Fast three-dimensional assembly of MoS2 inspired by the gelation of graphene oxide

二维材料的快速三维自组装: 从氧化石墨烯到二硫化钼


本工作借助1,4-丁二醇二缩水甘油醚(BDGE)与氧化石墨烯上羧基的相互作用, 实现了氧化石墨烯的快速三维组装. 基于此方法, 我们通过表面活性剂分散其他二维材料并实现材料表面官能化, 借助于这些表面官能团与BDGE的相互作用, 发展出一种普适的二维材料快速三维自组装方法. 以二硫化钼为例, 组装形成的三维结构显著提高了表面利用率, 极大地改善了其作为钠离子电池负极材料的电化学性能.


  1. 1

    Bonaccorso F, Colombo L, Yu G, et al. Graphene, related twodimensional crystals, and hybrid systems for energy conversion and storage. Science, 2015, 347: 1246501

    Article  Google Scholar 

  2. 2

    Mas-Ballesté R, Gómez-Navarro C, Gómez-Herrero J, et al. 2D materials: to graphene and beyond. Nanoscale, 2011, 3: 20–30

    Article  Google Scholar 

  3. 3

    Soundiraraju B, George BK. Two-dimensional titanium nitride (Ti2N) MXene: Synthesis, characterization, and potential application as surface-enhanced raman scattering substrate. ACS Nano, 2017, 11: 8892–8900

    Article  Google Scholar 

  4. 4

    Xu M, Liang T, Shi M, et al. Graphene-like two-dimensional materials. Chem Rev, 2013, 113: 3766–3798

    Article  Google Scholar 

  5. 5

    Wang R, Wang S, Jin D, et al. Engineering layer structure of MoS2- graphene composites with robust and fast lithium storage for highperformance Li-ion capacitors. Energy Storage Mater, 2017, 9: 195–205

    Article  Google Scholar 

  6. 6

    Lv W, Li Z, Deng Y, et al. Graphene-based materials for electrochemical energy storage devices: opportunities and challenges. Energy Storage Mater, 2016, 2: 107–138

    Article  Google Scholar 

  7. 7

    Li D, Müller MB, Gilje S, et al. Processable aqueous dispersions of graphene nanosheets. Nat Nanotech, 2008, 3: 101–105

    Article  Google Scholar 

  8. 8

    Dreyer DR, Park S, Bielawski CW, et al. The chemistry of graphene oxide. Chem Soc Rev, 2010, 39: 228–240

    Article  Google Scholar 

  9. 9

    Lv W, Zhang C, Li Z, et al. Self-assembled 3D graphene monolith from solution. J Phys Chem Lett, 2015, 6: 658–668

    Article  Google Scholar 

  10. 10

    Bai H, Li C, Wang X, et al. On the gelation of graphene oxide. J Phys Chem C, 2011, 115: 5545–5551

    Article  Google Scholar 

  11. 11

    Liu Z, Lau SP, Yan F. Functionalized graphene and other twodimensional materials for photovoltaic devices: device design and processing. Chem Soc Rev, 2015, 44: 5638–5679

    Article  Google Scholar 

  12. 12

    Chhowalla M, Shin HS, Eda G, et al. The chemistry of twodimensional layered transition metal dichalcogenide nanosheets. Nat Chem, 2013, 5: 263–275

    Article  Google Scholar 

  13. 13

    Zhang X, Lai Z, Tan C, et al. Solution-processed two-dimensional MoS2 nanosheets: Preparation, hybridization, and applications. Angew Chem Int Ed, 2016, 55: 8816–8838

    Article  Google Scholar 

  14. 14

    Zhang Q, Xu Z, Lu B. Strongly coupled MoS2–3D graphene materials for ultrafast charge slow discharge LIBs and water splitting applications. Energy Storage Mater, 2016, 4: 84–91

    Article  Google Scholar 

  15. 15

    Yun Q, Lu Q, Zhang X, et al. Three-dimensional architectures constructed from transition-metal dichalcogenide nanomaterials for electrochemical energy storage and conversion. Angew Chem Int Ed, 2018, 57: 626–646

