Skip to main content
SpringerLink
Log in

Tailoring lattice strain in ultra-fine high-entropy alloys for active and stable methanol oxidation

调控超细高熵合金晶格应变用于高活性和高稳定 性甲醇氧化

  • Articles
  • Published:
Science China Materials Aims and scope Submit manuscript

Abstract

High-entropy alloys (HEAs) have been widely studied due to their unconventional compositions and unique physicochemical properties for various applications. Herein, for the first time, we propose a surface strain strategy to tune the electrocatalytic activity of HEAs for methanol oxidation reaction (MOR). High-resolution aberration-corrected scanning transmission electron microscopy (STEM) and elemental mapping demonstrate both uniform atomic dispersion and the formation of a face-centered cubic (FCC) crystalline structure in PtFeCoNiCu HEAs. The HEAs obtained by heat treatment at 700°C (HEA-700) exhibit 0.94% compressive strain compared with that obtained at 400°C (HEA-400). As expected, the specific activity and mass activity of HEA-700 is higher than that of HEA-400 and most of the state-of-the-art catalysts. The enhanced MOR activity can be attributed to a shorter Pt-Pt bond distance in HEA-700 resulting from compressive strain. The nonprecious metal atoms in the core could generate compressive strain and down shift d-band centers via electron transfer to surface Pt layer. This work presents a new perspective for the design of high-performance HEAs electrocatalysts.

摘要

高熵合金(HEAs)因其非常规的组成和独特的物理化学性质 而得到广泛研究. 本文, 我们首次提出了一种表面应变策略来调控 HEAs的电子结构用于高效的甲醇电氧化反应(MOR). 高分辨像差 校正扫描透射电子显微镜(STEM)和元素分布分析表明, 在PtFeCo-NiCu HEAs中各原子分散均匀, 并形成FCC晶体结构. 700°C热处理 所得HEA-700的压缩应变比400°C热处理所得HEA-400的压缩应变 高0.94%. 正如预期, HEA-700的比活性和质量活性远超HEA-400和 目前大多数最先进的催化剂. MOR活性的增强归因于压缩应变导 致HEA-700中Pt–Pt键距缩短. 同时, 核中的非贵金属原子通过转移 电子到表面Pt层产生压缩应变和d带中心的下移. 这项工作为高性 能HEAs电催化剂的设计提供了一个新的视角.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zeb Gul Sial MA, Ud Din MA, Wang X. Multimetallic nanosheets: Synthesis and applications in fuel cells. Chem Soc Rev, 2018, 47: 6175–6200

    Article  CAS  Google Scholar 

  2. Zhang W, Yang Y, Huang B, et al. Ultrathin PtNiM (M = Rh, Os, and Ir) nanowires as efficient fuel oxidation electrocatalytic materials. Adv Mater, 2019, 31: 1805833

    Article  CAS  Google Scholar 

  3. Xia BY, Wu HB, Li N, et al. One-pot synthesis of Pt-Co alloy nanowire assemblies with tunable composition and enhanced electrocatalytic properties. Angew Chem Int Ed, 2015, 54: 3797–3801

    Article  CAS  Google Scholar 

  4. Li J, Jilani SZ, Lin H, et al. Ternary CoPtAu nanoparticles as a general catalyst for highly efficient electro-oxidation of liquid fuels. Angew Chem Int Ed, 2019, 58: 11527–11533

    Article  CAS  Google Scholar 

  5. Rethinasabapathy M, Kang SM, Haldorai Y, et al. Quaternary PtRuFeCo nanoparticles supported N-doped graphene as an efficient bifunctional electrocatalyst for low-temperature fuel cells. J Ind Eng Chem, 2019, 69: 285–294

    Article  CAS  Google Scholar 

  6. Lei Z, Liu X, Wu Y, et al. Enhanced strength and ductility in a high-entropy alloy via ordered oxygen complexes. Nature, 2018, 563: 546–550

    Article  CAS  Google Scholar 

  7. Ding Q, Zhang Y, Chen X, et al. Tuning element distribution, structure and properties by composition in high-entropy alloys. Nature, 2019, 574: 223–227

