Preparation of Sandwich-like NiCo2O4/rGO/NiO Heterostructure on Nickel Foam for High-Performance Supercapacitor Electrodes
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A kind of sandwich-like NiCo2O4/rGO/NiO heterostructure composite has been successfully anchored on nickel foam substrate via a three-step hydrothermal method with successive annealing treatment. The smart combination of NiCo2O4, reduced graphene oxide (rGO), and NiO nanostructure in the sandwich-like nano architecture shows a promising synergistic effect for supercapacitors with greatly enhanced electrochemical performance. For serving as supercapacitor electrode, the NiCo2O4/rGO/NiO heterostructure materials exhibit remarkable specific capacitance of 2644 mF cm−2 at current density of 1 mA cm−2, and excellent capacitance retentions of 97.5% after 3000 cycles. It is expected that the present heterostructure will be a promising electrode material for high-performance supercapacitors.
KeywordsNiCo2O4 Reduced graphene oxide (rGO) NiO Heterostructure Supercapacitors
A new sandwich-like NiCo2O4/rGO/NiO heterostructure is prepared by using a facile process via a three-step hydrothermal method.
This sandwich-like heterostructure exhibits a specific capacitance up to 2644 mF cm−2 and shows enhanced electrochemical performance.
Supercapacitors have attracted wide attention because of their ultra-high power density, long cycling stability, fast charge/discharge rate, and bridging function for the power and energy gaps between batteries and traditional dielectric capacitors [1, 2]. Generally, the electrode materials used for supercapacitors can be divided into two categories based on the different energy storage mechanisms: electrical double-layer capacitors (EDLCs) and pseudo-capacitors (PCs) . In fact, PCs exhibit much larger capacitance values and energy density than EDLCs due to their fast and reversible redox reaction . Therefore, considerable efforts have been focused on improving the performance of PCs. It has been recognized that the most used PCs’ electrode materials, including RuO2, NiO, Co3O4, and MnO2, possess multiple oxidation states/structures, which enable rich redox reactions on the surface of the electrodes and provide high specific capacitance. However, the poor conductivity and cycling stability of these materials restrict their applications [5, 6, 7, 8].
More recently, mixed transition-metal oxides (MTMOs), such as single-phase ternary metal oxides with two different metal cations, typically in a spinel structure (donated as AxB3−xO4, A, B = Co, Ni, Zn, Mn, Fe, and so on), have captured much attention as promising electrode materials in electrochemical energy conversion and storage systems [9, 10]. Among the MTMOs, compared with NiO and Co3O4, the spinel nickel cobaltite (NiCo2O4) exhibits better electrical conductivity and higher electrochemical activity [9, 11]. However, the relatively weak conductivity and small specific surface area make the capacity greatly lower than the theoretical value. Therefore, numerous efforts have been made to optimize the supercapacitors performance of NiCo2O4 via various methods, including control of microstructures, crystallinity, and electrical conductivity [12, 13, 14].
Rationally designed electrode materials with well-defined micro-/nanostructures are attractive methods to enhance the performance of PCs [15, 16, 17, 18]. For example, Zhang et al.  reported Co3O4@NiCo2O4 nanowire arrays for PCs with an improved specific capacitance (2.04 F cm−2 at 5 mV s−1) with respect to pure Co3O4. Liu et al.  synthesized a binder-free hierarchical NiCo2O4/NiO nanowire array using a facile hydrothermal method, and the composites exhibited superior pseudocapacitive performance with high specific capacitance (2220 F g−1 at 1 A g−1). Cai et al.  constructed a one-dimension (1D) CNT@NiCo2O4 core–shell structural nanocable for PCs with a high capacitance of 1038 F g−1 at 0.5 A g−1.
In addition, graphene has been widely used as electrode materials due to its excellent electrical, optical, and chemical properties [19, 20, 21, 22]. Zhang et al.  showed that flower-like NiCo2O4/3D graphene foam exhibited a specific capacitance of 1402 F g−1 at 1 A g−1. Liu et al.  prepared a mesoporous NiCo2O4 nanoneedle grown on graphene networks and the composite delivered a high specific capacitance of 970 F g−1 at 20 A g−1.
