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Effect of Temperature and Acid Concentration on Rhizophora mucronata Tannin as a Corrosion Inhibitor

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Abstract

The effect of temperature and acid concentration on a newly formulated tannin as a corrosion inhibitor for carbon steel in oil and gas facilities was investigated. Corrosion rate of carbon steel in HCl acid solutions (0, 5, 10, 15, 20, 25 and 30%) by Rhizophora mucronata tannin (RMT) was studied using chemical (weight loss method) and spectroscopic (FTIR) techniques at various temperatures in the ranges of 26–70 °C. At 20% optimum concentration of acid, the FTIR result showed the presence of hydroxyl group, aromatic group, esters and the substituted benzene group, indicating the purity of the tannin. The increase in HCl acid concentration and temperature increased the corrosion rate, but the rate of corrosion was mild with RMT. Therefore, the use of RMT as a cost-effective and environmental-friendly corrosion-inhibiting agent for carbon steel is herein proposed.

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References

  1. Ituen E, Akaranta O, James A (2016) Green anticorrosive oil field chemical from 5-hydroxytryptophan and synergistic additives for X80 steel surface protection in acidic oil well treatment fluid. J Mol Liq 224:408–419

    Article  Google Scholar 

  2. Deyab M (2007) Effect of cationic surfactant and inorganic anions on the electrochemical behaviour of carbon steel in formation water. Corros Sci 49:2315

    Article  Google Scholar 

  3. Cheng S, Chen S, Liu T, Chang X, Yin Y (2007) Carboxylmethylchitosan +Cu2+ Mixture as an inhibitor used for mild steel in 1 M HCl. Electrochem Acta 52(19):5932–5938

    Article  Google Scholar 

  4. Daoud D, Daoud T, Issaadi S, Chafaa S (2014) Adsorption and corrosion inhibition of new synthesized thiophene schiff base on mild steel X52 in HCl and H2SO4 solution. Corros Sci 79:50

    Article  Google Scholar 

  5. Berger MN, Boocock G, Harward RN (1969) Polymerization of olefins by ziegler catalysts. Adv Catal 19:211–240

    Google Scholar 

  6. Daminov A, Ragulin V (2006). Mechanical formation of corrosion damage of inter equipment in wells by continuous scale-inhibitor dosing utilizing surface dosing system: testing scale and corrosion inhibitor. Paper SPE-100476 presented at the SPE international oil field corrosion symposium. 30th May

  7. Grassino A, Halambek J, Djakovic S, Brncic S (2015) Utilization of tomatoes peel waste from canning factory as a potential source of pectin production and application as a tin corrosion inhibitor. Food Hydrocoll 52:265–274

    Article  Google Scholar 

  8. Chauhan L, Gunasekaran G (2006) Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corros Sci 49:1143–1161

    Article  Google Scholar 

  9. Okafor PC, Ikpi ME, Uwah IE, Ebenso EE, Ekpe UJ, Umoren SA (2008) Inhibitory action of Phyllantus amarus extract on the corrosion of mild steel in acidic media. Corros Sci 50:2310–2317

    Article  Google Scholar 

  10. Oguzie E (2008) Evaluation of the inhibitive effect of some plant extracts on the acid corrosion of mild steel. Corros Sci 50:2993–2998

    Article  Google Scholar 

  11. Shyamala M, Arulanantham A (2008) Eclipta alba as corrosion pickering inhibitor on mild steel in hydrochloric acid. J Mater Sci Technol 25(5):633–636

    Google Scholar 

  12. Ostovari A, Hoseinieh S, Peikari M, Shadizadeh S, Hashemi S (2009) Corrosion inhibition of mild steel in 1 M HCl solution by henna extract: a comparative study of the inhibition of henna and its constituents. Corros Sci 51:1935–1941

    Article  Google Scholar 

  13. Satapathy A, Gunasekaran G, Sahoo S, Amit K, Rodrigues P (2009) Corrosion Inhibition of Justicia gendarussa Plant Extract in Hydrochloric Acid Solution. Corros Sci 51:2848–2856

    Article  Google Scholar 

  14. Umoren S, Eduok U, Solomon M, Udoh A (2011) Corrosion inhibition by leaves and stem extract of sida acuta for mild steel in 1 M H2SO4 solutions investigated by chemical and spectroscopic technique. Arab J Chem 9:S209–S224

