Chemical Research in Chinese Universities

, Volume 34, Issue 2, pp 274–278 | Cite as

Synthesis and Visible-light Photocatalytic Performance of C-doped Nb2O5 with High Surface Area

  • Shuang Ding
  • Runwei Wang
  • Panpan Zhang
  • Bonan Kang
  • Daliang Zhang
  • Zongtao Zhang
  • Shilun Qiu
Article
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Abstract

C-doped Nb2O5 with abundant mesopores has been successfully synthesized through a facile solvothermal synthetic strategy followed by calcination treatment. The resulting C-doped Nb2O5 displayed the highest BET surface area(345 m2/g) and large mesopore size(ca. 4.2 nm), capable of offering more accessible active sites as well as faster mass transfer for catalysis. Besides, the doping of C(2.21%, molar fraction) at the O sites in Nb2O5 lattice greatly enhanced visible-light response by lowering the band gap, thereby making the material a photocatalyst under visible-light irradiation. Typically, the C-doped Nb2O5 exhibited a high H2 evolution rate of ca. 39.10 μmol·g–1·h–1 and also degraded RhB dye completely after 30 min of visible light exposure, which turned out to be much better than Degussa P25 and pure Nb2O5 catalysts.

Keywords

C-Doped Highest BET surface area Degradation RhB H2 evolution 

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Supplementary material

40242_2018_7260_MOESM1_ESM.pdf (328 kb)
The loaded process of photocatalyst with 0.5 wt. % Pt

