Skip to main content
SpringerLink
Log in

Template effect of hydrophobically associating polymers on the construction of cuprous oxide micro structure

  • Published:
Chemical Research in Chinese Universities Aims and scope

Abstract

To determine the template effect of hydrophobically associating copolymers(HACPs) on the morphology of nano/micro structures, six HACPs were synthesized and used as templates to biomimetically synthesize cuprous oxide(Cu2O), an important semiconductor. This experiment showed a clear relationship between the associating state of the HACP molecules and the morphology of the Cu2O particles. Cu2O hollow spheres were preferentially prepared when the HACP molecules were in an intramolecular associating state. Furthermore, a Cu2O hexapod was easily ob-tained when the HACP molecules were in an intermolecular associating state. The morphologies of the Cu2O crystals prepared in the presence of the HACPs also confirmed this result.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Mnna S., Nature, 1993, 365(7), 499

    Article  Google Scholar 

  2. Weiner S., Addadi L., J. Mater. Chem., 1997, 7(5), 689

    Article  CAS  Google Scholar 

  3. Annenkov V. V., Danilovtseva E. N., Pal’shin V. A., RSC Adv., 2017, 7, 20995

    Article  CAS  Google Scholar 

  4. Hartgerink J. D., Beniash E., Stupp S. I., Science, 2001, 294(5547), 1684

    Article  CAS  Google Scholar 

  5. Zheng Z., Huang B., Ma H., Cryst. Growth Des., 2007, 7(9), 1912

    Article  CAS  Google Scholar 

  6. Yan B. Q., Nan Z. D., Liu Y., Chinese J. Chem., 2008, 26(12), 2302

    Article  CAS  Google Scholar 

  7. Finnemore A., Cunha P., Shean T., Nat. Com., 2012, 3, 966

    Article  Google Scholar 

  8. Banerjee I. Yu A. L., Matsui H., J. Am. Chem. Soc., 2003, 125(32), 9542

    Article  CAS  Google Scholar 

  9. Zhang D., Qi L., Ma J., Cheng H., Chem. Mater., 2001, 13(9), 2753

    Article  CAS  Google Scholar 

  10. Qi L., Colfen H., Antonietti M., Nano Lett., 2001, 1(2), 61

    Article  CAS  Google Scholar 

  11. Bastakoti B. P., Guragain S., Yokoyama Y., Langmuir, 2011, 27(1), 379

    Article  CAS  Google Scholar 

  12. Ng C. H. B., Fan W. Y., J. Phys. Chem. B, 2006, 110(42), 20801

    Article  CAS  Google Scholar 

  13. Du S. S., Cheng P. F., Sun P., Wang B., Cai Y. X., Chem. Res. Chi-nese Universities, 2014, 30(4), 661

    Article  CAS  Google Scholar 

  14. Poizot P., Laruelle S., Grugeon S., Dupont L., Taracon J. M., Nature, 2000, 407, 496

    Article  CAS  Google Scholar 

  15. Qiu X. Q., Miyauchi M., Sunada K., Minoshima M., ACS Nano, 2012, 6(2), 1609

    Article  CAS  Google Scholar 

  16. Chang Y., Teo J. J., Zeng H. C., Langmuir, 2005, 21(3), 1074

    Article  CAS  Google Scholar 

  17. Xu J. S., Xue D. F., Acta. Mater., 2007, 55, 2397

    Article  CAS  Google Scholar 

  18. Yu L. M., An Z. G., Dong L., Paint Coat. Ind., 2007, 37(7), 70

    CAS  Google Scholar 

  19. Jia L. N., Yu L. M., Li R., J. Appl. Polym. Sci., 2013, 130(3), 1794

    Article  CAS  Google Scholar 

  20. Feng Y. J., Billon L., Grassl B., Polymer, 2002, 43(7), 2055

    Article  CAS  Google Scholar 

  21. Pu H. T., Jiang W. C., Liu L., Chem. J. Chinese Universities, 2005, 26(9), 1743

    CAS  Google Scholar 

  22. Gao B. J., Jiang L. D., Liu K. K., Eur. Poly. J., 2007, 43(10), 4530

    Article  CAS  Google Scholar 

  23. Dobrynin A. V., Rubinstein M., Macromolecules, 1999, 32(3), 915

    Article  CAS  Google Scholar 

  24. Dobrynin A. V., Rubinstein M., Macromolecules, 2000, 33(21), 8097

    Article  CAS  Google Scholar 

  25. Zhang L., Eisenberg A., Macromolecules, 1999, 32, 2239

    Article  CAS  Google Scholar 

  26. Zhang L., Eisenberg A., Polym. Adv. Technol., 1998, 9, 677

    Article  CAS  Google Scholar 

  27. Jiang L. F., Zhong C. R., Xu M., Acta Phys.-Chim. Sin., 2010, 26(3), 535

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, 266100, P. R. China

    Lei Dong, Huan Liu, Hongtao Zhang & Liangmin Yu

  2. School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou, 221116, P. R. China

    Yanjuan Li

  3. National Engineering Research Center for Marine Drugs, Ocean University of China, Qingdao, 266071, P. R. China

    Lanni Jia

  4. Marine Biomedical Research Institute of Qingdao, Qingdao, 266071, P. R. China

    Lanni Jia

Authors
  1. Lei Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Huan Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yanjuan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Hongtao Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Liangmin Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Lanni Jia
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Liangmin Yu or Lanni Jia.

Additional information

Supported by the National Natural Science Foundation of China(No.51102219) and the Fundamental Research Funds for the Central Universities of China(Nos.201113024, 41404010204).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dong, L., Liu, H., Li, Y. et al. Template effect of hydrophobically associating polymers on the construction of cuprous oxide micro structure. Chem. Res. Chin. Univ. 34, 138–144 (2018). https://doi.org/10.1007/s40242-018-7173-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40242-018-7173-7

Keywords

Search

Navigation