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Influence of Crude Source on the Structural Indices of Short Residue

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Abstract

Production of bitumen for paving purposes is a complex operation at the refinery considering the variability in the crude source. At any instant of time, refineries process a blend of different crudes, and the associated process parameters are varied in real time to maximize the throughput of the lighter ends. Such changes influence the chemical composition of the short residue. To quantify such changes, three different crude sources (Arab Mix, Kuwait, and Assam) were identified, and FTIR spectroscopy was used to characterize them. The variability across different crudes and different short residue obtained from the respective crudes and the relation between the crude and the short residue were quantified in terms of the structural indices such as factor of aliphaticity, aromaticity index, carbonyl index, sulfoxide index, and condensation indices. It was seen that the structural indices from crude oil to short residue were related and the relationship varied between the three different crude sources. Inter-relationships among different indices such as aliphaticity, aromaticity, branching, and condensation were observed, and the relationship among the crude and short residue for these indices was reported.

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References

  1. IS 73 (2013) Paving bitumen-Specification. Bureau of Indian Standards, 4th revision, New Delhi, India (2013)

  2. Nivitha MR, Neethu R, Krishnan JM (2019) Influence of refinery processing methods on ageing of Bitumen. Sadhana 44:128

    Article  Google Scholar 

  3. Billy Wei J, Shull JC, Lee Y-J, Hawley MC (1996) Characterization of asphalt binders based on chemical and physical properties. Int J Polym Anal Charact 3(1):33–58

    Article  Google Scholar 

  4. Liu M, Ferry MA, Davison RR, Glover CJ, Bullin JA (1998) Oxygen up-take as correlated to carbonyl growth in aged asphalts and asphalt corbett fractions. Ind Eng Chem Res 37(12):4669–45674

    Article  Google Scholar 

  5. Corbett LW (1975) Reaction variables in the air blowing of asphalt. Ind Eng Chem Process Design Dev 14(2):181–187

    Article  Google Scholar 

  6. Edwards Y, Tasdemir Y, Issacson U (2005) Influence of commercial waxes on Bitumen aging properties. Energy Fuels 19:2519–2525

    Article  Google Scholar 

  7. Claudy P, Letoffe JM, King GN, Planche JP, Burle B (1991) Characterization of paving asphalts by differential scanning calorimetry. Fuel Sci Tech Int 9(1):71–92

    Article  Google Scholar 

  8. Pieri N, Jacquot F, Mille G, Planche JP, Kister J (1996) GC–MS identification of biomarkers in road asphalts and in their parent crude oils. Org Geochem 25(1–2):51–68

    Article  Google Scholar 

  9. Pieri N, Kister J, Quoniam L, Planche JP, Germanaud L (1996) Assessment of asphalt rheological behaviors by studying their aromatic structures poly-cyclic. Aromat Compd 9(1–4):29–39

    Article  Google Scholar 

  10. Herrington PR, Patrick JE, Ball GFA (1994) Oxidation of roading asphalts. Ind Eng Chem Res 33:2801–2809

    Article  Google Scholar 

  11. Gonzalez G, Sousa MA, Lucas EF (2006) Asphaltenes precipitation from crude oil and hydrocarbon media. Energy fuels 13(12):2544–2551

    Article  Google Scholar 

  12. Michalica P, Daucik P, Zanzotto L (2008) Monitoring of compositional changes occurring during the oxidative aging of two selected asphalts from different sources. Pet Coal 50(2):1–10

    Google Scholar 

  13. Guern ML, Chailleux E, Farcas F, Dreessen S, Mabille I (2010) Physico-chemical analysis of five hard bitumens: identification of chemical species and molecular organization before and after artificial aging. Fuel 89(11):3330–3339

    Article  Google Scholar 

  14. Nivitha MR, Prasad E, Krishnan JM (2015) Ageing in modified Bitumen using FTIR spectroscopy. Int J Pavement Eng 17(7):565–577

    Article  Google Scholar 

  15. Corbett LC (1970) Relationships between composition and physical properties of asphalt. Proc Assoc Asph Paving Technol 39:481–491

    Google Scholar 

  16. Domke CH, Davison RR, Glover CJ (1999) Effect of asphaltenes on SHRP superpave specifications. Energy Fuels 13(2):340–345

    Article  Google Scholar 

  17. Daly WH, Qiu Z (1992) Characterisation of microstructure of asphalt and correlation with their performance. Prepri ACS Div Fuel 37(3):1329–1334

    Google Scholar 

  18. Petersen JC (2009) A review of the fundamentals of asphalt oxidation: chemical, physicochemical, physical property and durability relationships, transportation research e-circular E-C140. Sponsored by characteristics of bituminous materials committee, Transportation Research Board, National Academies of Engineering, Washington, DC, USA

  19. Silverstein RM, Bassler GC, Morrill TC (2005) Spectrometric identification of organic compounds, vol 6. Wiley, Chichester

    Google Scholar 

  20. Speight JG (2016) Handbook of petroleum refining. CRC Press, Boca Raton ISBN 9781466591608

    Book  Google Scholar 

  21. Speight JG, Francisco MA (1990) Studies in petroleum composition IV: changes in the nature of chemical constituents during crude oil distillation. Revue de l’InstitutFrancais du Petrole 45:733

    Google Scholar 

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Correspondence to J. Murali Krishnan.

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Sandeep, I.J.S., Nivitha, M.R., Maheshwari, S. et al. Influence of Crude Source on the Structural Indices of Short Residue. Transp. in Dev. Econ. 6, 8 (2020). https://doi.org/10.1007/s40890-020-0096-2

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  • DOI: https://doi.org/10.1007/s40890-020-0096-2

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