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Corrosion Inhibition Effect of Quinoxaline Derivative on Carbon Steel in Hydrochloric Acid: Experimental and Theoretical Investigations

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Abstract

The inhibitory effect of ethyl 2-(2-oxo-3-phenylquinoxalin-1(2H)-yl) acetate (PQXA) on the corrosion of carbon steel (CS35) in a 1 M HCl electrolyte was investigated using weight loss, potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), surface morphology, and UV–visible spectroscopy techniques. Quantum chemical calculations were also conducted to corroborate the experimental findings. The experimental results indicate that PQXA has excellent effectiveness in inhibiting the corrosion of CS35 in 1 M HCl. The inhibition efficiency demonstrated improvement with increasing concentration, reaching a maximum of 94.7% at a concentration of 10−3M at 303 K. The PDP measurements show that PQXA acts as a mixed-type inhibitor. Adsorption of PQXA on the CS35 surface conforms to the Langmuir isotherm model. UV–visible spectroscopy examinations confirmed chemical interactions between the PQXA and CS35, while the SEM/EDX analyses revealed the formation of the protective film of the inhibitor on the CS35 surface. Moreover, theoretical investigations employing density functional theory (DFT) and molecular dynamics (MD) simulation were conducted to define the nature of adsorption, the possible adsorption orientation of quinoxaline molecules on the CS35 surface, and the correlation between inhibition effectiveness and molecular structure.

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  1. Laboratory of Materials, Nanotechnology and Environment, Faculty of Sciences, Mohammed V University in Rabat, P.O. Box 1014, Rabat, Morocco

    L. Chahir, F. Benhiba, G. Kaichouh, A. Bellaouchou & A. Zarrouk

  2. Laboratory of Organic Chemistry, Inorganic, Electrochemistry, and Environment, Department of Chemistry, Faculty of Sciences, Ibn Tofaïl University, PO Box 133, 14000, Kenitra, Morocco

    M. El Faydy

  3. Laboratory of Medicinal Chemistry, Drug Sciences Research Center, Faculty of Medicine and Pharmacy, Mohammed V University, Rabat, Morocco

    N. Abad & Y. Ramli

  4. Higher Institute of Nursing Professions and Health Techniques of Agadir Annex Guelmim, Guelmim, Morocco

    F. Benhiba

  5. Department of Chemistry, An-Najah National University, P.O. Box 7, Nablus, Palestine

    I. Warad

  6. Laboratory of Interface Materials Environment, Faculty of Sciences Aἵn Chock, Hassan II University of Casablanca, BP 5366, Casablanca, Morocco

    D. Benmessaoud Left & M. Zertoubi

  7. Institute of Nursing Professions and Health Techniques Fez, EL Ghassani Hospital, 30000, Fez, Morocco

    M. Allali

  8. Department of Mechanical Engineering, Ataturk University, 25240, Erzurum, Turkey

    B. Dikici

  9. Mohammed VI Center for Research and Innovation (CM6), 10000, Rabat, Morocco

    Y. Ramli

Authors
  1. L. Chahir
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  2. M. El Faydy
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  3. N. Abad
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  4. F. Benhiba
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  5. I. Warad
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  6. D. Benmessaoud Left
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  7. M. Zertoubi
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  8. M. Allali
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  9. G. Kaichouh
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  10. B. Dikici
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  11. A. Bellaouchou
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  12. Y. Ramli
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  13. A. Zarrouk
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Contributions

LC and NA: Conceptualization; Data curation; Formal analysis; Software; Investigation; Methodology; Writing—original draft; Writing—review & editing. ME, FB, IW, DBL, MZ, MA, GK, BD, AB, YR, and AZ: Conceptualization; Data curation; Formal analysis; Methodology; Writing—original draft; Writing—review & editing.

Corresponding author

Correspondence to A. Zarrouk.

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Chahir, L., Faydy, M.E., Abad, N. et al. Corrosion Inhibition Effect of Quinoxaline Derivative on Carbon Steel in Hydrochloric Acid: Experimental and Theoretical Investigations. J Bio Tribo Corros 10, 36 (2024). https://doi.org/10.1007/s40735-024-00840-6

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  • DOI: https://doi.org/10.1007/s40735-024-00840-6

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