Chemical Research in Chinese Universities

, Volume 34, Issue 2, pp 311–317 | Cite as

Mechanical and Adhesive Properties of Ploy(ethylene glycerol) Diacrylate Based Hydrogels Plasticized with PEG and Glycerol

  • Longyun Li
  • Shuang Guan
  • Li Yang
  • Xuzhen Qin
  • Wei Feng
Article
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Abstract

Using polyethylene glycol(PEG) or glycerol as the plasticizer, we synthesized the hydrogels from poly(ethylene glycol) diacrylate(PEGDA), polyvinylpyrrolidone(PVP) and poly(vinyl alcohol)(PVA) under UV radiation. The effects of different plasticizers on the mechanical properties and adhesion properties of the hydrogels were investigated. The results show that the plasticizer can improve the elongation and peeling force. The most pronounced changes in the tensile property of the hydrogels are due to the addition of glycerol followed by PEG, the lower the plasticizer’s molecular weight, the greater its effect. The maximum peeling force is 0.317 or 0.257 N with PEG or glycerol as plasticizer, respectively, and their adhesion properties are due to the formation of hydrogen bonds.

Keywords

Poly(ethylene glycol) diacrylate Hydrogel Plasticizer Adhesion 

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References

  1. [1]
    Tan H. S., Pfister W. R., Pharmaceutical Science and Technology Today, 1999, 2, 60CrossRefGoogle Scholar
  2. [2]
    Venkatraman S., Gale R., Biomaterials, 1998, 19, 1119CrossRefGoogle Scholar
  3. [3]
    Satas D., Handbook of Pressure Sensitive Adhesive Technology: Hospital and First Aid Products, van Nostrand Reinhold, New York, 1989CrossRefGoogle Scholar
  4. [4]
    Wang T., Colver P. J., Bon S. A. F., Keddie J. L., Soft Matter, 2009, 5, 3842CrossRefGoogle Scholar
  5. [5]
    Langer R., Peppas N. A., AIChE Journal, 2003, 49, 2990CrossRefGoogle Scholar
  6. [6]
    Kundakci S., Uzum O. B., Karadag E., Reactive and Functional Po-lymers, 2008, 68, 458CrossRefGoogle Scholar
  7. [7]
    Schwall C. T., Banerjee I. A., Materials, 2009, 2, 577CrossRefGoogle Scholar
  8. [8]
    Baker M. I., Walsh S. P., Schwartz Z., Boyan B. D., Journal of Bio-medical Material Research Part B: Applied Biomaterials, 2012, 100B, 1451CrossRefGoogle Scholar
  9. [9]
    Qiu Y., Park K., Advanced Drug Delivery Reviews, 2012, 64, 49CrossRefGoogle Scholar
  10. [10]
    Jayakumar R., Prabaharan M., Muzzarelli R. A. A., Chitosan for Biomaterials II, Springer, New York, 2011Google Scholar
  11. [11]
    Croisier F., Jerome C., European Polymer Journal, 2013, 49, 780CrossRefGoogle Scholar
  12. [12]
    Peppas N. A., Hydrogels in Medicine and Pharmacy: Vol.I—III, CRC Press, Boca Raton, 1986Google Scholar
  13. [13]
    Gong J. P., Katsuyama Y., Kurokawa T., Osada Y., Advanced Mate-rials, 2003, 15, 1155CrossRefGoogle Scholar
  14. [14]
    Yasuda K., Gong J. P., Katsuyama Y., Nakayama A., Tanabe Y., Kondo E., Ueno M., Osada Y., Biomaterials, 2005, 26, 4468CrossRefGoogle Scholar
  15. [15]
    Tominaga T., Tirumala V. R., Lin E. K., Gong J. P., Furukawa H., Osada Y., Wu W. L., Polymer, 2007, 48, 7449CrossRefGoogle Scholar
  16. [16]
    Nakajima T., Furukawa H., Gong J. P., Lin E. K., Wu W. L., Macro-molecular Symposia, 2010, 291/292, 122CrossRefGoogle Scholar
  17. [17]