References

  1. [1]
    Osterloh F. E., Chem. Mater., 2008, 20(1), 35CrossRefGoogle Scholar
  2. [2]
    Ni M., Leung M. K. H., Leung D. Y. C., Sumathy K., Renew Sust. Energ. Rev., 2007, 11(3), 401CrossRefGoogle Scholar
  3. [3]
    Zhang J. J., Li L., Hao Y. T., Sun L. L., Zhang X. Y., Chem. J. Chi-nese Universities, 2017, 38(2), 238Google Scholar
  4. [4]
    Chen X. B., Shen S. H., Guo L. J., Mao S. S., Chem. Rev., 2010, 110(11), 6503CrossRefGoogle Scholar
  5. [5]
    Kim J., Henao C. A., Johnson T. A., Dedrick D. E., Miller J. E., Ste-chel E. B., Maravelias C. T., Energ. Environ. Sci., 2011, 4(9), 3122CrossRefGoogle Scholar
  6. [6]
    Mubeen S., Singh N., Lee J., Stucky G. D., Moskovits M., McFar-land E. W., Nano Lett., 2013, 13(5), 2110CrossRefGoogle Scholar
  7. [7]
    Han F., Kambala V. S. R., Srinivasan M., Rajarathnam D., Naidu R., Appl. Catal. A: Gen., 2009, 359(1/2), 25CrossRefGoogle Scholar
  8. [8]
    Liu S. H., Sun X. D., Li J. G., Li X. D., Xiu Z. M., Yang H., Xue X. X., Langmuir, 2010, 26(6), 4546CrossRefGoogle Scholar
  9. [9]
    Li R., Yu L. M., Yan X. F., Jiang T., Chem. J. Chinese Universities, 2017, 38(2), 267Google Scholar
  10. [10]
    Liang H. O., Bai J., Yu D. D., Zhang Q. Y., Li C. P., Chem. J. Chinese Universities, 2017, 38(6), 947Google Scholar
  11. [11]
    Liang R. Y., Xu D. D., Zha W. Y., Qi J. Z., Huang L. H., Chem. J. Chinese Universities, 2016, 37(11), 1953Google Scholar
  12. [12]
    Sun L. Z., Zhao S. Z., Gao Z. L., Cheng Z. Q., Chem. J. Chinese Universities, 2017, 38(6), 907Google Scholar
  13. [13]
    Fujishima A., Honda K., Nature, 1972, 238(5358), 37CrossRefGoogle Scholar
  14. [14]
    Ding Z., And G. Q. L., Greenfield P. F., J. Phys. Chem. B, 2000, 104(19), 4815CrossRefGoogle Scholar
  15. [15]
    Khan S. U., Alshahry M., Jr I. W., Science, 2003, 34(2), 2243Google Scholar
  16. [16]
    Wolcott A., Smith W. A., Kuykendall T. R., Zhao Y. P., Zhang J. Z., Adv. Funct. Mater., 2009, 19(12), 1849CrossRefGoogle Scholar
  17. [17]
    Yang X. Y., Wolcott A., Wang G. M., Sobo A., Fitzmorris R. C., Qian F., Zhang J. Z., Li Y., Nano Lett., 2009, 9(6), 2331CrossRefGoogle Scholar
  18. [18]
    Chakrabarti S., Dutta B. K., J. Hazard. Mater., 2004, 112(3), 269CrossRefGoogle Scholar
  19. [19]
    Chen X. Y., Yu T., Fan X. X., Zhang H. T., Li Z. S., Ye J. H., Zou Z. G., Appl. Surf. Sci., 2007, 253(20), 8500CrossRefGoogle Scholar
  20. [20]
    Ge S., Jia H., Zhao H., Zheng Z., Zhang L., J. Mater. Chem., 2010, 20(15), 3052CrossRefGoogle Scholar
  21. [21]
    Gu D. E., Lu Y., Yang B. C., Hu Y. D., Chem. Commun., 2008, (21), 2453CrossRefGoogle Scholar
  22. [22]
    Sathish M., Viswanathan B., Viswanath R. P., Gopinath C. S., Chem. Mater., 2005, 17(25), 6349CrossRefGoogle Scholar
  23. [23]
    Silva M. K., Marques R. G., Machado N. R. C. F., Santos O. A. A., Braz. J. Chem. Eng., 2002, 19(4), 359CrossRefGoogle Scholar
  24. [24]
    Suzuki N., Athar T., Huang Y. T., Shimasaki K., Miyamoto N., Ya-mauchi Y., J. Ceram. Soc. Jpn., 2011, 119(1390), 405CrossRefGoogle Scholar
  25. [25]
    Zhao Y., Eley C., Hu J. P., Foord J. S., Ye L., He H. Y., Tsang S. C. E., Angew. Chem. Int. Ed., 2012, 51(16), 3846CrossRefGoogle Scholar
  26. [26]
    Wang X., Chen G., Zhou C., Yu Y. G., Wang G., Eur. J. Inorg. Chem., 2012, (11), 1742CrossRefGoogle Scholar
  27. [27]
    Vettraino M., He X., Trudeau M., Drake J. E., Antonelli D. M., Adv. Funct. Mater., 2010, 12(3), 174CrossRefGoogle Scholar
  28. [28]
    Fontaine R., Caillat R., Feve L., Guittet M. J., J. Electron. Spectrosc. Relat. Phenom., 1977, 10(4), 349CrossRefGoogle Scholar
  29. [29]
    Dr S. S., Dr H. K., Angew. Chem., 2003, 42(40), 4908CrossRefGoogle Scholar
  30. [30]
    Nedfors N., Tengstrand O., Lewin E., Furlan A., Eklund P., Hultman L., Jansson U., Surf. Coat. Tech., 2011, 206(2/3), 354CrossRefGoogle Scholar
  31. [31]
    Li Y., Hwang D. S., Lee N. H., Kim S. J., Chem. Phys. Lett., 2005, 404(1), 25CrossRefGoogle Scholar
  32. [32]
    Ren W. J., Ai Z. H., Jia F. L., Zhang L. Z., Fan X. X., Zou Z. G., Appl. Catal. B: Environ., 2007, 69(3/4), 138CrossRefGoogle Scholar

Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Shuang Ding
    • 1
  • Runwei Wang
    • 2
  • Panpan Zhang
    • 1
  • Bonan Kang
    • 1
  • Daliang Zhang
    • 1
  • Zongtao Zhang
    • 2
  • Shilun Qiu
    • 2
  1. 1.Stage Key Laboratory of Integrated Optoelectronics, College of Electronic Science and EngineeringJilin UniversityChangchunP. R. China
  2. 2.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of ChemistryJilin UniversityChangchunP. R. China

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