In this paper, we prepared a sandwich-like NiCo2O4/rGO/NiO heterostructure composite on nickel foam (NF) via a facile hydrothermal method and subsequent annealing in the air. In the designed sandwich-like structure, the components were assembled into a uniform structure and each component could partially retain its individual traits to improve electrochemical properties. When it was used as electrode materials, it showed a much higher specific capacitance than those of materials such as NiCo2O4, NiO, and NiCo2O4/NiO. We propose that the smart combination among NiO, rGO, and NiCo2O4 nanostructures may provide a synergistic effect for supercapacitors to enhance the electrochemical performance.
3 Experimental Section
3.1 Preparation of NiO on NF
Prior to the synthesis, the NF substrate was carefully cleaned with acetone, ethanol, and deionized (DI) water in an ultrasound bath to remove surface impurities. In a typical procedure, the cleaned NF (approximately 1 × 1 cm2 for each piece) and 40 mL DI water were put into a 50-mL Teflon-lined stainless autoclave and heated at 200 °C for 24 h. The precursor products were washed with ethanol and DI water, and dried at 80 °C for 6 h. Then, the products were annealed at 350 °C for 2 h in air to obtain NiO on NF. The load mass of NiO is 0.6 mg cm−2.
3.2 Preparation of rGO/NiO Composite on NF
Graphene oxide (GO) was synthesized by a modified Hummer’s method which is described in detail in our previous work . The rGO/NiO composites were prepared according to the following process. (i) The as-synthesized GO (40 mg) was added into DI water (40 mL) and dispersed for 2 h with an aid of ultra-sonication. (ii) Several pieces of NiO on NF were put into the above GO dispersion, followed by soaking for 2 h. (iii) The mixture was then transferred into a 50 mL Teflon-lined stainless autoclave, and maintained at 200 °C for 24 h. (iv) As the autoclave cooled down to room temperature, the products were washed for several times with DI water and ethanol, and dried at 60 °C for 4 h in vacuum to obtain the rGO/NiO composites on NF. The load mass of rGO/NiO was 0.6 mg cm−2 (the mass of rGO was too small to be weighed out).
3.3 Preparation of Sandwich-like NiCo2O4/rGO/NiO Heterostructure Composites on NF
The typical synthesis process of sandwich-like NiCo2O4/rGO/NiO heterostructure composites on NF is as follows. Firstly, 0.5 g urea, 1 mmol Co(NO3)2·6H2O, and 0.5 mmol Ni(NO3)2·6H2O were dissolved into 40 mL DI water, and stirred for 30 min to form a uniform solution. Then, a piece of rGO/NiO on NF was put into the above solution and soaked for 2 h. The mixture was transferred into a 50 mL Teflon-lined stainless autoclave, and maintained at 120 °C for 6 h. As the autoclave cooled down to room temperature, the precursor products were washed for several times with DI water and ethanol, and dried at 60 °C for 4 h under vacuum. Finally, the precursors were annealed at 350 °C for 2 h to obtain sandwich-like NiCo2O4/rGO/NiO heterostructure on NF. The NiCo2O4 or the NiCo2O4/NiO composite on NF were fabricated under identical conditions, in which the substrate was changed into NF or NiO on NF. The load mass of the NiCo2O4/rGO/NiO, NiCo2O4/NiO, and NiCo2O4 are 1.6, 1.4, and 0.9 mg cm−2, respectively.
3.4 Materials Characterizations
The phase structures of the samples were characterized by using an X-ray diffraction spectrometer (XRD, D8 Advanced XRD; Bruker AXS, Karlsruhe, Germany) with Cu Kα radiation. The morphologies of the samples were observed by using a scanning electron microscope (SEM, S-4800, Hitachi High-Technologies Corporation, Japan). Raman spectra were measured in a laser scanning confocal micro-Raman spectrometer (LabRAM HR, HORIBA, France).
3.5 Electrochemical Measurement
The electrochemical tests were performed in a 6 M KOH aqueous electrolyte solution at room temperature. The electrochemical properties of the samples were evaluated using a CHI660D Electrochemical Working Station in a three-electrode system, wherein the samples on NF function as the working electrode (WE), platinum functions as the counter electrode, and saturated calomel electrode (SCE) electrode functions as the reference electrode.
The specific capacitance (C) was calculated from the slope of each discharge curve, according to the equation \(C = (I \times \Delta t)/(\Delta V \times S),\) where I is the constant discharge current; Δt is the discharge time; ΔV is the voltage difference in discharge (exclude IR drop); and S is the area of each active materials [19, 23]. Electrochemical impedance spectroscopy (EIS) measurements were made in the frequency range of 0.1–100,000 Hz by applying an AC voltage with 5 mV perturbation.
