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Recent progress and challenges in crystalline graphdiyne

晶体石墨炔的最新研究进展与挑战

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Abstract

Graphynes (GYs), as a novel carbon allotrope, are composed of sp- and sp2-hybridized carbon atoms. Among them, graphdiyne (GDY) is the most widely studied and has received great attention. Its unique sp-hybridization, uniform pores, and highly conjugated structures, especially GDY with high crystallinity, bring excellent electronic, optic, and mechanical characteristics, making them extensively used in electronic devices, energy storage and conversion, catalysis, gas separation, seawater desalination, and so on. However, GDY materials still face challenges, including the synthesis of highly crystalline GDY and the rapid and non-destructive characterization methods. In this review, we primarily summarize the design, synthesis, and structural characterization of high-crystallinity GDY. Various applications are also described, which may bring new opportunities for highly uniform single-crystalline GDY materials.

摘要

石墨炔(GYs)是一种新型碳同素异形体, 由sp和sp2杂化碳原子组 成. 其中, 石墨双炔(GDY)是目前研究和关注度最广泛的材料. 其独特 的sp杂化、均匀的孔隙和高度共轭的结构带来了优良的电子、光学和 力学特性, 其被广泛应用于电子器件、储能和转换、催化、气体分 离、海水淡化等领域. 然而, GDY材料仍然面临着诸多挑战, 包括高结 晶GDY的合成和快速无损的表征方法. 本文就高结晶度GDY的设计、 合成和结构表征进行了综述. 本文还描述了GDY在各个领域的应用, 为高度均匀的单晶GDY材料带来新的机遇.

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Acknowledgements

This work was supported by the National Key R&D Program of China (2018YFA0703504 and 2022YFA1204502) and the National Natural Science Foundation of China (51932001, 52201284, and 52174387).

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Authors and Affiliations

  1. Henan Province Industrial Technology Research Institute of Resources and Materials, Zhengzhou University, Zhengzhou, 450001, China

    Xinkang Liu  (刘心康) & Jiang Du  (杜江)

  2. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China

    Xinkang Liu  (刘心康) & Jiang Du  (杜江)

  3. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, 100190, China

    Xinkang Liu  (刘心康), Yasong Zhao  (赵亚松) & Dan Wang  (王丹)

  4. University of Chinese Academy of Sciences, Beijing, 100049, China

    Dan Wang  (王丹)

Authors
  1. Xinkang Liu  (刘心康)
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  2. Yasong Zhao  (赵亚松)
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  3. Jiang Du  (杜江)
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  4. Dan Wang  (王丹)
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Contributions

Author contributions Wang D supervised the project and conceived the idea. Liu X wrote the draft. Zhao Y revised the manuscript. Du J provided constructive suggestions. All authors discussed and commented on the manuscript.

Corresponding authors

Correspondence to Yasong Zhao  (赵亚松), Jiang Du  (杜江) or Dan Wang  (王丹).

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Conflict of interest The authors declare that they have no conflict of interest.

Additional information

Xinkang Liu received his BS degree from Taiyuan University of Technology. He is currently studying at Zhengzhou University under the supervision of Prof. Jiang Du. His research interests include the synthesis and catalytic properties of graphdiyne.

Yasong Zhao received her PhD degree from the Department of Chemistry and Chemical Engineering, Harbin Institute of Technology in 2019. She is currently an assistant researcher at the Institute of Process Engineering, Chinese Academy of Sciences. Her research involves the design and synthesis of 2D materials for energy conversion and catalytic applications.

Jiang Du received his BS degree from Nankai University, and then obtained his PhD degree from the University of Chinese Academy of Sciences in 2012 under the supervision of Prof. Dan Wang. Then he joined Professor Brian A. Korgel’s group at the University of Texas in Austin. His research interests include the synthesis and properties of nanowires and 2D nanomaterials. He started working at Zhengzhou University in 2018 as an associate professor.

Prof. Dan Wang received his BS and MS degrees from Jilin University (1994 and 1997) and his PhD degree from Yamanashi University (2001). In 2004, he began his position as a Principal Investigator at the Institute of Process Engineering, Chinese Academy of Sciences. His research interests include inorganic materials chemistry, surface and colloidal chemistry, and hydrothermal chemistry, with a focus on multishelled hollow micro/nanostructured materials and their applications in energy conversion and storage, photocatalysis, sensors, and drug delivery.

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Liu, X., Zhao, Y., Du, J. et al. Recent progress and challenges in crystalline graphdiyne. Sci. China Mater. 67, 729–751 (2024). https://doi.org/10.1007/s40843-023-2735-6

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  • DOI: https://doi.org/10.1007/s40843-023-2735-6

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