    Article  Google Scholar 

  15. Al-Sahlanee H, Sultan A, Al-Faize M (2013) Corrosion inhibition of carbon steel in 1 M HCl solution using Sesbania sesban extract. Aquat Sci Technol 1(2):135–151

    Google Scholar 

  16. Arockiasamy P, Sheela X, Thenmozhi G, Franco M, Sahayaraj J, Santhi R (2014). Evaluation of corrosion inhibition of mild steel in 1 M hydrochloric acid solution by Mollugo cerviana. Int J Corros 1–7

  17. Hussin M, Kassim M, Razali N, Dahon N, Nasshorudin D (2011) The effect of tinospora crispa extract as a natural mild steel corrosion inhibitor in 1 M HCl. Mater Chem Phys 125:461–468

    Article  Google Scholar 

  18. Hussin M, Rahim A, Ibrahim M, Brosse N (2015) The capacity of ultra filtered alkaline and organosolv oil palm (Elaeis guineensis) fronds lignin as a green corrosion inhibitor for mild steel in 05 M HCl solution. Measurement 78:90–103

    Article  Google Scholar 

  19. Aribo S, Olusegun S, Ibhadiyi L, Oyetunji A, Folorunso D (2016) Green inhibitor for corrosion protection in acidizing oilfield environment. J Assoc Arab Univ Basic Appl, Sci

    Google Scholar 

  20. El-Etre AY, Ali AI (2017) A novel new inhibitor for C-steel corrosion in 2.0 mol. L−1 hydrochloric acid solution. Chin J Chem Eng 25:373–380

    Article  Google Scholar 

  21. Raghavendra N, Bhat J (2017) Chemical and electrochemical studies on the areca fat as a novel and sustainable corrosion inhibitor for industrially important material in hostile fluid environments. J Bio Tribo Corros 3:12

    Article  Google Scholar 

  22. Martinez S, Stagljar I (2003) Correlation between the molecular and the corrosion inhibition efficiency of chestnut tannin in acidic solution. J Mol Struct Theochem 640:167–174

    Article  Google Scholar 

  23. Rahim A, Rocca E, Steinmetz J, Ibrahim M (2007) Mangrove tannins and their flavoured monomers as alternative steel corrosion inhibitors in acid medium. Corros Sci 49:402–417

    Article  Google Scholar 

  24. Rahim A, Kassim M, Rocca E, Steinmetz J (2011) Mangrove (Rhizophora apiculata) tannin: an eco-friendly rust converter. Corros Eng, Sci Technol 46(4):425–431

    Article  Google Scholar 

  25. Shah A, Rahim A, Yahya S, Raja B (2011) Acid corrosion inhibition of copper by mangrove tannin. Pigment Resin Technol 40(2):118–122

    Article  Google Scholar 

  26. Shah A, Rahim A, Hamid S, Yahya M (2013) Green inhibitor for copper corrosion by mangrove tannin. Int J Electrochem Sci 8:2140–2153

    Google Scholar 

  27. Nik WB, Hajar HM, Idora M, Suriani M, Yakubi A (2015) Effect of mangrove bark condensed tannins (Rhizophora apiculata) as corrosion inhibitor for mild steel in simulated splash zone. J Sci Res Dev 2(13):59–63

    Google Scholar 

  28. Peres R, Cassel E, Azambuja S (2012). Black wattle tannin as steel corrosion inhibitor. Int Sch Res Netw 9

  29. Oki M, Charles E, Alaka C, Oki T (2011) Corrosion inhibition of mild steel in hydrochloric acid by tannins from Rhizophora racemosa. Mater Sci Appl 2:592–595

    Google Scholar 

  30. Brown A, Ko H (1997) Black wattle and its utilization. Rural Industrial Research and Development Cooperation, Barton

    Google Scholar 

  31. Mabrour J, Aksirra M, Azzi M (2004) Effect of vegetal tannin on anodic copper dissolution in chloride solution. Corros Sci 46(8):1833–1846

    Article  Google Scholar 

  32. Yahya S, Shah A, Rahim A, Aziz A, Roslan R (2008) Phase transformation of rust in the presence of various tannin. J Phys Sci 19(1):31–41

    Google Scholar 

  33. Rahim A, Rocca E, Steinmetz J, Kassim M (2008) Inhibitive action of mangrove tannins and phosphoric acid on pre-rusted steel via electrochemical methods. Corros Sci 50:1546–1550

