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Adsorption and Inhibitive Action of Mitracarpus Hirtus Extract Towards the Corrosion of Mild Steel in H2SO4 Medium

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Abstract

The corrosion inhibition of mild steel in 0.5 M H2SO4 medium by methanol extract of Mitracarpus Hirtus leaves was studied using weight loss, colorimetric and electrochemical studies. Results indicate that the inhibitor is effective in H2SO4 medium and the efficiency decreases with increase in temperature and concentration of the acid. The adsorption of the inhibitor through charge transfer mechanism was confirmed by impedance studies and the mixed type nature of the inhibitor was inferred from the Tafel plots. The adsorption of the inhibitor onto the mild steel surface follows Frenulidch isotherm. FESEM, EDS and FT-IR analyses confirmed the protective layer formed on the mild steel surface.

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References

  1. Perumal S, Muthumanickam S, Elangovan A, Karthik R, Mothilal KK (2017) Bauhinia tomentosa leaves extract as green corrosion inhibitor for mild steel in 1M HCl medium. J Bio Tribo Corros 3(2):13. https://doi.org/10.1007/s40735-017-0072-5

    Article  Google Scholar 

  2. Zhang K, Xu B, Yang W, Yin X, Liu Y, Chen Y (2015) Halogen-substituted imidazoline derivatives as corrosion inhibitors for mild steel in hydrochloric acid solution. Corros Sci 90:284–295

    Article  CAS  Google Scholar 

  3. Shahabi S, Norouziz P, Ganjali MR (2015) Investigation of two carboxamide compounds containing heterocyclic rings as carbon steel corrosion inhibitors in HCl solution. Russ J Electrochem 51(9):833–842

    Article  CAS  Google Scholar 

  4. Upadhyaya RK, Anthony S, Mathur SP (2007) Schiffs bases as inhibitors of mild steel corrosion in hydrochloric acid. Russ J Electrochem 43(2):238–241

    Article  Google Scholar 

  5. Yousefi A, Javadian S, Dalir N, Kakema J, Akbari J (2015) Imidazolium-based ionic liquids as modulators of corrosion inhibition of SDS on mild steel in hydrochloric acid solutions: experimental and theoretical studies. RSC Adv 5(16):11697–11713

    Article  CAS  Google Scholar 

  6. Singh DK, Kumar S, Udayabhanu G, John RP (2016) 4 (N, N-dimethylamino) benzaldehyde nicotinic hydrazone as corrosion inhibitor for mild steel in 1 M HCl solution: an experimental and theoretical study. J Mol Liq 216:738–746

    Article  CAS  Google Scholar 

  7. EI-Etre AY (2008) Inhibition of C-steel corrosion in acidic solution using the aqueous extract of zallouh root. Mater Chem Phys 108(2–3):278–282

    Article  Google Scholar 

  8. Krishnaveni K, Ravichandran J, Selvaraj A (2014) Inhibition of mild steel corrosion by Morinda tinctoria leaves extract in sulphuric acid medium. Ionics 20(1):115–126

    Article  CAS  Google Scholar 

  9. Jyothi S, Ravichandran J (2013) Inhibitive effect of leaves extract of coccinia indica on the corrosion of mild steel in hydrochloric acid. J Environ Nanotechnol 2:21–27

    Google Scholar 

  10. Jyothi S, Ravichandran J (2015) Inhibitive action of the acid extract of Luffa aegyptiaca leaves on the corrosion of mild steel in acidic medium. J Adhes Sci Technol 29(3):207–231

    Article  CAS  Google Scholar 

  11. Kathiravan S, Ragul R, Raja G, Ravichandran J (2018) Theoretical and experimental studies about the inhibitive action of Ruellia tuberosa L on mild steel in HCl medium. J Bio Tribo Corros 4(3):46

    Article  Google Scholar 

  12. Ragul R, Kathiravan S, Murugesh A, Ravichandran J (2018) Anticorrosion performance of Mitracarpus hirtus extract on mild steel in 1 M HCl. J Bio Tribo Corros 4:63

    Article  Google Scholar 

  13. Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M (2020) Experimental complemented with microscopic (electronic/atomic)-level modeling explorations of Laurus nobilis extract as green inhibitor for carbon steel in acidic solution. J Ind Eng Chem 84:52–71

    Article  CAS  Google Scholar 

  14. Saxena A, Thakur KK, Bhardwaj N (2020) Electrochemical studies and surface examination of low carbon steel by applying the extract of Musa acuminata. Surf Interfaces 18:100436

    Article  Google Scholar 

  15. Ferdosi Heragh M, Tavakoli H (2019) Electrochemical properties of a new green corrosion inhibitor derived from Prosopis farcta for St37 steel in 1 M hydrochloric acid. Met Mater Int. https://doi.org/10.1007/s12540-019-00453-6

