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Investigation on the Functionally Graded Properties of Zn–6MgO–12MnO2 Composite Coating Fabricated by Dual Anode Electrolytic Deposition Technique

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Abstract

The effect of MnO2 particulates on Zn–MgO composite prepared via electrocodeposition route on low carbon steel was investigated. The experiment was conducted at constant current density of 11.2 A cm−2. The microstructural properties of the coated surfaces were characterized using high-resolution Nikon Optical Microscope (OPM) and scanning electron microscopy attached with energy-dispersive spectrometer (SEM/EDX). The corrosion behaviour was examined using linear polarization method in 3.5% NaCl-simulated seawater environment. The micro-hardness features of the electrodeposits were analyzed by dura scan hardness tester. The homogenizing and thermal stability of the fabricated composite was determined at 200 °C for 4 h. The results show that the structural performance and corrosion resistance property of the coating is dependent on the dispersion strengthening of the particle incorporation. The micro-hardness of the deposited samples increased with the increased addition of MnO2 with over 90%. The improvement in the micro-hardness of the deposited samples suggests that MnO2 has a strengthening effect on the mild steel.

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References

  1. Praveen BM, Venkatesha TV (2008) Electrodeposition and properties of Zn-nanosized TiO2 composite coatings. Appl Surf Sci 254:2418–2424

    Article  CAS  Google Scholar 

  2. Chuen-Chang L, Chi-Ming H (2006) Zinc-nickel alloy coatings electrodeposited by pulse current and their corrosion behavior. J Coat Technol Res 3:99–104

    Article  Google Scholar 

  3. Callister WD Jr (2008) Materials science and engineering, vol 5. Wiley, New York, pp 400–736

    Google Scholar 

  4. ASM handbook, friction, lubrication, and wear technology, U.S.A. 18 (1992) 713

  5. Daniyan AA, Umoru LE, Popoola API, Fayomi OSI (2017) Results Phys 7:3222–3229

    Article  Google Scholar 

  6. Axen N, Alahelisten A, Jacobson S (1994) Abrasive wear of alumina fibre-reinforced aluminium. Wear 173:95–104

    Article  CAS  Google Scholar 

  7. Favier F, Belanger D, Simon P (2007) Long-term cycling behavior of asymmetric activated carbon/MnO2 aqueous electrochemical supercapacitor. J. Power Sources 173:633

    Article  Google Scholar 

  8. Kwok CT, Cheng FT, Man HC (2006) Cavitation erosion and corrosion behaviors of laser-aluminized mild steel. J Surf Coat Technol 200:3544

    Article  CAS  Google Scholar 

  9. Lin CK, Chuang KH, Lin CY, Tsay CY, Chen CY (2007) Manganese oxide films prepared by sol–gel process for supercapacitor application. Surf Coat Technol 202:1272

    Article  CAS  Google Scholar 

  10. Chang JK, Tsai WT (2003) Material characterization and electrochemical performance of hydrous manganese oxide electrodes for use in electrochemical pseudocapacitors. J Electrochem Soc 150:A1333

    Article  CAS  Google Scholar 

  11. Nam KW, Kim KB (2006) Manganese oxide film electrodes prepared by electrostatic spray deposition for electrochemical capacitors. J Electrochem Soc 153:A81

    Article  CAS  Google Scholar 

  12. Pang SC, Anderson MA, Chapman TW (2000) Novel electrode materials for thin‐film ultracapacitors: comparison of electrochemical properties of sol‐gel‐derived and electrodeposited manganese dioxide. J Electrochem Soc 147:444

    Article  CAS  Google Scholar 

  13. Athouel L, Moser F, Dugas R, Crosnier O, Belanger D, Brousse T (2008) Variation of the MnO2 birnessite structure upon charge/discharge in an electrochemical supercapacitor electrode in aqueous Na2SO4 electrolyte. J Phys Chem C 112:7270

    Article  Google Scholar 

  14. Daniyan AA, Umoru LE, Popoola API, Fayomi OSI (2017) Opto‐electrical and corrosion properties of electrocodeposited Zn‐TiO2/WO3‐ZnO‐SnO2 nanocomposite coatings. Mater Corros 69(6):725–735. https://doi.org/10.1002/maco.201709722

    Article  CAS  Google Scholar 

  15. Fayomi OSI, Popoola API, Loto CA (2014) Tribo-mechanical investigation and anti-corrosion properties of Zn-TiO2 thin film composite coatings from electrolytic chloride bath. Int J Electrochem Sci 9:3885–3903

    Google Scholar 

  16. Fayomi OSI, Popoola API (2014) Study of Al2O3/SiC particle loading on the microstructural strengthening characteristics of Zn–Al2O3–SiC matrix composite coating. Egypt J Basic Appl Sci 1:120

    Article  Google Scholar 

  17. Daniyan AA, Fayomi OSI, Umoru LE, Popoola API (2018) Effect of current density and ZnO nano particles influence on the microstructure and mechanical strengthening properties of Zn-TiO2-ZnO alloys at constant deposition time. Int J Mater Eng Innov 9(1):34–45

    Article  Google Scholar 

  18. Fayomi OSI, Joseph OO, Mubiayi MP, Durodola BM, Gabriel O (2016) Microstructural evolution and characterization of super-induced MgO composite on zinc-rich coatings. Egypt J Basic Appl Sci 3(1):1–9

    Article  Google Scholar 

  19. Fayomi OSI, Popoola API, Inegbenebor AO (2014) Multiple loading and mechanical response of Al6O13Si2–ZrO2/Zn composite coating. Results Phys 4:79–80

    Article  Google Scholar 

  20. Ngaotrakanwiwat P, Saitoh S, Ohko Y, Tatsuma A, Fujishima A (2003) TiO2-phosphotungstic acid photocatalysis systems with an energy storage ability. J. Electrochem. Soc. 150:1405

    Article  Google Scholar 

  21. Popoola API, Daniyan AA, Umoru LE, Fayomi OSI (2017) Effect of WO3 nanoparticle loading on the microstructural, mechanical and corrosion resistance of Zn matrix/TiO2-WO3 nanocomposite coatings for marine application. J Mar Sci Appl 16(1):102–109. https://doi.org/10.1007/s11804-017-1389-7

    Article  Google Scholar 

  22. Daniyan AA, Fayomi OSI, Umoru LE, Popoola API (2018) Structural evolution, optoelectrical and corrosion properties of electrodeposited WO3 integration on Zn-TiO2 electrolyte for defence super application. Def Technol 14(2018):396–402

    Article  Google Scholar 

  23. Ogundare O, Babatope B, Adetunji AR, Olusunle SOO (2012) Atmospheric corrosion studies of ductile iron and austenitic stainless steel in an extreme marine environment. J Miner Mater Charact Eng 11:914

    Google Scholar 

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Acknowledgements

The authors acknowledge the support from Surface Engineering Research Centre (SERC), Tshwane University of Technology, and Pretoria, South Africa.

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Correspondence to O. S. I. Fayomi.

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Fayomi, O.S.I., Daniyan, A.A., Popoola, A.P.I. et al. Investigation on the Functionally Graded Properties of Zn–6MgO–12MnO2 Composite Coating Fabricated by Dual Anode Electrolytic Deposition Technique. J Bio Tribo Corros 5, 102 (2019). https://doi.org/10.1007/s40735-019-0295-8

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  • DOI: https://doi.org/10.1007/s40735-019-0295-8

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