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Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface

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Abstract

The direct polymerization via irreversible C-C coupling on inert substrates will give access to new low-dimensional advanced functional materials and simplify their industrial fabrication. In this work, we present our initial results in the application of Glaser coupling to the direct on-surface polymerization of a model diacetylene compound at the solid-vapor interface. The self-assembly of the monomer and polymerization products was characterized using scanning tunneling microscopy (STM). In addition, selected optical properties and the electronic structure of all compounds were investigated.

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Acknowledgements

This work was supported by the Natural Sciences and Engineering Research Council of Canada(NSERC) Discovery Grants, the National Natural Science Foundation of China(No.22102110), the Natural Science Foundation of Jiangsu Province, China(No.SBK2021040457) and the NSERC Scholarship(No.PDF-532834-2019).

CUCCIA Louis A. acknowledges NSERC and FQRNT and the multi-institutional Québec Center for Advanced Materials (QCAM) for financial support of this research.

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Authors and Affiliations

  1. Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano & Soft Materials(FUNSOM), Soochow University, Suzhou, 215123, P. R. China

    Yuan Fang, Nianyue Zhang & Oleksandr Ivasenko

  2. Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Québec, H3A 0B8, Canada

    Yuan Fang, Zahra Heydari, Chenghao Liu & Dmitrii F. Perepichka

  3. Division of Molecular Imaging and Photonics, Department of Chemistry, KU Leuven-University of Leuven, Celestijnenlaan 200F, B-3001, Leuven, Belgium

    Oleksandr Ivasenko

  4. Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St. W., Montreal, Québec, H4B 1R6, Canada

    Louis A. Cuccia

Authors
  1. Yuan Fang
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  2. Zahra Heydari
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  3. Chenghao Liu
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  4. Nianyue Zhang
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  5. Louis A. Cuccia
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  6. Oleksandr Ivasenko
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  7. Dmitrii F. Perepichka
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Corresponding authors

Correspondence to Yuan Fang, Oleksandr Ivasenko or Dmitrii F. Perepichka.

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Fang, Y., Heydari, Z., Liu, C. et al. Glaser Coupling of Substituted Anthracene Diynes on a Non-metallic Surface at the Vapor-Solid Interface. Chem. Res. Chin. Univ. 37, 1143–1148 (2021). https://doi.org/10.1007/s40242-021-1324-y

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  • DOI: https://doi.org/10.1007/s40242-021-1324-y

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