Skip to main content
SpringerLink
Log in

Effect of Sodium Concentration on the Synthesis of Faujasite by Two-step Synthesis Procedure

  • Article
  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

The relationship between the concentration of sodium cations and the properties of faujasite(FAU) zeolite was investigated using a two-step synthesis procedure including (1) formation of amorphous aluminosilicate precursors and separation of amorphous nanoparticles, and (2) transformation of these amorphous particles into zeolite crystals by treatment with alkali solutions(NaOH). Three representative samples including two nano-sized zeolites and one micron-sized zeolite were prepared using different concentrations of sodium hydroxide. The crystallization process of these zeolites was studied in detail by Fourier transform infrared(FTIR) spectrometry, nuclear magnetic resonance spectroscopy(NMR), X-ray diffraction(XRD), scanning electron microscopy (SEM), transmission electron microscopy(TEM), and N2 adsorption. The results indicated that minor changes in the concertation of inorganic cations can significantly shorten the induction period and crystallization time and thus affect the morphology, size and chemical composition of the zeolite crystals.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Liang J., Shan G., Sun Y., Renew. Sust. Energ. Rev., 2021, 139, 110707

    Article  CAS  Google Scholar 

  2. Rong H., Wang G., Yan J., Zou X., Zhu G., Sci. China Mater., 2021, 64(2), 374

    Article  CAS  Google Scholar 

  3. Hong M., Yu L., Wang Y., Zhang J., Chen Z., Dong L., Zan Q., Li R., Chem. Eng. J., 2019, 359, 363

    Article  CAS  Google Scholar 

  4. Kim J. Y., Oh H., Moon H. R., Adv. Mater., 2018, 31(20), 1805293

    Article  Google Scholar 

  5. Bacakova L., Vandrovcova M., Kopova I. Jirka I., Biomater. Sci., 2018, 6(5), 974

    Article  CAS  Google Scholar 

  6. Shen Y., Xu M., Li J., Qin Z., Wang C., Mintova S., Liu X., Inorg. Chem. Front., 2021, 8, 2144

    Article  CAS  Google Scholar 

  7. Sachse A., García-Martínez J., Chem. Mater., 2017, 29(9), 3827

    Article  CAS  Google Scholar 

  8. Cheng X., Mao J., Lv X., Hua T., Cheng X., Long Y., Tang Y., J. Mater. Chem. A., 2014, 2(5), 1247

    Article  CAS  Google Scholar 

  9. Rios C., Williams C., Fullen M., App. Clay Sci., 2009, 42, 446

    Article  CAS  Google Scholar 

  10. Novembre D., di Sabatino B., Gimeno D., Pace C., Clay Miner., 2011, 46(3), 339

    Article  CAS  Google Scholar 

  11. Otero Areán C., Rodríguez Delgado M., Turnes Palomino G., Tomás Rubio M., Tsyganenko N. M., Tsyganenko A. A., Garrone E., Micro. Meso. Mater., 2005, 80(1–3), 247

    Article  Google Scholar 

  12. Zhang G., Wang B., Zhang W., Li M., Tian Z., Dalton Trans., 2016, 45(15), 6634

    Article  CAS  Google Scholar 

  13. Cho Y., Lee J., Bokare A. D., Kwon S.-B., Park D.-S., Jung W.-S., Choi J. -S., Yang Y.-M., Lee J.-Y., Choi W., J. Ind. Eng. Chem., 2015, 22, 350

    Article  CAS  Google Scholar 

  14. Xu W., Zhang T., Bai R., Bai R., Zhang P., Yu J., J. Mater. Chem. A, 2020, 8(19), 9677

    Article  CAS  Google Scholar 

  15. Arbel Haddad M., Ofer-Rozovsky E., Bar-Nes G., Borojovich E. J. C., Nikolski D., Mogiliansky D., Katz A., J. Nucl. Mater., 2017, 493, 168

    Article  CAS  Google Scholar 

  16. Yokoi T., Yoshioka M., Imai H., Tatsumi T., Angew. Chem. Int. Ed., 2009, 48(52), 9884

    Article  CAS  Google Scholar 

  17. Majano G., Darwiche A., Mintova S., Valtchev V., Ind. Eng. Chem. Res., 2009, 48(15), 7084

    Article  CAS  Google Scholar 

  18. Majano G., Delmotte L., Valtchev V., Mintova S., Chem. Mater., 2009, 21(18), 4184

    Article  CAS  Google Scholar 

  19. Iyoki K., Kamimura Y., Itabashi K., Shimojima A., Okubo T., Chem. Lett., 2010, 39(7), 730

    Article  CAS  Google Scholar 

  20. Goel S., Wu Z., Zones S. I., Iglesia E., J. Am. Chem. Soc., 2012, 134(42), 17688

    Article  CAS  Google Scholar 

  21. Gatta G. D., Lee Y., Mineral. Mag., 2014, 78(2), 267

    Article  CAS  Google Scholar 

  22. Frising T., Leflaive P., Micro. Meso. Mater., 2008, 114(1–3), 27

    Article  CAS  Google Scholar 

  23. Rios C., Williams C., Fullen M., App. Clay Sci., 2009, 42(3/4), 446

    Article  CAS  Google Scholar 

  24. Guo H., Zhao L., Martineau-Corcos C., Fayon F., Viger-Gravel J., Awala H., Boullay P., Grand J., Vicente A., Gilson J.-P., Mintova S., Adv. Mater. Inter., 2021, 8(4), 2000634

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos.U1862118, 21975285, 21991091, 21991090, 21908246), the Fundamental Research Funds for the Central Universities, China(No.21CX06024A) and the Postgraduate Innovation Projects of China University of Petroleum(East China) (No.YCX2021053).

Author information

Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, Key Laboratory of Catalysis of China National Petroleum Corp. (CNPC), China University of Petroleum (East China), Qingdao, 266555, P. R. China

    Lei Zhao, Ge Yang, Hailing Guo, Chunzheng Wang, Lijuan Wang & Svetlana Mintova

  2. Laboratoire Catalyse et Spectrochimie(LCS), CNRS, ENSICAEN, Université de Caen, 6 boulevard du Maréchal Juin, 14050, Caen, France

    Svetlana Mintova

Authors
  1. Lei Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ge Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Hailing Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chunzheng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Lijuan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Svetlana Mintova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Hailing Guo or Svetlana Mintova.

Ethics declarations

The authors declare no conflicts of interest.

Electronic Supplementary Material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhao, L., Yang, G., Guo, H. et al. Effect of Sodium Concentration on the Synthesis of Faujasite by Two-step Synthesis Procedure. Chem. Res. Chin. Univ. 37, 1137–1142 (2021). https://doi.org/10.1007/s40242-021-1292-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-021-1292-2

Keywords

Search

Navigation