    Article  CAS  Google Scholar 

  8. El-Atwani O, Li N, Li M, et al. Outstanding radiation resistance of tungsten-based high-entropy alloys. Sci Adv, 2019, 5: eaav2002

    Article  CAS  Google Scholar 

  9. Yao Y, Huang Z, Xie P, et al. Carbothermal shock synthesis of high-entropy-alloy nanoparticles. Science, 2018, 359: 1489–1494

    Article  CAS  Google Scholar 

  10. Yang T, Zhao YL, Tong Y, et al. Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys. Science, 2018, 362: 933–937

    Article  CAS  Google Scholar 

  11. Bondesgaard M, Broge NLN, Mamakhel A, et al. General solvothermal synthesis method for complete solubility range bimetallic and high-entropy alloy nanocatalysts. Adv Funct Mater, 2019, 29: 1905933

    Article  CAS  Google Scholar 

  12. Cantor B, Chang ITH, Knight P, et al. Microstructural development in equiatomic multicomponent alloys. Mater Sci Eng-A, 2004, 375–377: 213–218

    Article  CAS  Google Scholar 

  13. Yeh JW, Chen SK, Lin SJ, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes. Adv Eng Mater, 2004, 6: 299–303

    Article  CAS  Google Scholar 

  14. Zhang Y, Zuo TT, Tang Z, et al. Microstructures and properties of high-entropy alloys. Prog Mater Sci, 2014, 61: 1–93

    Article  CAS  Google Scholar 

  15. Tsai KY, Tsai MH, Yeh JW. Sluggish diffusion in Co-Cr-Fe-Mn-Ni high-entropy alloys. Acta Mater, 2013, 61: 4887–4897

    Article  CAS  Google Scholar 

  16. Yeh JW, Chang SY, Hong YD, et al. Anomalous decrease in X-ray diffraction intensities of Cu-Ni-Al-Co-Cr-Fe-Si alloy systems with multi-principal elements. Mater Chem Phys, 2007, 103: 41–46

    Article  CAS  Google Scholar 

  17. Zhang W, Liaw PK, Zhang Y. Science and technology in high-entropy alloys. Sci China Mater, 2018, 61: 2–22

    Article  CAS  Google Scholar 

  18. Lacey SD, Dong Q, Huang Z, et al. Stable multimetallic nano-particles for oxygen electrocatalysis. Nano Lett, 2019, 19: 5149–5158

    Article  CAS  Google Scholar 

  19. Qiu HJ, Fang G, Wen Y, et al. Nanoporous high-entropy alloys for highly stable and efficient catalysts. J Mater Chem A, 2019, 7: 6499–6506

    Article  CAS  Google Scholar 

  20. Qiu HJ, Fang G, Gao J, et al. Noble metal-free nanoporous high-entropy alloys as highly efficient electrocatalysts for oxygen evolution reaction. ACS Mater Lett, 2019, 1: 526–533

    Article  CAS  Google Scholar 

  21. Luo M, Guo S. Strain-controlled electrocatalysis on multimetallic nanomaterials. Nat Rev Mater, 2017, 2: 17059

    Article  CAS  Google Scholar 

  22. Wang H, Xu S, Tsai C, et al. Direct and continuous strain control of catalysts with tunable battery electrode materials. Science, 2016, 354: 1031–1036

    Article  CAS  Google Scholar 

  23. Strasser P, Koh S, Anniyev T, et al. Lattice-strain control of the activity in dealloyed core-shell fuel cell catalysts. Nat Chem, 2010, 2: 454–460

    Article  CAS  Google Scholar 

  24. Qin Y, Zhang W, Guo K, et al. Fine-tuning intrinsic strain in penta-twinned Pt-Cu-Mn nanoframes boosts oxygen reduction catalysis. Adv Funct Mater, 2020, 30: 1910107

