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Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives

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Abstract

Two isostructural metal-organic frameworks, [NO3][M3(H2O)3O(TBA)3]·2DMF·6H2O(1 and 2)[M=In and Fe, H2TBA=4-(1H-tetrazol-5-yl)-benzoic acid], have been successfully synthesized. Compounds 1 and 2 have three- dimensional structures bridged via the typical 6-connected tri-nuclear cluster units M3O(COO)6 and linear linker H2TBA. The whole 3D framework possesses a 6-connected acs topology. Notably, by the fluorescence technique, compound 1 can detect nitro explosives through fluorescence quenching effect, especially for 2,4,6-trinitrophenol(TNP, Ksv=3.64× 104 L/mol). Furthermore, the fluorescence spectrum red shifts as the number of −NO2 group increases. Based on the aforementioned consideration, compound 1 can be considered as a potential luminescent probe for the detection of TNP.

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References

  1. He Y. B., Chen F. L., Li B., Qian G. D., Zhou W., Chen B. L., Coord. Chem. Rev., 2018, 373, 167

    Article  CAS  Google Scholar 

  2. Adil K., Belmabkhout Y., Pillai R. S., Cadiau A., Bhatt P. M., Assen A. H., Maurin G., Eddaoudi M., Chem. Soc. Rev., 2017, 46, 3402

    Article  CAS  PubMed  Google Scholar 

  3. Fan C. B., Gong L. L., Huang L., Luo F., Krishna R., Yi X. F., Zheng A. M., Zhang L., Pu S. Z., Feng X. F., Luo M. B., Guo G. C., Angew. Chem., Int. Ed., 2017, 56, 7900

    Article  CAS  Google Scholar 

  4. Wang D. M., Liu B., Yao S., Wang T., Li G. H., Huo Q. S., Liu Y. L., Chem. Commun., 2015, 57, 15287

    Article  CAS  Google Scholar 

  5. Yao S., Wang D. M., Cao Y., Li G. H., Huo Q. S., Liu Y. L., J. Mater. Chem. A, 2015, 3, 16627

    Article  CAS  Google Scholar 

  6. Fan W. D., Liu X. P., Wang X., Li Y., Xing C. Y., Wang Y. T., Guo W. Y., Zhang L. L., Sun D. F., Inorg. Chem. Front, 2018, 5, 2445

    Article  CAS  Google Scholar 

  7. Zhang M. H., Xin X. L., Xiao Z. Y., Wang R. M., Zhang L. L., Sun D. F., J. Mater. Chem. A, 2017, 5, 1168

    Article  CAS  Google Scholar 

  8. Flores J. G., Sanchez-Gonzalez E., Gutierrez-Alejandre A., Aguilar-Pliego J., Martinez A., Jurado-Vazquez T., Lima E., Gonzalez-Zamora E., Diaz-Garcia M., Sanchez-Sanchez M., Ibarra I. A., Dalton Trans., 2018, 47, 4639

    Article  CAS  PubMed  Google Scholar 

  9. Li X. Y., Ma L. N., Liu Y., Hou L., Wang Y. Y., Zhu Z. H., ACS Appl. Mater. Interfaces, 2018, 10, 10965

    Article  CAS  PubMed  Google Scholar 

  10. Huang Y. B., Liang I., Wang X. S., Cao R., Chem. Soc. Rev, 2017, 46, 126

    Article  CAS  PubMed  Google Scholar 

  11. Zhao M., Ou S., Wu C. D., Acc. Chem. Res., 2014, 47, 1199

    Article  CAS  Google Scholar 

  12. Rao P. C., Mandal S., ChemCatChem, 2017, 9, 1172

    Article  CAS  Google Scholar 

  13. Coronado E., Minguez E. G., Chem. Soc. Rev, 2013, 42, 1525

    Article  CAS  PubMed  Google Scholar 

  14. Tan P., Xie X. Y., Liu X. Q., Pan T., Gu C., Chen P. F., Zhou J. Y., Pan Y. C., Sun L. B., J. Hazard Mater, 2017, 321, 344

    Article  CAS  PubMed  Google Scholar 

  15. Lustig W. P., Mukherjee S., Rudd N. D., Desai A. V., Li I., Ghosh S. K., Chem. Soc. Rev, 2017, 46, 3242

    Article  CAS  PubMed  Google Scholar 

  16. Kreno L. E., Leong K., Farha O. K., Allendorf M., Duyne R. P. V., Hupp J. T., Chem. Rev, 2012, 112, 1105

    Article  CAS  PubMed  Google Scholar 

  17. Cui Y. I., Yue Y. F., Qian G. D., Chen B. L., Chem. Rev, 2012, 112, 1126

    Article  CAS  PubMed  Google Scholar 

  18. Yan B., Acc. Chem. Res., 2017, 50, 2789

    Article  CAS  PubMed  Google Scholar 

  19. Zhang Q. S., Wang I., Kirillov A. M., Dou W., Xu C., Xu C. L., Yang L. Z., Fang R., Liu W. S., ACS Appl. Mater. Interfaces, 2018, 10, 23976

