K. Nogita, A.K. Dahle, L. Arnberg, Columnar to equiaxed transition of eutectic in hypoeutectic aluminium–silicon alloys. Acta Mater. 50(10), 2537–2546 (2002)
C.M. Dinnis, A.K. Dahle, J.A. Taylor, Three-dimensional analysis of eutectic grains in hypoeutectic Al–Si alloys. Mater. Sci. Eng. A 392(1–2), 440–448 (2005)
S.G. Shabestari, M. Keshavarz, M.M. Hejazi, Effect of strontium on the kinetics of formation and segregation of intermetallic compounds in A380 aluminum alloy. J. Alloys Compd. 477(1–2), 892–899 (2009)
L. Heusler, W. Schneider, Influence of alloying elements on the thermal analysis results of Al–Si cast alloys. J. Light Met. 2(1), 17–26 (2002)
B. Kulunk, D.J. Zuliani, Applications for the strontium treatment of wrought and die-cast Al. JOM 48(10), 60–63 (1996)
S.D. McDonald, A.K. Dahle, J.A. Taylor, D.H. St. John, Eutectic grains in unmodified and strontium-modified hypoeutectic aluminum-silicon alloys. Metall. Mater. Trans. A 35(6), 1829–1837 (2004)
M. Timpel, N. Wanderka, R. Schlesiger, T. Yamamoto, N. Lazarev, D. Isheim, J. Banhart, The role of strontium in modifying aluminium–silicon alloys. Acta Mater. 60(9), 3920–3928 (2012)
K. Nogita, H. Yasuda, K. Yoshida, K. Uesugi, A. Takeuchi, Y. Suzuki, A.K. Dahle, Determination of strontium segregation in modified hypoeutectic Al–Si alloy by micro X-ray fluorescence analysis. Scr. Mater. 55(9), 787–790 (2006)
A.K. Dahle, K. Nogita, S.D. McDonald, J.W. Zindel, L.M. Hogan, Eutectic nucleation and growth in hypoeutectic Al–Si alloys at different strontium levels. Metall. Mater. Trans. A. 32(4), 949–960 (2001)
Y.H. Cho, H.-C. Lee, K.H. Oh, A.K. Dahle, Effect of strontium and phosphorus on eutectic Al–Si nucleation and formation of β-Al5FeSi in hypoeutectic Al–Si foundry alloys. Metall. Mater. Trans. A. 39(10), 2435–2448 (2008)
S.D. McDonald, A.K. Dahle, J.A. Taylor, D.H. St. John, Modification-related porosity formation in hypoeutectic aluminum–silicon alloys. Metall. Mater. Trans. B. 35(6), 1097–1106 (2004)
S.D. McDonald, K. Nogita, A.K. Dahle, Eutectic grain size and strontium concentration in hypoeutectic aluminium–silicon alloys. J. Alloys Compd. 422(1–2), 184–191 (2006)
H. Liao, Y. Sun, G. Sun, Correlation between mechanical properties and amount of dendritic α-Al phase in as-cast near-eutectic Al–11.6% Si alloys modified with strontium. Mater. Sci. Eng. A 335(1–2), 62–66 (2002)
M.M. Haque, M.A. Maleque, Effect of process variables on structure and properties of aluminium–silicon piston alloy. J. Mater. Process. Technol. 77(1–3), 122–128 (1998)
M. Easton, D. StJohn, Grain refinement of aluminum alloys: part I. The nucleant and solute paradigms—a review of the literature. Metall. Mater. Trans. A 30(6), 1613–1623 (1999)
M. Easton, D. StJohn, Grain refinement of aluminum alloys: part II. Confirmation of, and a mechanism for, the solute paradigm. Metall. Mater. Trans. A 30(6), 1625–1633 (1999)
L. Lu, A.K. Dahle, Effects of combined additions of Sr and AlTiB grain refiners in hypoeutectic Al–Si foundry alloys. Mater. Sci. Eng. A 435–436, 288–296 (2006)
D.G. Mallapur, S.A. Kori, K.R. Udupa, Influence of Ti, B and Sr on the microstructure and mechanical properties of A356 alloy. J. Mater. Sci. 46(6), 1622–1627 (2010)
B.S. Murty, S.A. Kori, M. Chakraborty, Grain refinement of aluminium and its alloys by heterogeneous nucleation and alloying. Int. Mater. Rev. 47(1), 3–29 (2002)
Y.C. Lee, A.K. Dahle, D.H. StJohn, J.E.C. Hutt, The effect of grain refinement and silicon content on grain formation in hypoeutectic Al–Si alloys. Mater. Sci. Eng. A 259(1), 43–52 (1999)
R.P. Martukanitz, Selection and weldability of heat-treatable aluminum alloys. ASM Handb. 6, 528–536 (1993)
P.B. Dickerson, Welding of aluminum alloys. ASM Handb. 6, 722–739 (1993)
M.J. Caton, J.W. Jones, J.M. Boileau, J.E. Allison, The effect of solidification rate on the growth of small fatigue cracks in a cast 319-type aluminum alloy. Metall. Mater. Trans. A. 30(12), 3055–3068 (1999)
J.M. Boileau, J.E. Allison, The effect of solidification time and heat treatment on the fatigue properties of a cast 319 aluminum alloy. Metall. Mater. Trans. A. 34(9), 1807–1820 (2003)
I.C. Stone, H. Jones, Effect of cooling rate and front velocity on solidification micro structure selection in Al–3.5 wt% Fe–0 to 8.5 wt% Si alloys. Mater. Sci. Eng. A 226, 33–37 (1997)