    Article  CAS  Google Scholar 

  25. Bu L, Zhang N, Guo S, et al. Biaxially strained PtPb/Pt core/shell nanoplate boosts oxygen reduction catalysis. Science, 2016, 354: 1410–1414

    Article  CAS  Google Scholar 

  26. Wang D, Xin HL, Hovden R, et al. Structurally ordered intermetallic platinum-cobalt core-shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts. Nat Mater, 2013, 12: 81–87

    Article  CAS  Google Scholar 

  27. Chen L, Zhu J, Xuan C, et al. Effects of crystal phase and composition on structurally ordered Pt-Co-Ni/C ternary intermetallic electrocatalysts for the formic acid oxidation reaction. J Mater Chem A, 2018, 6: 5848–5855

    Article  CAS  Google Scholar 

  28. Wei PC, Liao CN, Wu HJ, et al. Thermodynamic routes to ultralow thermal conductivity and high thermoelectric performance. Adv Mater, 2020, 32: 1906457

    Article  CAS  Google Scholar 

  29. Lee C, Kim G, Chou Y, et al. Temperature dependence of elastic and plastic deformation behavior of a refractory high-entropy alloy. Sci Adv, 2020, 6: eaaz4748

    Article  CAS  Google Scholar 

  30. Sonkusare R, Swain A, Rahul MR, et al. Establishing processing-microstructure-property paradigm in complex concentrated equiatomic CoCuFeMnNi alloy. Mater Sci Eng-A, 2019, 759: 415–429

    Article  CAS  Google Scholar 

  31. Broge NLN, Bondesgaard M, Søndergaard-Pedersen F, et al. Autocatalytic formation of high-entropy alloy nanoparticles. Angew Chem Int Ed, 2020, 59: 21920–21924

    Article  CAS  Google Scholar 

  32. Li C, Yuan Q, Ni B, et al. Dendritic defect-rich palladium-copper-cobalt nanoalloys as robust multifunctional non-platinum electrocatalysts for fuel cells. Nat Commun, 2018, 9: 3702

    Article  CAS  Google Scholar 

  33. Wang L, Yamauchi Y. Metallic nanocages: Synthesis of bimetallic Pt-Pd hollow nanoparticles with dendritic shells by selective chemical etching. J Am Chem Soc, 2013, 135: 16762–16765

    Article  CAS  Google Scholar 

  34. Dutta A, Ouyang J. Ternary NiAuPt nanoparticles on reduced graphene oxide as catalysts toward the electrochemical oxidation reaction of ethanol. ACS Catal, 2015, 5: 1371–1380

    Article  CAS  Google Scholar 

  35. Becknell N, Kang Y, Chen C, et al. Atomic structure of Pt3Ni nanoframe electrocatalysts by in situ X-ray absorption spectroscopy. J Am Chem Soc, 2015, 137: 15817–15824

    Article  CAS  Google Scholar 

  36. Jiang K, Wang P, Guo S, et al. Ordered PdCu-based nanoparticles as bifunctional oxygen-reduction and ethanol-oxidation electrocatalysts. Angew Chem Int Ed, 2016, 55: 9030–9035

    Article  CAS  Google Scholar 

  37. Zhang J, Qu X, Han Y, et al. Engineering PtRu bimetallic nanoparticles with adjustable alloying degree for methanol electrooxidation: Enhanced catalytic performance. Appl Catal B-Environ, 2020, 263: 118345

    Article  CAS  Google Scholar 

  38. Wang H, Wang J, Pi Y, et al. Double perovskite LaFexNi1−xO3 nanorods enable efficient oxygen evolution electrocatalysis. Angew Chem Int Ed, 2019, 58: 2316–2320

    Article  CAS  Google Scholar 

  39. Li YH, Xing J, Chen ZJ, et al. Unidirectional suppression of hydrogen oxidation on oxidized platinum clusters. Nat Commun, 2013, 4: 2500

    Article  CAS  Google Scholar 

  40. Cheng X, Li Y, Zheng L, et al. Highly active, stable oxidized platinum clusters as electrocatalysts for the hydrogen evolution reaction. Energy Environ Sci, 2017, 10: 2450–2458