    Tominaga T., Tirumala V. R., Lee S., Lin E. K., Gong J. P., Wu W. L., Journal of Physical Chemistry B, 2008, 112, 3903CrossRefGoogle Scholar
  18. [18]
    Chen Q., Zhu L., Zhao C., Wang Q., Zheng J., Advanced Materials, 2013, 25, 4171CrossRefGoogle Scholar
  19. [19]
    Chen Q., Zhu L., Chen H., Yan H., Huang L., Yang J., Zheng J., Advanced Functional Materials, 2015, 25, 1598CrossRefGoogle Scholar
  20. [20]
    Chen H., Chen Q., Hu R. D., Wang H., Chang Y., Zheng J., Journal of Material Chemistry B, 2015, 3, 5426CrossRefGoogle Scholar
  21. [21]
    Chen Q., Zhu L., Huang L. N., Chen H., Xu K., Tan Y., Wang P. X., Zheng J., Macromolecules, 2014, 47, 2140CrossRefGoogle Scholar
  22. [22]
    Chen Q., Wei D. D., Chen H., Zhu L., Jiao C. C., Liu G., Huang L. N., Yang J., Wang L. B., Zheng J., Macromolecules, 2015, 48, 8003CrossRefGoogle Scholar
  23. [23]
    Kreeva P. E., Shandryuk G. A., Kostina J. V., Bondarenko G. N., Singh P., Cleary G. W., Feldstein M. M., Journal of Applied Polymer Science, 2007, 105, 3017CrossRefGoogle Scholar
  24. [24]
    Feldstein M. M., Shandryuk G. A., Plate N. A., Polymer, 2001, 42, 971CrossRefGoogle Scholar
  25. [25]
    Ajji Z., Othman I., Rosiak J. M., NIMB Beam Interactions with Ma-terials and Atoms, 2005, 229, 375Google Scholar
  26. [26]
    Dana S. F., Nguyen D. V., Kochhar J. S., Liu X. Y., Kang L. F., Soft Matter, 2013, 9, 6270CrossRefGoogle Scholar
  27. [27]
    Yang X. M., Liu Q., Chen X. L., Yu F., Zhu Z. Y., Carbohydrate Po-lymers, 2008, 73, 401CrossRefGoogle Scholar
  28. [28]
    Qin X. Z., Hu Q. Q., Gao G. H., Guan S., Chem. Res. Chinese Uni-versities, 2015, 31(6), 1046CrossRefGoogle Scholar
  29. [29]
    Rosiak J. M.; Clough R.L., Shalaby S. W., Hydrogel Dressing, Radiation Effects on Polymers, ACS Book Series, Washington DC, 1991Google Scholar
  30. [30]
    Liu G. Q., Polish Journal of Chemical Technology, 2013, 15, 85CrossRefGoogle Scholar
  31. [31]
    Zhao C. M., Lu X. T., Hu Q. Q., Liu S., Guan S., Chem. Res. Chinese Universities, 2017, 33(6), 995Google Scholar
  32. [32]
    Gal A., Nussinovitch A., International Journal of Pharmaceutics, 2009, 370, 103CrossRefGoogle Scholar
  33. [33]
    Wypych G., Handbook of Plasticizers, ChemTec Publishing, Toronto, 2004Google Scholar
  34. [34]
    Arvanitoyannis I., Kolokuris I., Nakayama A., Yamaoto N., Aiba S. I., Carbohydrate Polymers, 1997, 34, 9CrossRefGoogle Scholar
  35. [35]
    Wang R., Wang Q., Li L., Polymer International, 2003, 52, 1820CrossRefGoogle Scholar
  36. [36]
    Rajendran S., Sivakumar M., Subadevi R., Materials Letter, 2004, 58, 641CrossRefGoogle Scholar
  37. [37]
    Haq M. A., Hasnain A., Azam M., LWT-Food Science and Technolo-gy, 2014, 55, 163CrossRefGoogle Scholar
  38. [38]
    Zhang Y. C., Han J. H., Journal of Food Science, 2006, 71, 253CrossRefGoogle Scholar
  39. [39]
    Minghetti P., Cilurzo F., Montanari L., Drug Development and Industrial Pharmacy, 1999, 25, 1CrossRefGoogle Scholar

Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Longyun Li
    • 1
  • Shuang Guan
    • 2
  • Li Yang
    • 1
  • Xuzhen Qin
    • 2
  • Wei Feng
    • 1
  1. 1.China-Japan Union Hospital of Jilin UniversityChangchunP. R. China
  2. 2.School of Chemistry and Life Science, Advanced Institute of Materials ScienceChangchun University of TechnologyChangchunP. R. China

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