Abstract
[Zn(phen)3] ZTO 6H2O(1) and [Cu(phen)3] ZTO 6H2O(2) were synthesized by the reaction of Zn(NO3)2 6H2O/Cu(NO3)2 3H2O with 4,4-azo-1H-1,2,4-triazol-5-one(ZTO) and 1,10-phenanthroline(phen). The two compounds were characterized by elemental analysis and IR spectrum analysis, respectively. Compound 1 was also characterized by single crystal X-ray diffraction analysis. For compound 1, the coordination geometry around the Zn2+ is a distorted octahedron, with the bite angles of 76.7(3)°―77.6(4)° for all three phen ligands. Moreover, the thermal behaviors and thermal decomposition kinetics were studied and analyzed. Besides, thermal stability and safety parameters(TSADT, Tb) are 164.7 and 166.4 °C for compound 1, and 149.6 and 150.8 °C for compound 2, respectively.
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Supported by the Northwest University Graduate Innovation and Creativity Fund, China(No.YZZ17145) and the Natural Science Basic Research Fund of Shaanxi Province, China(No.2018JM2061).
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Synthesis, Structure characteristic and Thermal behavior of two new metal-organic azo-triazole compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O
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Ding, Z., Cao, W., Zheng, H. et al. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3] ZTO 6H2O and [Cu(phen)3] ZTO 6H2O. Chem. Res. Chin. Univ. 34, 1009–1013 (2018). https://doi.org/10.1007/s40242-018-8051-z
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DOI: https://doi.org/10.1007/s40242-018-8051-z