    Article  CAS  Google Scholar 

  41. Senkov ON, Senkova SV, Dimiduk DM, et al. Oxidation behavior of a refractory NbCrMo0.5Ta0.5TiZr alloy. J Mater Sci, 2012, 47: 6522–6534

    Article  CAS  Google Scholar 

  42. He C, Tao J. Pt loaded two-dimensional TaC-nanosheet/graphene hybrid as an efficient and durable electrocatalyst for direct methanol fuel cells. J Power Sources, 2016, 324: 317–324

    Article  CAS  Google Scholar 

  43. Shao M, Chang Q, Dodelet JP, et al. Recent advances in electrocatalysts for oxygen reduction reaction Chem Rev, 2016, 116: 3594–3657

    Article  CAS  Google Scholar 

  44. Wang Q, Zhao Q, Su Y, et al. Hierarchical carbon and nitrogen adsorbed PtNiCo nanocomposites with multiple active sites for oxygen reduction and methanol oxidation reactions. J Mater Chem A, 2016, 4: 12296–12307

    Article  CAS  Google Scholar 

  45. Jia Q, Zhao Z, Cao L, et al. Roles of Mo surface dopants in Enhancing the ORR performance of octahedral PtNi nanoparticles Nano Lett, 2018, 18: 798–804

    Article  CAS  Google Scholar 

  46. Zhang Y, Shi Y, Chen R, et al. Enriched nucleation sites for Pt deposition on ultrathin WO3 nanosheets with unique interactions for methanol oxidation J Mater Chem A, 2018, 6: 23028–23033

    Article  CAS  Google Scholar 

  47. Xue S, Deng W, Yang F, et al. Hexapod PtRuCu nanocrystalline alloy for highly efficient and stable methanol oxidation ACS Catal, 2018, 8: 7578–7584

    Article  CAS  Google Scholar 

  48. Wang Q, Chen S, Li P, et al. Surface Ru enriched structurally ordered intermetallic PtFe@PtRuFe core-shell nanostructure boosts methanol oxidation reaction catalysis. Appl Catal B-Environ, 2019, 252: 120–127

    Article  CAS  Google Scholar 

  49. Wu G, Li L, Xu BQ. Effect of electrochemical polarization of PtRu/C catalysts on methanol electrooxidation. Electrochim Acta, 2004, 50: 1–10

    Article  CAS  Google Scholar 

  50. Gorle DB, Velacheri Kumman V, Kulandainathan MA. Highly efficient, large surface area and spherically shaped Pt particles deposited electrolytically synthesized graphene for methanol oxidation with impedance spectroscopy. Int J Hydrogen Energy, 2017, 42: 16258–16268

    Article  CAS  Google Scholar 

  51. Hsing IM, Wang X, Leng YJ. Electrochemical impedance studies of methanol electro-oxidation on Pt/C thin film electrode J Electrochem Soc, 2002, 149: A615

    Article  CAS  Google Scholar 

  52. Chen W, Kim J, Sun S, et al. Composition effects of FePt alloy nanoparticles on the electro-oxidation of formic acid Langmuir, 2007, 23: 11303–11310

    Article  CAS  Google Scholar 

  53. Zhang Y, Qiao M, Huang Y, et al. In situ exfoliation and Pt deposition of antimonene for formic acid oxidation via a predominant dehydrogenation pathway. Research, 2020, 2020: 1–11

    CAS  Google Scholar 

  54. Chen W, Kim J, Sun S, et al. Electro-oxidation of formic acid catalyzed by FePt nanoparticles Phys Chem Chem Phys, 2006, 8: 2779–2786

    CAS  Google Scholar 

  55. Li J, Sharma S, Liu X, et al. Hard-magnet L10-CoPt nanoparticles advance fuel cell catalysis. Joule, 2019, 3: 124–135

    Article  CAS  Google Scholar 

  56. Lu Z, Chen ZW, Singh CV Neural network-assisted development of high-entropy alloy catalysts: Decoupling ligand and coordination effects Matter, 2020, 3: 1318–1333

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (51402100, 21573066, 21825201, 22002039, and 21522305), the Scientific Research Foundation of Hunan Provincial Education Department (19C0054), the Postgraduate Scientific Research Innovation Project of Hunan Province (CX20200441), the Australian Research Council (CE 140100012)∣ the Australian National Fabrication Facility ∣ UOW Electron Microscopy Centre, and Compute Canada, Natural Sciences and Engineering Research Council of Canada (NSERC), University of Toronto.

