Skip to main content
SpringerLink
Log in

Photocatalytic phosphine-mediated water activation generates hydrogen atom radicals for transfer hydrogenation of closed-shell π systems

  • Highlights
  • Published:
Science China Materials Aims and scope Submit manuscript

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Wang D, Astruc D. The golden age of transfer hydrogenation. Chem Rev, 2015, 115: 6621–6686

    Article  CAS  Google Scholar 

  2. Nishimura S. Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis. New Jersey: John Wiley & Sons, 2001

    Google Scholar 

  3. Grünwald A, Heinemann FW, Munz D. Oxidative addition of water, alcohols, and amines in palladium catalysis. Angew Chem Int Ed, 2020, 59: 21088–21095

    Article  Google Scholar 

  4. Rauch M, Kar S, Kumar A, et al. Metal–ligand cooperation facilitates bond activation and catalytic hydrogenation with zinc pincer complexes. J Am Chem Soc, 2020, 142: 14513–14521

    Article  CAS  Google Scholar 

  5. Cooney SE, Fertig AA, Buisch MR, et al. Coordination-induced bond weakening of water at the surface of an oxygen-deficient poly-oxovanadate cluster. Chem Sci, 2022, 13: 12726–12737

    Article  CAS  Google Scholar 

  6. Xiang X, Zhu B, Zhang J, et al. Photocatalytic H2-production and benzyl-alcohol-oxidation mechanism over CdS using Co2+ as hole co-catalyst. Appl Catal B-Environ, 2023, 324: 122301

    Article  CAS  Google Scholar 

  7. Xu F, Meng K, Cheng B, et al. Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction. Nat Commun, 2020, 11: 4613

    Article  CAS  Google Scholar 

  8. Bie C, Zhu B, Wang L, et al. A bifunctional CdS/MoO2/MoS2 catalyst enhances photocatalytic H2 evolution and pyruvic acid synthesis. Angew Chem Int Ed, 2022, 61: e202212045

    Article  CAS  Google Scholar 

  9. Zhang J, Mück-Lichtenfeld C, Studer A. Photocatalytic phosphine-mediated water activation for radical hydrogenation. Nature, 2023, 619: 506–513

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan, 430078, China

    Linxi Wang & Jiaguo Yu

Authors
  1. Linxi Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jiaguo Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jiaguo Yu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, L., Yu, J. Photocatalytic phosphine-mediated water activation generates hydrogen atom radicals for transfer hydrogenation of closed-shell π systems. Sci. China Mater. 66, 4133–4134 (2023). https://doi.org/10.1007/s40843-023-2594-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40843-023-2594-1

Search

Navigation