    Article  Google Scholar 

  16. Sin HLY, Al-Shishani A, Rahim AA, Saad B, Pandian BR (2019) Corrosion inhibition potential of aquilaria leaf constituents—A HPLC view. Prog Org Coat 135:536–544

    Article  CAS  Google Scholar 

  17. Suleiman M, Rugumamu CP, Ibrahim ND (2018) Insecticidal toxicity of some botanicals against Sitophilus zeamais Motsch. (Coleoptera: Curculionidae) in stored sorghum grains in Nigeria. J Entomol Zool Stud 6:1280–1287

    Google Scholar 

  18. Karthik R, Muthukrishnan P, Elangovan A, Jeyaprabha B, Prakash P (2014) Extract of Cassia senna as green inhibitor for the corrosion of mild steel in 1M hydrochloric acid solution. Adv Civil Eng Mater 3(1):413–433

    CAS  Google Scholar 

  19. Karthikaiselvi R, Subhashini S, Rajalakshmi R (2012) Poly (vinyl alcohol–aniline) water soluble composite as corrosion inhibitor for mild steel in 1 M HCl. Arab J Chem 5(4):517–522

    Article  CAS  Google Scholar 

  20. Ozcan M, Solmaz R, Kardas G, Dehri I (2008) Adsorption properties of barbiturates as green corrosion inhibitors on mild steel in phosphoric acid. Physicochem Eng Asp 325(1–2):57–63

    Article  CAS  Google Scholar 

  21. Tavakoli H, Shahrabi T, Hosseini MG (2008) Synergistic effect on corrosion inhibition of copper by sodium dodecylbenzenesulphonate (SDBS) and 2-mercaptobenzoxazole. Mater Chem Phys 109(2–3):281–286

    Article  CAS  Google Scholar 

  22. Feng Y, Siow KS, Teo WK, Hsieh AK (1999) The synergistic effects of propargyl alcohol and potassium iodide on the inhibition of mild steel in 0.5 M sulfuric acid solution. Corros Sci 41(5):829–852

    Article  CAS  Google Scholar 

  23. Umoren SA, Obot IB, Ebenso EE, Obi-Egbedi NO (2009) The Inhibition of aluminium corrosion in hydrochloric acid solution by exudate gum from Raphia hookeri. Desalination 250(1–3):561–572

    Article  Google Scholar 

  24. Shukla SK, Singh AK, Ahamad I, Quraishi MA (2009) Streptomycin: a commercially available drug as corrosion inhibitor for mild steel in hydrochloric acid solution. Mater Lett 63(9–10):819–822

    Article  CAS  Google Scholar 

  25. Singh A, Ahamad I, Singh VK, Quraishi MA (2011) Inhibition effect of environmentally benign Karanj (Pongamia pinnata) seed extract on corrosion of mild steel in hydrochloric acid solution. J Solid State Electrochem 15(6):1087–1097

    Article  CAS  Google Scholar 

  26. Szauer T, Brandt A (1981) On the role of fatty acid in adsorption and corrosion inhibition of iron by amine—fatty acid salts in acidic solution. Electrochim Acta 26(9):1257–1260

    Article  Google Scholar 

  27. Khaled KF (2003) The inhibition of benzimidazole derivatives on corrosion of iron in 1 M HCl solutions. Electrochim Acta 48(17):2493–2503

    Article  CAS  Google Scholar 

  28. Behpour M, Ghoreishi SM, Soltani N, Salavathi-Niasari M (2008) Electrochemical and theoretical investigation on the corrosion inhibition of mild steel by thiosalicylaldehyde derivatives in hydrochloric acid solution. Corros Sci 50(8):2172–2181

    Article  CAS  Google Scholar 

  29. Ahamad I, Prasad R, Quraishi MA (2010) Adsorption and inhibitive properties of some new Mannich bases of Isatin derivatives on corrosion of mild steel in acidic media. Corros Sci 52(4):1472–1481

    Article  CAS  Google Scholar 

  30. Raja PB, Sethuraman MG (2008) Inhibitive effect of black pepper extract on the sulphuric acid corrosion of mild steel. Mater Lett 62(17–18):2977

    Article  Google Scholar 

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Ragul, R., Ravichandran, J. & Murugesh, A. Adsorption and Inhibitive Action of Mitracarpus Hirtus Extract Towards the Corrosion of Mild Steel in H2SO4 Medium. J Bio Tribo Corros 6, 65 (2020). https://doi.org/10.1007/s40735-020-00360-z

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  • DOI: https://doi.org/10.1007/s40735-020-00360-z

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