Author information

Author notes

  1. These authors contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory of Chemo/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China

    Dongdong Wang  (王东东), Wei Li  (李巍), Kaizhi Gu  (顾开智), Tehua Wang  (王特华), Yujie Wu  (吴雨洁), Chen Chen  (陈晨), Li Tao  (陶李) & Shuangyin Wang  (王双印)

  2. Department of Materials Science and Engineering, University of Toronto, Toronto, ON, M5S 3E4, Canada

    Zhiwen Chen  (陈志文), Zhuole Lu  (卢琢乐) & Chandra Veer Singh

  3. College of Materials Science and Engineering, Changsha University of Science & Technology, Changsha, 410114, China

    Yiqiong Zhang  (张怡琼)

  4. ARC Centre of Excellence for Electromaterials Science, Intelligent Polymer Research Institute (IPRI), Australian Institute of Innovative Materials (AIIM), University of Wollongong, Wollongong, NSW, 2522, Australia

    Jun Chen  (陈俊)

  5. Research Center for X-Ray Science & Department of Physics, Tamkang University, New Taipei City, 25137, Taiwan

    Yu-Cheng Huang  (黃裕呈) & Chung-Li Dong  (董崇禮)

  6. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, China

    Juan Wang  (王娟) & Xiaoqing Huang  (黄小青)

Authors
  1. Dongdong Wang  (王东东)
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhiwen Chen  (陈志文)
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu-Cheng Huang  (黃裕呈)
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wei Li  (李巍)
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Juan Wang  (王娟)
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Zhuole Lu  (卢琢乐)
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Kaizhi Gu  (顾开智)
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Tehua Wang  (王特华)
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. Yujie Wu  (吴雨洁)
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. Chen Chen  (陈晨)
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. Yiqiong Zhang  (张怡琼)
    View author publications

    You can also search for this author in PubMed Google Scholar

  12. Xiaoqing Huang  (黄小青)
    View author publications

    You can also search for this author in PubMed Google Scholar

  13. Li Tao  (陶李)
    View author publications

    You can also search for this author in PubMed Google Scholar

  14. Chung-Li Dong  (董崇禮)
    View author publications

    You can also search for this author in PubMed Google Scholar

  15. Jun Chen  (陈俊)
    View author publications

    You can also search for this author in PubMed Google Scholar

  16. Chandra Veer Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  17. Shuangyin Wang  (王双印)
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Wang S, Singh CV, Tao L, Zhang Y, Chen J and Dong CL conceived the idea and directed the research Wang D, Chen Z, Huang YC and Li W designed the experiments. Wang D, Li W, Wang J, Gu K, Huang X, Chen J and Wang T synthesized the materials and carried out the XRD, XPS, TEM and STEM physical characterizations. Huang Y and Dong CL did the XANES and EXAFS experiments. Wang D, Zhang Y, Wu Y and Chen C completed the electrochemical tests. Chen Z, Lu Z and Singh CV provided the DFT calculation for this work Wang D, Chen Z, Huang YC and Li W wrote the paper with comments from all authors

Corresponding authors

Correspondence to Yiqiong Zhang  (张怡琼), Li Tao  (陶李), Chung-Li Dong  (董崇禮), Jun Chen  (陈俊), Chandra Veer Singh or Shuangyin Wang  (王双印).

Additional information

Conflict of interest

The authors declare that they have no conflict of interest

Supplementary information

Supporting data are available in the online version of the paper

Dongdong Wang received his Bachelor degree in 2018 from Hunan University of Science and Technology, China. He is currently pursuing his PhD degree under the supervision of Prof. Shuangyin Wang at Hunan University. His research interest includes the synthesis, characterization of nanomaterials for electrocatalysis and electrochemical coupling.

