Abstract
Nanocomposites were synthesized via compocasting using Zn25Al3Si and Zn25Al3Si0.03Sr alloys as the matrices and nanoparticles of Al2O3 (1 wt%) as the reinforcement. Structure of the nanocomposites was examined, and their basic mechanical and tribological properties were tested. Distribution of primary silicon particles in the structure of nanocomposites has been improved compared to their distribution in the Zn25Al3Si matrix alloy due to the presence of Al2O3 nanoparticles and strontium. The primary silicon particles in the structure of the nanocomposites were found to be more fine-grained compared to the same particles in the structure of the as-cast Zn25Al3Si alloy. Tested mechanical properties of the nanocomposite with Zn25Al3Si alloy matrix are improved, compared to the matrix alloy. The nanocomposite with Zn25Al3Si0.03Sr alloy matrix is characterized with slightly higher value of compressive yield strength and a slightly lower hardness value compared to the as-cast Zn25Al3Si alloy. Both nanocomposites showed lower wear rate and higher coefficient of friction, compared to the matrix alloy, in sliding under the boundary lubricating regime. However, the nanocomposite with Zn25Al3Si alloy matrix showed better tribological properties than the nanocomposite with Zn25Al3Si0.03Sr alloy matrix.
Similar content being viewed by others
References
Prasad BK, Yegneswaran AH, Patwardhan AK (1996) Characterization of the wear response of a modified zinc-based alloy vis-à-vis a conventional zinc-based alloy and a bearing bronze at a high sliding speed. Metall Mater Trans A 27(11):3513–3523
Gervais E, Barnhurst RJ, Loong CA (1985) An analysis of selected properties of ZA alloys. J Met (JOM) 37(11):43–47
ASTM B 86 Standard specification for zinc and zinc-aluminum (ZA) alloy foundry and die castings
Ninković R, Babić M, Rac A (2000) Yugoslav Zn–Al alloys as bearings material. Tribol Ind 22(1–2):14–18
Lyon R (1985) High strength zinc alloys for engineering applications in motor cars. Met Mater 1:55–57
Murphy S, Savaskan T (1987) Metallography of zinc–25% Al based alloys in the as-cast and aged conditions. Pract Metallogr 24(5):204–221
Lee PP, Savaskan T, Laufer E (1987) Wear resistance and microstructure of Zn–Al–Si and Zn–Al–Cu alloys. Wear 117(1):79–89
Savaskan T, Murphy S (1987) Mechanical properties and lubricated wear of Zn–25Al-based alloys. Wear 116(2):211–224
Jian L, Laufer EE, Masounave J (1993) Wear in Zn–Al–Si alloys. Wear 165(1):51–56
Segawa T, Sato T, Kimura Y (1983) Effects of Al and Si of zinc alloys on the bearing performance under conditions of boundary lubrication. J Jpn Inst Met Mater 47(6):515–520 (in Japanese)
Zyska A, Konopka Z, Łągiewka M, Nadolski M (2011) Structure and selected properties of high-aluminium Zn alloy with silicon addition. Arch Foundry Eng 11(3):261–264
Prasad BK, Modi OP (2009) Slurry wear characteristics of zinc-based alloys: effects of sand content of slurry, silicon addition to alloy system and traversal distance. Trans Nonferrous Met Soc China 19(2):277–286
Savaşkan T, Pürçek G, Murphy S (2002) Sliding wear of cast zinc-based alloy bearings under static and dynamic loading conditions. Wear 252(9–10):693–703
Vencl A, Bobić I, Vučetić F, Bobić B, Ružić J (2014) Structural, mechanical and tribological characterization of Zn25Al alloys with Si and Sr addition. Mater Des 64:381–392
Berent K, Pstruś J, Gancarz T (2016) Thermal and microstructure characterization of Zn–Al–Si alloys and chemical reaction with Cu substrate during spreading. J Mater Eng Perform 25(8):3375–3383
Choi H, Konishi H, Li X (2012) Al2O3 nanoparticles induced simultaneous refinement and modification of primary and eutectic Si particles in hypereutectic Al–20Si alloy. Mater Sci Eng A 541:159–165
Choi H, Li X (2012) Refinement of primary Si and modification of eutectic Si for enhanced ductility of hypereutectic Al–20Si–4.5Cu alloy with addition of Al2O3 nanoparticles. J Mater Sci 47(7):3096–3102
De Cicco MP, Li X, Turng L-S (2009) Semi-solid casting (SSC) of zinc alloy nanocomposites. J Mater Process Technol 209(18–19):5881–5885
Aćimović-Pavlović Z, Raić KT, Bobić I, Bobić B (2011) Synthesis of ZrO2 particles reinforced ZA25 alloy composites by compocasting process. Adv Compos Mater 20(4):375–384
Lehuy H, Masounave J, Blain J (1985) Rheological behaviour and microstructure of stir-casting zinc-aluminium alloys. J Mater Sci 20(1):105–113
ASTM G 77 Standard test method for ranking resistance of materials to sliding wear using block-on-ring wear test
Flemings MC (1991) Behavior of metal alloys in the semisolid state. Metall Trans A 22(5):957–981
Rac A (1991) Basics of tribology. Faculty of Mechanical Engineering, University of Belgrade, Belgrade (in Serbian)
Hamrock BJ, Schmid SR, Jacobson BO (2004) Fundamental of fluid film lubrication. Marcel Dekker, New York
Rohatgi PK, Schultz B (2007) Lightweight metal matrix nanocomposites—stretching the boundaries of metals. Mater Matters 2(4):16–20
Casati R, Vedani M (2014) Metal matrix composites reinforced by nano-particles—a review. Metals 4(1):65–83
Casati R, Amadio M, Biffi CA, Dellasega D, Tuissi A, Vedani M (2013) Al/Al2O3 nano-composite produced by ECAP. Mater Sci Forum 762:457–464
Rohatgi PK, Moghadam AD, Schultz BF, Ferguson JB (2013) Synthesis and properties of metal matrix nanocomposites (MMnCs), syntactic foams, self lubricating and self-healing metals. In: Proceedings of the 8th Pacific Rim international conference on advanced materials and processing. Wiley, Hoboken, p 1515–1524
Kandeva-Ivanova M, Vencl A, Karastoyanov D (2016) Advanced tribological coatings for heavy-duty applications: case studies. Prof. Marin Drinov Publishing House of Bulgarian Academy of Sciences, Sofia
Acknowledgements
This work has been performed as a part of activities within the Projects OI 172005, TR 35021 and TR 35045. These projects are supported by the Republic of Serbia, Ministry of Education, Science and Technological Development, whose financial help is gratefully acknowledged. Petr Svoboda acknowledges the Project FSI-S-14-2336 from the Ministry of Education, Youth and Sports of Czech Republic.
Author information
Authors and Affiliations
Corresponding author
Additional information
Technical Editor: Paulo de Tarso Rocha de Mendonça, Ph.D.
Rights and permissions
About this article
Cite this article
Vencl, A., Bobić, B., Vučetić, F. et al. Effect of Al2O3 nanoparticles and strontium addition on structural, mechanical and tribological properties of Zn25Al3Si alloy. J Braz. Soc. Mech. Sci. Eng. 40, 513 (2018). https://doi.org/10.1007/s40430-018-1441-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s40430-018-1441-9