Abstract
Topological supramolecular polymers are responsible for design of innovative materials with unique physical properties but remain a challenging task to prepare by means of supramolecular polymerization. In this contribution, we present a novel method of region-confined amphiphilic supramolecular polymerization (RASP) in a controllable two-step self-organization pathway, which was certified by a new type of pyridine-oxadiazole alternating 48-membered macrocycles with structurally regional distribution of distinct self-assembling groups that can self-organize into circular supramolecular architectures. Meanwhile, water molecule plays a crucial role in RASP, and the water content in nonpolar solvent chloroform is sensitive to trigger controllable amphiphilic self-organization. Moreover, differing from the traditional rodlike micelles formed by self-assembly of linearly amphiphilic molecules, this approach of RASP exclusively gives rise to the formation of circularly assembled supramolecular polymers.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Yang L., Tan X., Wang Z., Zhang X., Chem. Rev., 2015, 115, 7196
Clemons T. D., Stupp S. I., Prog. Polym. Sci., 2020, 111, 101310
Guo D. S., Liu Y., Chem. Soc. Rev., 2012, 41, 5907
Hashim P. K., Bergueiro J., Meijer E. W., Aida T., Prog. Polym. Sci., 2020, 105, 101250
Qin B., Yin Z., Tang X., Zhang S., Wu Y., Xu J.-F., Zhang X., Prog. Polym. Sci., 2020, 100, 101167
Yagai S., Kitamoto Y., Datta S., Adhikari B., Acc. Chem. Res., 2019, 52, 1325
Fenniri H., Packiarajan M., Vidale K. L., Sherman D. M., Hallenga K., Wood K. V., Stowell J. G., J. Am. Chem. Soc., 2001, 123, 3854
Percec V., Dulcey A. E., Balagurusamy V. S. K., Miura Y., Smidrkal J., Peterca M., Nummelin S., Edlund U., Hudson S. D., Heiney P. A., Duan H., Magonov S. N., Vinogradov S. A., Nature, 2004, 430, 764
Shimizu T., Masuda M., Minamikawa H., Chem. Rev., 2005, 105, 1401
Huang Z., Kang S. K., Banno M., Yamaguchi T., Lee D., Seok C., Yashima E., Lee M., Science, 2012, 337, 1521
Fukino T., Joo H., Hisada Y., Obana M., Yamagishi H., Hikima T., Takata M., Fujita N., Aida T., Science, 2014, 344, 499
Beingessner R. L., Fan Y., Fenniri H., RSC Adv., 2016, 6, 75820
Yashima E., Ousaka N., Taura D., Shimomura K., Ikai T., Maeda K., Chem. Rev., 2016, 116, 13752
Ghadiri M. R., Granja J. R., Milligan R. A., Mcree D. E., Khazanovich N., Nature, 1993, 366, 324
Kim Y., Kang J., Shen B., Wang Y., He Y., Lee M., Nat. Commun., 2015, 6, 8650
Hirschberg J. H. K. K., Brunsveld L., Ramzi A., Vekemans J. A. J. M., Sijbesma R. P., Meijer E. W., Nature, 2000, 407, 167
Zhang C., Deng X., Wang C., Bao C., Yang B., Zhang H., Qi S., Dong Z., Chem. Sci., 2019, 10, 8648
Suzuki A., Aratsu K., Datta S., Shimizu N., Takagi H., Haruki R., Adachi S. I., Hollamby M., Silly F., Yagai S., J. Am. Chem. Soc., 2019, 141, 13196
Kim J. K., Lee E., Huang Z. G., Lee M., J. Am. Chem. Soc., 2006, 128, 14022
Shen B., Zhu Y., Kim Y., Zhou X., Sun H., Lu Z., Lee M., Nat. Commun., 2019, 10, 1080
Datta S., Kato Y., Higashiharaguchi S., Aratsu K., Isobe A., Saito T., Prabhu D. D., Kitamoto Y., Hollamby M. J., Smith A. J., Dalgliesh R., Mahmoudi N., Pesce L., Perego C., Pavan G. M., Yagai S., Nature, 2020, 583, 400
De Greef T. F., Smulders M. M., Wolffs M., Schenning A. P., Sijbesma R. P., Meijer E. W., Chem. Rev., 2009, 109, 5687
Korevaar P. A., George S. J., Markvoort A. J., Smulders M. M., Hilbers P. A., Schenning A. P., De Greef T. F., Meijer E. W., Nature, 2012, 481, 492
Ghadiri M. R., Granja J. R., Buehler L. K., Nature, 1994, 369, 301
Kim Y., Li, H., He Y., Chen X., Ma X., Lee M., Nat. Nanotechnol., 2017, 12, 551
Zhang K., Zha Y., Peng B., Chen Y., Tew G. N., J. Am. Chem. Soc., 2013, 135, 15994
Zhu J., Dong Z., Lei S., Cao L., Yang B., Li W., Zhang Y., Liu J., Shen J., Angew. Chem. Int. Ed., 2015, 54, 3097
Van Zee N. J., Adelizzi B., Mabesoone M. F. J., Meng X., Aloi A., Zha R. H., Lutz M., Filot I. A. W., Palmans A. R. A., Meijer E. W., Nature, 2018, 558, 100
Ogasawara M., Lin X., Kurata H., Ouchi H., Yamauchi M., Ohba T., Kajitani T., Fukushima T., Numata M., Nogami R., Adhikari B., Yagai S., Mater. Chem. Front., 2018, 2, 171
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Nos.92156012, 22071078) and the Program for Jilin University Science and Technology Innovative Research Team(JLUSTIRT), China(No.2019TD-36).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
DONG Zeyuan is a youth executive editorial board member for Chemical Research in Chinese Universities and was not involved in the editorial review or the decision to publish this article. The authors declare no conflicts of interest.
Supporting Information
40242_2023_3153_MOESM1_ESM.pdf
A General Approach for Synthesis of Circularly Assembled Supramolecular Polymers by means of Region-Confined Amphiphilic Supramolecular Polymerization
Rights and permissions
About this article
Cite this article
Zhang, L., Zhang, C., Min, J. et al. A General Approach for Synthesis of Circularly Assembled Supramolecular Polymers by Means of Region-confined Amphiphilic Supramolecular Polymerization. Chem. Res. Chin. Univ. 39, 736–740 (2023). https://doi.org/10.1007/s40242-023-3153-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-023-3153-7