Zhiwen Chen works as a postdoctoral fellow in the Department of Materials Science and Engineering (MSE) at the University of Toronto, Canada. He received his PhD degree from Jilin University, China. His current research focuses on the catalyst design for hydrogen evolution reaction, CO2 reduction reaction, nitrogen reduction reaction, etc. through density functional theory calculations. Some of his studies are carried out in close collaboration with experiments.

Yu-Cheng Huang received his BSc degree from Tamkang University in 2015, and obtained his MSc degree in the Department of Electrophysics from Chiao Tung University in 2017. He started studying for PhD in the Department of Electrophysics, Chiao Tung University in 2017. His research focuses on fundamental XAS analysis, including XANES, EXAFS and soft X-ray in-situ measurement techniques.

Wei Li received his BSc degree in 2013 from Huazhong Agricultural University and his PhD degree in 2018 from Chongqing University under the supervision of Prof. Zidong Wei. He currently works at Hunan University as a postdoctoral researcher under the co-supervision of Prof. Shuangyin Wang. His main research focuses on the development of defective nanomaterials in fuel cell application.

Yiqiong Zhang received her Master degree in 2015 from South China Normal University and her PhD degree in 2019 from Hunan University under the supervision of Prof. Shuangyin Wang. She is currently working at the College of Materials Science and Engineering, Changsha University of Science & Technology. Her current research interests include the synthesis and characterization of nanomaterials with various defects for electrochemical energy conversion and storage technologies.

Li Tao received his Master degree in 2016 and his PhD degree in 2019 from Hunan University under the supervision of Prof. Shuangyin Wang. He is currently an assistant professor of the key Laboratory for Graphene Materials and Devices and College of Chemistry and Chemical Engineering, Hunan University. His research interests are in plasma technology, defect chemistry and fuel cell.

Chung-Li Dong received his PhD degree in physics from Tamkang University in 2004. He then worked as a postdoctoral fellow at the Advanced Light Source Facility (Lawrence Berkeley National Laboratory) with Prof. Jinghua Guo. Now he joined the Department of Physics at Tamkang University as Associate Professor. His current research interests include the development of electrochromic, gaschromic and thermochromic related soft/hard X-ray in-situ reactors, lithium battery systems, supercapacitor systems, and electrocatalytic hydrogen production catalysts.

Jun Chen received his PhD degree at the School of Chemistry, University of Wollongong, Australia, in 2003. Professor Chen is a Chief Investigator of The ARC Centre of Excellence for Electromaterials Science (ACES). His research interests include sustainable energy devices/systems, electro-/bio- interfaces, nano/micro-materials, 2D/3D printing, and design and fabrication of smart electronic devices.

Chandra Veer Singh is the Erwin Edward Hart Endowed Associate Professor and Associate Chair of Research in the Department of Materials Science and Engineering at the University of Toronto, Canada. Dr Singh received his PhD degree in aerospace engineering from Texas A&M University. Subsequently, he worked as a postdoctoral fellow at Cornell University. His research is currently focused on the atomistic modeling and machine learning enabled development of new materials for catalysts and metal-ion batteries.

Shuangyin Wang received his BSc degree in 2006 from Zhejiang University and his PhD degree in 2010 from Nanyang Technological University, Singapore. He is currently a professor of the Key Laboratory for Graphene Materials and Devices and College of Chemistry and Chemical Engineering, Hunan University. His research interests are in plasma technology, defects in various crystals and their application for electrochemical energy storage and conversion.

Supporting Information

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, D., Chen, Z., Huang, YC. et al. Tailoring lattice strain in ultra-fine high-entropy alloys for active and stable methanol oxidation. Sci. China Mater. 64, 2454–2466 (2021). https://doi.org/10.1007/s40843-020-1635-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40843-020-1635-9

Keywords

Search

Navigation