4 Results and Discussion
With the increasing scan rate, the redox peaks maintain stable, indicating excellent kinetic reversibility at a large scan rate. To further calculate the specific capacitance and understand the rate capability of the NiCo2O4/rGO/NiO composite electrode, the charge/discharge measurements were performed. Figure 5b gives the discharge curves of the NiCo2O4/rGO/NiO electrode at various current densities. The corresponding specific capacitance was calculated to be 2644 mF cm−2 at a low current density (1 mA cm−2), and 1821.6 mF cm−2 at a high current density (100 mA cm−2).
Figure 6c illustrates specific capacitance as a function of current density of NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO. Within the current density range of 1–100 mA cm−2, the area-specific capacitance of the samples has the order of NiO < rGO/NiO < NiCo2O4 < NiCo2O4/NiO < NiCo2O4/rGO/NiO. Since the area-specific capacitances of NiO and rGO/NiO are too small at a high current density of 100 mA cm−2, the data are not presented in Fig. 6c. The area-specific capacitances of the NiO, rGO/NiO, NiCo2O4, NiCo2O4/NiO, and NiCo2O4/rGO/NiO were 374, 516.8, 975.5, 2092, and 2644 mF cm−2 at a low current density (1 mA cm−2), respectively.
In general, EIS is usually used to investigate the performance of electrochemical capacitors, such as internal resistance and capacity [18, 19]. The EIS data were commonly analyzed by using Nyquist plots, in which the frequency response of the electrode/electrolyte system and the plots of the imaginary component (Z″) of the impedance against the real component (Z′) are presented . As shown in Fig. 6d, the EIS curves exhibit similar forms with inconspicuous semicircle in the high-frequency region and an almost straight sloping line in the low-frequency region. The inconspicuous semicircle region indicates low faradaic resistance of the materials and good electrical conductivity between the samples and NF [30, 31].
All the above results confirm that the sandwich-like NiCo2O4/rGO/NiO heterostructure can improve the electrochemical performance for supercapacitor application. The possible mechanism may be ascribed as follows: (i) NiCo2O4 is a kind of p-type semiconductor material. If it is coupled with other semiconductors, it will introduce impurity band effect which can greatly enhance the electrical conductivity as electrode materials [32, 33, 34]. The unique structure characteristics of the NiCo2O4/rGO/NiO composite present a promising candidate for high-performance supercapacitors electrode materials. (ii) The 2D NiO nanoplates, 1D NiCo2O4 nanoneedles, and 2D rGO film constructed to 3D porous structure on NF, allow completely exposing to the electrolyte, and thus optimize the electrochemical accessibility [26, 27]. (iii) The hierarchical architecture which directly grew from the current collector avoids the use of binders and substantially reduces the dead volume in the electrode, and therefore would be favorable for the migration of hydrated ions in the electrolyte to the surface of the electrode [15, 35]. (iv) The existence of graphene enhances the conductivity, and therefore enhances the specific capacitance. Also the flexible graphene between NiO and NiCo2O4 could buffer against the local volume change during the charge–discharge process, as well as alleviate the pulverization and aggregation of the electrode material [36, 37, 38]. (v) Moreover, the synergistic effect of each component would lead to fast ion/electron transfer and enhance flexibility, which finally results in the improvement of electrochemical performance.
The sandwich-like NiCo2O4/rGO/NiO heterostructure composites with high electrochemical performance were synthesized on NF directly via a three-step hydrothermal strategy. The as-fabricated heterostructure composites exhibit excellent electrochemical performance including high specific capacitance, good electrochemical stability, and excellent rate capability. Its remarkably enhanced electrochemical performance is attributed to the unique hierarchical sandwich-like structure and the synergistic effects among NiCo2O4, rGO, and NiO. The results suggest that the sandwich-like NiCo2O4/rGO/NiO heterostructure composites will be promising electrode materials for high-performance sustainable energy storage devices.
This work was supported by the Special Fund for the Development of Strategic Emerging Industries of Shenzhen City of China (No. JCYJ20140419141154246), the National Nature Science Foundation of China (No. 11174227), and Chinese Universities Scientific Fund.
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