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Fluorine Modified TAPO-5: Synthesis and Catalytic Performance in Cyclohexanone Ammoximation

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Abstract

A series of fluorine modified TAPO-5 molecular sieves was synthesized by one-pot method using ammo-nium hexafluorotitanate as titanium and fluorine sources. The XPS and DRS UV-Vis results indicated that the exis-tence of F could promote the formation of tetrahedrally coordinated framework Ti and Al, meanwhile, inhibit the formation of anatase TiO2 in TAPO-5 sieves due to the unique role of F in the sol-gel process of metal ions. Further-more, TG, contact angle test, Py-FTIR and 27Al MAS NMR results revealed that fluorine modification increased the surface hydrophobicity and the Lewis acidity of Ti active sites through forming Al x F y units in the neighborhood. All these factors make these fluorine modified TAPO-5 sieves exhibit good catalytic performance in the ammoximation of cyclohexanone.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Engineering Research Centre of Ministry of Education for Fine Chemicals, Shanxi University, Taiyuan, 030006, P. R. China

    Hengjie Li, Pengfei Gao, Xiaolu Xue, Hongxi Zhang & Yongxiang Zhao

Authors
  1. Hengjie Li
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  2. Pengfei Gao
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  3. Xiaolu Xue
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  4. Hongxi Zhang
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  5. Yongxiang Zhao
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Corresponding authors

Correspondence to Pengfei Gao or Yongxiang Zhao.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21403135, 21303097, 21305082), and the Science and Technology Research Project of Shanxi Province, China(Nos 201603D121018-1).

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Li, H., Gao, P., Xue, X. et al. Fluorine Modified TAPO-5: Synthesis and Catalytic Performance in Cyclohexanone Ammoximation. Chem. Res. Chin. Univ. 34, 247–253 (2018). https://doi.org/10.1007/s40242-018-7296-x

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  • DOI: https://doi.org/10.1007/s40242-018-7296-x

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