    Article  CAS  PubMed  Google Scholar 

  20. Hu J. S., Cheng T. T., Dong S. I., Zhou C. H., Huang X. H., Zhang L., Microporous Mesoporous Mater., 2018, 272, 177

    Article  CAS  Google Scholar 

  21. Ming M., Bai N., J. Solid State Chem., 2017, 254, 9

    Article  CAS  Google Scholar 

  22. Sun X. D., Yao S., Yu C., Li G. H., Liu C. M., Huo Q. S., Liu Y. L., J. Mater. Chem. A, 2018, 6, 6363

    Article  CAS  Google Scholar 

  23. Gao R. C., Guo F. S., Bai N. N., Wu Y. L., Yang F., Liang J. Y., Li Z. J., Wang Y. Y., Inorg. Chem., 2016, 55, 11323

    Article  CAS  PubMed  Google Scholar 

  24. Li Y., Xiao A. S., Zou B., Zhang H. X., Yan K. L., Lin Y., Polyhedron, 2018, 154, 83

    Article  CAS  Google Scholar 

  25. Dmello M. E., Sundaram N. G., Kalidindi S. B., Chem.-Eur. J. 2018, 24, 9220

    Article  CAS  PubMed  Google Scholar 

  26. Zhang X., Jiang K., He H. J., Yue D., Zhao D., Cui Y. I., Yang Y., Qian G. D., Sens. Actuators, B, 2018, 254, 1069

    Article  CAS  Google Scholar 

  27. Xing K., Fan R. Q., Wang F. Y., Nie H., Du X., Gai S., Wang P., Yang Y. L., ACS Appl. Mater. Interfaces, 2018, 10, 22746

    Article  CAS  PubMed  Google Scholar 

  28. Chen H. Y., Wang J., Shan D. L., Chen I., Zhang S. T., Lu X., Anal. Chem., 2018, 90, 7056

    Article  CAS  PubMed  Google Scholar 

  29. Zhao S., Hao X. M., Liu J. L., Wu L. W., Wang H., Wu Y. B., Yang D., Guo W L., J. Solid State Chem., 2017, 255, 76

    Article  CAS  Google Scholar 

  30. Wu J. X., Yan B., J. Coll. Interface Sci., 2017, 504, 197

    Article  CAS  Google Scholar 

  31. Wang D. M., Zhang L. R., Li G. H., Huo Q. S., Liu Y. L., RSC Adv., 2015, 5, 18087

    Article  CAS  Google Scholar 

  32. Das P., Mandal S. K., ACS Appl. Mater. Interfaces, 2018, 10, 25360

    Article  CAS  PubMed  Google Scholar 

  33. Li J. T., Luo X. L., Zhou Y., Zhang L. R., Huo Q. S., Liu Y. L., Cryst. Growth Des., 2018, 18, 1857

    Article  CAS  Google Scholar 

  34. Zhang L., Xin X., Lu Y., Sun D., Chem. Res. Chinese Universities, 2018, 34 (1), 175

    Article  CAS  Google Scholar 

  35. Fu J. J., Luo R., Wang S. H., Zhang N., Chen C., Chem. J. Chinese Universities, 2019, 40 (2), 419

    CAS  Google Scholar 

  36. Xing S. H., Bing Q. M., Qi H, Liu J. Y., Bai T. Y., Li G. H., Shi Z., Feng S. H, Xu R. R., ACS Appl. Mater. Interfaces, 2017, 9, 23828

    Article  CAS  PubMed  Google Scholar 

  37. Hu Z. C., Deibert B. J., Li I., Chem. Soc. Rev, 2014, 43, 5815

    Article  CAS  PubMed  Google Scholar 

  38. Rachuri Y., Parmar B., Bisht K. K., Suresh E., Dalton Trans., 2016, 45, 7881

    Article  CAS  PubMed  Google Scholar 

  39. Liu X. I., Wang X., Xu J. L., Tian D., Chen R. Y., Xu J., Bu X. H., Dalton Trans., 2017, 46, 4893

    Article  CAS  PubMed  Google Scholar 

  40. Sheldrick G., Acta Cryst. A, 1990, 46, 467

    Article  Google Scholar 

  41. Sheldrick G., Acta Cryst. A, 2008, 64, 112

    Article  CAS  Google Scholar 

  42. Sheldrick G., Acta Cryst. C, 2015, 71, 3

    Article  CAS  Google Scholar 

  43. Blatov V. A., Shevchenko A. P., Proserpio D. M., Cryst. Growth Des., 2014, 14, 3576

    Article  CAS  Google Scholar 

  44. Zhang L. L., Kang Z. X., Xin X. L., Sun D. F., CrystEngComm, 2016, 18, 193

    Article  CAS  Google Scholar 

  45. Zhang S. R., Du D. Y., Qin J. S., Bao S. I., Li S. L., He W. W., Lan Y. Q., Shen P., Su Z. M., Chem.-Eur. J., 2014, 20, 3589

    Article  CAS  PubMed  Google Scholar 

  46. Hu Z. C., Deibert B. J., Li I., Chem. Soc. Rev, 2014, 43, 5815

    Article  CAS  PubMed  Google Scholar 

  47. Hu Z. C., Pramanik S., Tan K., Zheng C., Liu W., Zhang X., Chabal Y. I., Li I., Cryst. Growth Des., 2013, 13, 4204

    Article  CAS  Google Scholar 

  48. Lan A. I., Li K. H., Wu H. H., Kong L. Z., Nijem N., Olson D. H., Emge T. I., Chabal Y. I., Langreth D. C., Hong M., Li I., Inorg. Chem., 2009, 48, 7165

    Article  CAS  PubMed  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory for Advanced Catalysis Materials, Ministry of Education, College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua, 321004, P. R. China

    Dongmei Wang, Shengjun Lou, Yiting Ying, Zhiqi Guo & Lijun Wang

Authors
  1. Dongmei Wang
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  2. Shengjun Lou
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  3. Yiting Ying
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  4. Zhiqi Guo
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  5. Lijun Wang
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Corresponding author

Correspondence to Dongmei Wang.

Additional information

Supported by the Natural Science Foundation of Zhejiang Province, China(No.LQ18B010002).

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Wang, D., Lou, S., Ying, Y. et al. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives. Chem. Res. Chin. Univ. 35, 762–766 (2019). https://doi.org/10.1007/s40242-019-9099-0

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  • DOI: https://doi.org/10.1007/s40242-019-9099-0

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