    Article  Google Scholar 

  34. Hill DG, Romijn H (2000) Reduction of risk to the marine environment from oil field chemicals environmentally improved acid corrosion inhibition for well stimulation. NACE International Corrosion Paper No.00342, Orlando, Florida, 26–31 March

  35. Smith C, Dollarhide F, Byth M (1978) Acid corrosion inhibitor: are we getting what we need? J Petrol Technol 30:737–746

    Article  Google Scholar 

  36. Loo AY, Jain K, Darah I (2008) Antioxidant activity of compound isolated from the pyroligneous acid, Rhizophora apiculata. Food Chem 107:1151–1160

    Article  Google Scholar 

  37. Horsup DI, Clark JC, Binks BP, Fletcher PD, Hicks JT (2010) The faith of oil field corrosion inhibitors in multiphase system. Corrosion 66 (3)

  38. Finsgar M, Jackson J (2014) Application of corrosion inhibitor for steel in acidic media for oil and gas industry: a review. Corros Sci 86:17–41

    Article  Google Scholar 

  39. Papavinasam S, Revie R, Attard M, Demoz A, Michaelian K (2003) Comparison of technique for monitoring. Corrosion 59:1096–1111

    Article  Google Scholar 

  40. Khadom A, Yaro A, Kadum A (2009) The effect of temperature and acid concentration on corrosion of mild steel in hydrochloric acid medium. Am J Appl Sci 6(7):1403–1409

    Article  Google Scholar 

  41. Emran K (2013) Effect of concentration and temperature on the corrosion properties of Fe–Ni–Mn Alloy in HCl solutions. Res Chem Intermed 41:3583–3596

    Article  Google Scholar 

  42. Haynes GS, Baboian R (1990) Review of laboratory corrosion test and standards. Phila ASTM Spec Tech Publ 1000:505–509

    Google Scholar 

  43. Gust J (1991) Application of infrared spectroscopy for investigation of rust phase component conversion by agents containing oak tannin and phosphoric acid. Corrosion 47(6):453–457

    Article  Google Scholar 

  44. Hoong Y, Paridaha M, Luqman C, Koh M, Loh Y (2009) Fortification of sulfited tannin from the bark of Acacia mangium with phenol-formaldehyde for use as plywood adhesive. Ind Crops Prod 30:416–421

    Article  Google Scholar 

  45. Socrates G (2001) Infrared and Raman characteristics group frequency: tables and charts. Wiley, Chichester

    Google Scholar 

  46. Hinggins RA (2004) Engineering metallurgy applied physical metallurgy. Vinod Vasishtha for Viva Books Private Limited, New Delhi

    Google Scholar 

  47. Ogundare O, Momoh I, Akinribide O, Adetunji A, Borode J, Olusunle S, Adewoye O (2012) Comparative study of corrosion sensitivity of ferrous metals in crude oil. J Miner Mater Charact Eng 11(6):559–568

    Google Scholar 

  48. Abdul A, Azim Sanad S (1972) Effect of acid concentration, C-content and temperature on the corrosion rate of steel in HCl. Corros Sci 12:313–324

    Article  Google Scholar 

  49. Abiola OK (2005) Adsorption of methionine on mild steel. J Chil Chem Soc 50:685–690

    Article  Google Scholar 

  50. Umoren S, Ogbobe O, Igwe I, Ebenso E (2008) Inhibition of mild steel corrosion in acidic medium using synthetic and natural occurring polymers and synthetic halide additives. Corros Sci 50:1998–2006

    Article  Google Scholar 

  51. Umoren S, Solomon S, Eduok U, Obot I, Israel A (2014) Inhibition of mild steel corrosion in H2SO4 solution by coconut coir dust extract obtained from different solvent systems and synergistic effect of iodine ions: ethanol and acetone extracts. J Environ Chem Eng 2:1048–1060

    Article  Google Scholar 

Download references

Acknowledgement

The authors would like to thank the Ministry of Higher Education (MOHE), Malaysia, and Universiti Teknologi Malaysia (UTM), for supporting this research through Research Management Grant Vot. No. Q. J30000.2546.14H50.

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Correspondence to Radzuan Junin.

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Agi, A., Junin, R., Zakariah, M.I. et al. Effect of Temperature and Acid Concentration on Rhizophora mucronata Tannin as a Corrosion Inhibitor. J Bio Tribo Corros 4, 5 (2018). https://doi.org/10.1007/s40735-017-0121-0

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  • DOI: https://doi.org/10.1007/s40735-017-0121-0

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