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Vacuum Recovery of Polyimide Films Damaged with High Energy Electron Radiation

  • Emerging Techniques in Space Domain Awareness
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Abstract

Ground- and space-based optical observations of space objects rely on knowledge about how spacecraft materials interact with light. In polymers, the changes in optical signature occur due to surface degradation caused by radiation induced chemical modification. This leads to altered reflectivity and deviation from a material’s expected absorption/transmission properties. The optical fingerprint of commonly used spacecraft materials changes continuously under space weather exposure. Laboratory observations have also shown that these changes in a material’s optical signature are to some degree transient. This work investigates the rate and degree of “optical healing” in vacuum and air exposure for electron damaged polyimide (PI) samples. Characterization of optical damage as a function of electron exposure and optical healing as a function of time in vacuum represents a major step toward a predictive model for optical characterization of space objects.

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References

  1. Zanoni, P., Burkhardt, J., Johann, U., Aspelmeyer, M., Kaltenbaek, R., Hechenblaikner, G.: Thermal performance of a radiatively cooled system for quantum optomechanical experiments in space. Appl. Therm. Eng. 107, 689 (2016)

    Article  Google Scholar 

  2. Gouzman, I., Grossman, E., Verker, R., Atar, N., Bolker, A., Eliaz, N.: Advances in polyimide-based materials for space applications. Adv. Mater. 31(18), 1807738 (2019)

    Article  Google Scholar 

  3. Mesforoush, H., Pakmanesh, M.R., Esfandiary, H., Asghari, S., Baniasadi, E.: Experimental and numerical analyses of thermal performance of a thin-film multi-layer insulation for satellite application. Cryogenics 102, 77–84 (2019)

    Article  Google Scholar 

  4. Griseri, V.: Polyimide used in space applications. In: Polyimide for Electronic and Electrical Engineering Applications. IntechOpen, London (2020)

  5. Plis, E.A., Engelhart, D.P., Cooper, R., Johnston, W.R., Ferguson, D., Hoffmann, R.: Review of radiation-induced effects in polyimide. Appl. Sci. 9(10), 1999 (2019)

    Article  Google Scholar 

  6. McKnight, D.: Examination of spacecraft anomalies provides insight into complex space environment. Acta Astronaut. 158, 172 (2019)

    Article  Google Scholar 

  7. Tribble, A.C.: The Space Environment: Implications for Spacecraft Design-Revised and Expanded Edition. Princeton University Press, Princeton (2020)

    Book  Google Scholar 

  8. Berger, M.J., Coursey, J.S., Zucker, M.A., Chang, J.: ESTAR, PSTAR, and ASTAR: Computer Programs for Calculating Stopping-Power and Range Tables for Electrons, Protons, and Helium Ions (Version 1.2.1). National Institute of Standards and Technology, Gaithersburg (1999). http://physics.nist.gov/Star

  9. Jursa, A.S.: Laboratory USAFG. Handbook of Geos and the Space Environment. Air Force Geophysics Laboratory, Air Force Systems Command, U.S. Air Force (1985)

  10. Ginet, G., O’Brien, T., Huston, S., Johnston, W., Guild, T., Friedel, R., Lindstrom, C.D., Roth, C.J., Whelan, P., Quinn, R.A., Madden, D., Morley, S., Su, Y.J.: AE9, AP9 and SPM: new models for specifying the trapped energetic particle and space plasma environment. Space Sci. Rev. 179(1–4), 579–615 (2013)

    Article  Google Scholar 

  11. Laghari, J.R., Hammoud, A.N.: A brief survey of radiation effects on polymer dielectrics. IEEE Trans. Nucl. Sci. 37(2), 1076 (1990)

    Article  Google Scholar 

  12. Engelhart, D.P., Plis, E., Humagain, S., Greenbaum, S., Ferguson, D., Cooper, R., Hoffmann, R.: Chemical and electrical dynamics of polyimide film damaged by electron radiation. IEEE Trans. Plasma Sci. 45, 2573 (2017)

    Article  Google Scholar 

  13. Rahnamoun, A., Engelhart, D.P., Humagain, S., Koerner, H., Plis, E., Kennedy, W.J., Cooper, R., Greenbaum, S.G., Hoffmann, R., van Duin, A.C.: Chemical dynamics characteristics of Kapton polyimide damaged by electron beam irradiation. Polymer 176, 135–145 (2019)

    Article  Google Scholar 

  14. Humagain, S., Johnson, J., Stallworth, P., Engelhart, D., Plis, E., Ferguson, D., Cooper, R., Hoffmann, R., Greenbaum, S.: Study of damage and recovery of electron irradiated polyimide using EPR and NMR spectroscopy. In: APS March Meeting Abstracts 2017 H28-014 (2017)

  15. Li, R., Li, C., He, S., Di, M., Yang, D.: Radiation effect of keV protons on optical properties of aluminized Kapton film. Radiat. Phys. Chem. 76(7), 1200–1204 (2007)

    Article  Google Scholar 

  16. Plis, E.A., Engelhart, D.P., Cooper, R., Ferguson, D.C., Hoffmann, R.: Effect of environment on charge transport properties of polyimide films damaged by high-energy electron radiation. J. Vac. Sci. Technol. B 36(5), 52906 (2018)