M.F. Ourfali, I. Todd, H. Jones, Effect of solidification cooling rate on the morphology and number per unit volume of primary Mg2Si particles in a hypereutectic Al–Mg–Si alloy. Metall. Mater. Trans. A. 36(5), 1368–1372 (2005)
J. Zhang, Z. Fan, Y.Q. Wang, B.L. Zhou, Effect of cooling rate on the microstructure of hypereutectic Al-Mg2Si alloys. J. Mater. Sci. Lett. 19(20), 1825–1828 (2000)
J.A. Juarez-Islas, D.H. Warrington, H. Jones, Formation of stable and metastable phases in Al–Mn alloys by the use of a gravity chill casting technique. J. Mater. Sci. 24(6), 2076–2080 (1989)
A. Hawksworth, W.M. Rainforth, H. Jones, Solidification microstructure selection in the Al-rich Al–La, Al–Ce and Al–Nd systems. J. Cryst. Growth 197(1), 286–296 (1999)
J.H. Perepezko, K. Hildal, Analysis of solidification microstructures during wedge-casting. Philos. Mag. 86(24), 3681–3701 (2006)
A.F. Norman, P.B. Prangnell, R.S. McEwen, The solidification behaviour of dilute aluminum–scandium alloys. Acta Mater. 46(16), 5715–5732 (1998)
A.F. Norman, K. Hyde, F. Costello, S. Thompson, S. Birley, P.B. Prangnell, Examination of the effect of Sc on 2000 and 7000 series aluminium castings: for improvements in fusion welding. Mater. Sci. Eng. A 354(1–2), 188–198 (2003)
W. S. Rasband, Image J., U.S. National Institutes of Health, Bethsesda, Maryland, USA, http://imagej.nih.gov/ig/, 1997–2014
D. Bouchard, J.S. Kirkaldy, Prediction of dendrite arm spacings in unsteady- and steady-state heat flow of unidirectionally solidified binary alloys. Metall. Mater. Trans. B 28(4), 651–663 (1997)
S. Su, X. Liang, A. Moran, E.J. Lavernia, Solidification behavior of an Al–6Si alloy during spray atomization and deposition. Int. J. Rapid Solidif. 8(3), 161–177 (1994)
D.W. Heard, S. Brophy, M. Brochu, Solid freeform fabrication of Al–Si components via the CSC-MIG process. Can. Metall. Q. 51(3), 302–312 (2012)
ASTM B557-02. Standard test methods for tension testing wrought and cast aluminum- and magnesium-alloy products. ASTM International, West Conshohocken, PA, 2013, www.astm.org
Q.G. Wang, Microstructural effects on the tensile and fracture behavior of aluminum casting alloys A356/357. Metall. Mater. Trans. A. 34, 2887–2899 (2003)
Q.G. Wang, C.J. Davidson, Solidification and precipitation behaviour of Al–Si–Mg casting alloys. J. Mater. Sci. 36(3), 739–750 (2001)
S. Kou, Welding Metallurgy (Wiley, New York, 1987)
M. Tiryakioglu, J.T. Staley, Physical metallurgy and the effect of alloying additions in aluminum alloys, in Handbook of Aluminum, vol. 1, ed. by G.E. Totten, D.S. MacKenzie (Marcel Dekker Inc, New York, 2003), pp. 81–209
Q.G. Wang, C.H. Caceres, J.R. Griffiths, Damage by eutectic particle cracking in aluminum casting alloys A356/357. Metall. Mater. Trans. A 34, 2901–2912 (2003)
M. Drouzy, S. Jacob, M. Richard, Interpretation of tensile results by means of quality index and probable yield strength—application to Al–Si Mg foundry alloys—France. Int. Cast Met. J. 5(2), 43–50 (1980)
M. Tiryakioglu, J. Campbell, Quality index for aluminum alloy castings. Int. J. Metalcast. 8(3), 39–42 (2014)
Acknowledgements
The authors wish to acknowledge valuable casting and chemical analysis assistance from P. Quimby, polishing assistance from V. Thole, and helpful discussions with Dr. Stephen Kampe and Dr. Thomas Dorin. The authors would also like to acknowledge support and helpful discussions with C. Hsu and technical assistance from the Miller Electric Manufacturing Company. This material is based on research sponsored by Air Force Research Laboratory under agreement number FA8650-12-2-7230. The US Government is authorized to reproduce and distribute reprints for governmental purposes notwithstanding any copyright notation thereon. The views and conclusions contained herein are those of the authors and should not be interpreted as necessarily representing the official policies or endorsements, either expressed or implied, of Air Force Research Laboratory or the US Government.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
No conflicts of interest exist.
Rights and permissions
About this article
Cite this article
Haselhuhn, A.S., Sanders, P.G. & Pearce, J.M. Hypoeutectic Aluminum–Silicon Alloy Development for GMAW-Based 3-D Printing Using Wedge Castings. Inter Metalcast 11, 843–856 (2017). https://doi.org/10.1007/s40962-017-0133-z
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40962-017-0133-z
Keywords
- 3-D printing
- additive manufacturing
- aluminum
- alloy development
- metal casting
- casting