    Article  Google Scholar 

  16. 16

    Wang P, Tian J, Hu J, et al. Supernormal conversion anode consisting of high-density MoS2 bubbles wrapped in thin carbon network by self-sulfuration of polyoxometalate complex. ACS Nano, 2017, 11: 7390–7400

    Article  Google Scholar 

  17. 17

    Huang C, Bai H, Li C, et al. A graphene oxide/hemoglobin composite hydrogel for enzymatic catalysis in organic solvents. Chem Commun, 2011, 47: 4962–4964

    Article  Google Scholar 

  18. 18

    Thommes M, Kaneko K, Neimark AV, et al. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution. Pure Appl Chem, 2015, 87: 1051–1069

    Article  Google Scholar 

  19. 19

    Pei S, Cheng HM. The reduction of graphene oxide. Carbon, 2012, 50: 3210–3228

    Article  Google Scholar 

  20. 20

    Jiang H, Ren D, Wang H, et al. 2D monolayer MoS2-carbon interoverlapped superstructure: engineering ideal atomic interface for lithium ion storage. Adv Mater, 2015, 27: 3687–3695

    Article  Google Scholar 

  21. 21

    Liu Y, He X, Hanlon D, et al. Liquid phase exfoliated MoS2 nanosheets percolated with carbon nanotubes for high volumetric/ areal capacity sodium-ion batteries. ACS Nano, 2016, 10: 8821–8828

    Article  Google Scholar 

  22. 22

    Choi SH, Ko YN, Lee JK, et al. 3D MoS2-graphene microspheres consisting of multiple nanospheres with superior sodium ion storage properties. Adv Funct Mater, 2015, 25: 1780–1788

    Article  Google Scholar 

  23. 23

    David L, Bhandavat R, Singh G. MoS2/graphene composite paper for sodium-ion battery electrodes. ACS Nano, 2014, 8: 1759–1770

    Article  Google Scholar 

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This work was supported by the National Natural Science Foundation of China (51772164 and U1601206), Guangdong Natural Science Funds for Distinguished Young Scholar (2017B030306006), Guangdong Special Support Program (2017TQ04C664), Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01N111) and Shenzhen Technical Plan Project (JCYJ20170412171630020 and JCYJ20170412171359175).

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Correspondence to Wei Lv 吕伟 or Quan-Hong Yang 杨全红.

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Yaqian Deng received her Bachelor’s degree of materials chemistry from Sichuan University in 2014 and now she is a PhD candidate under the guidance of Prof. Quan-Hong Yang and Prof. Wei Lv. Her research interest mainly focuses on the assembly of graphene and other two dimensional materials for energy storage.

Chong Luo received his Bachelor’s degree of materials science and engineering from the Central South University in 2013 and now he is a PhD candidate under the guidance of Prof. Quan-Hong Yang and Prof. Wei Lv. His research interest focuses on the liquid phase assembly of graphene oxide and the mechanism on energy storage characteristics and devices.

Wei Lv received his PhD from Tianjin University in 2012 under the supervision of Prof. Quan-Hong Yang. He currently works as an Associate Professor in the Graduate School at Shenzhen, Tsinghua University. His research mainly focuses on novel carbon materials, such as graphene and porous carbons, and their applications in electrochemical energy storage.

Quan-Hong Yang was born in 1972, joined Tianjin University as a full professor of nanomaterials in 2006 and became a chair professor in 2016. His research is related to novel carbon materials, from porous carbons, tubular carbons to sheetlike graphene and their applications in energy storage and environmental protection.

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Fast three-dimensional assembly of MoS2 inspired by the gelation of graphene oxide

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Deng, Y., Luo, C., Zhang, J. et al. Fast three-dimensional assembly of MoS2 inspired by the gelation of graphene oxide. Sci. China Mater. 62, 745–750 (2019).

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