    Article  Google Scholar 

  17. Amiour, N., Ziari, Z., Sahli, S.: Traps energy distribution in Kapton HN polyimide films through surface potential decay model under humidity conditions. J. Electrostat. 109, 103551 (2021)

    Article  Google Scholar 

  18. Plis, E., Engelhart, D.P., Cooper, R., Humagain, S., Brunetti, M., Koch, A., Greenbaum, S., Ferguson, D., Hoffmann, R.: Effect of atmosphere on recovery dynamics of polyimide film damaged by electron radiation. IOP Conf. Ser. Mater. Sci. Eng. 239(1), 012015 (2017)

    Article  Google Scholar 

  19. Bovey, F.A.: The Effect of Ionizing Radiation on Natural and Synthetic High Polymers. Interscience, New York (1958)

    Google Scholar 

  20. Plis, E., Engelhart, D.P., Barton, D., Cooper, R., Ferguson, D., Hoffmann, R.: Degradation of polyimide under exposure to 90 keV electrons. Phys. Status Solidi B 254(7), 1600819 (2017)

    Article  Google Scholar 

  21. Engelhart, D.P., Plis, E.A., Cooper, R., Cowardin, H., Maxwell, J., Ferguson, D., Schiefer, S., Hoffmann, R.: Optical degradation and recovery of multilayer insulation in a simulated GEO environment. IAC-18, A6, IP, 40, x46936. In: 69th International Astronautical Congress (IAC), Bremen, Germany (2018)

  22. Abercromby, K., Hamada, K., Guyote, M., Okada, J., Barker, E.S.: Remote and ground truth spectral measurement comparisons of FORMOSAT III. In: Advanced Maui Optical and Space Surveillance Technologies Conference, Maui, USA (2007)

  23. Seitzer, P., Lederer, M.M., Cowardin, H., Barker, E.S., Abercromby, K.J.: Visible light spectroscopy of GEO debris. In: Advance Maui Optical and Space Surveillance Technologies Conference, Maui, USA (2012)

  24. Cooper, R., Hoffmann, R.: Jumbo Space Environment Simulation and Spacecraft Charging Chamber Characterization. Air Force Report No. AFRL-RV-PS-TP-2015-0012. Air Force Research Laboratory, Albuquerque (2015)

  25. Bengtson, M., Maxwell, J., Hoffman, R., Cooper, R., Schieffer, S., Ferguson, D., Cowardin, H., Plis, E., Engelhart, D.: Optical characterization of commonly used spacecraft paints in a simulated GEO electron environment. In: Advanced Maui Optical and Space Surveillance Technologies Conference, Maui, USA (2018)

  26. Sloan Digital Sky Survey. http://www.sdss.org/dr12/algorithms/ugrizvegasun/

  27. Reyes, J.A., Cowardin, H.M.: Spectral characterization of spacecraft materials used in hypervelocity impact testing. In: Algorithms, Technologies, and Applications for Multispectral and Hyperspectral Imaging XXVII, 12 April 2021, vol. 11727, p. 117271G. International Society for Optics and Photonics

  28. Ishida, H., Wellinghoff, S.T., Baer, E., Koenig, J.L.: Spectroscopic studies of poly[N, N′-bis(phenoxyphenyl)pyromellitimide]. 1. Structures of the polyimide and three model compounds. Macromolecules 13, 826–834 (1980)

    Article  Google Scholar 

  29. LaFemina, J.P., Arjavalingam, G., Hougham, G.: Electronic structure and ultraviolet absorption spectrum of polyimide. J. Chem. Phys. 90, 5154–5160 (1989)

    Article  Google Scholar 

  30. Burke, M., Dawson, C., Allen, C.S., Brum, J., Roberts, J., Krekeler, M.P.S.: Reflective spectroscopy investigations of clothing items to support law enforcement, search and rescue, and war crime investigations. Forensic Sci. Int. 304, 109945 (2019)

    Article  Google Scholar 

  31. George, M.A., Ramakrishna, B.L., Glaunsinger, W.S.: Electron paramagnetic resonance investigation of free radicals in poiyimide films. J. Phys. Chem. 94, 5159 (1990)

    Article  Google Scholar 

  32. Wu, Y., Sun, C., Xiao, J., Li, R., Yang, D., He, S.: A study on the free-radical evolution and its correlation with the optical degradation of 170 keV proton-irradiated polyimide. Polym. Degrad. Stab. 95, 1219 (2010)

    Article  Google Scholar 

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Acknowledgements

This work was partially supported by Air Force Office of Scientific Research, Remote Sensing and Imaging Physics Portfolio (Dr. Michael Yakes) Grant 20RVCOR024. Authors also would like to thank Mr. Timothy R. Scott from DuPont de Nemours, Inc., for providing polyimide materials for this research.

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Correspondence to Elena A. Plis.

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This article belongs to the Topical Collection: Emerging Techniques in Space Domain Awareness.

Guest Editors: Elena Plis, Daniel P. Engelhart, Ryan C. Hoffmann, Vishnu Reddy, Roberto Furfaro, James Frith.

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Plis, E.A., Engelhart, D.P., Murray, V.G. et al. Vacuum Recovery of Polyimide Films Damaged with High Energy Electron Radiation. J Astronaut Sci 69, 1250–1261 (2022). https://doi.org/10.1007/s40295-022-00336-w

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