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Chemical Research in Chinese Universities

, Volume 33, Issue 4, pp 513–519 | Cite as

Structure-directing effect on synthesis of layered aluminophosphates with same topology

  • Aitian Wang
  • Jun Xu
  • Chao Wang
  • Feng Deng
  • Ruren Xu
  • Wenfu YanEmail author
Article

Abstract

Three layered aluminophosphates(UiO-15, APDAP12-150 and APDAP-150) with same topology were crystallized from an initial mixture with a molar composition of Al2O3:1.5P2O5:5.5R:227H2O, where R is ethylene-diamine, 1,2-diaminopropane or 1,3-diaminopropane, respectively. The crystallization processes of UiO-15, APDAP12-150 and APDAP-150 were investigated using solid-state NMR in combination with XRD and other characterization techniques. The evolution of the coordination states of Al and P in the solid products was monitored, and the possible starting points of crystallization(core units) of UiO-15, APDAP12-150 and APDAP-150 were obtained and analyzed. The formation of a trimer as well as a hexamer of aluminophosphate, a monomer of PO4 and a nonamer containing two three-membered rings is critical for the start of crystallization of UiO-15. The formation of a hexamer and a pentamer is critical for the start of crystallization of APDAP12-150. The formation of an AlO6 monomer and a pentamer containing a three-membered ring is critical for the start of crystallization of APDAP-150. The crystal water played a co-structure-directing role in the formation of APDAP-150.

Keywords

Zeolite Aluminophosphate Templating effect Structure-directing effect 

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Supplementary material

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Structure-directing effect in the synthesis of layered aluminophosphates with the same topology

References

  1. [1]
    Xu R. R., Pang W. Q., Yu J. H., Huo Q. S., Chen J. S., Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2008Google Scholar
  2. [2]
    Wright P. A., Microporous Framework Solids, Royal Society of Chemistry, Cambridge, 2008Google Scholar
  3. [3]
    Chester A. W., Derouane E. G., Zeolite Characterization and Cataly-sis——A Tutorial, Springer, New York, 2009Google Scholar
  4. [4]
    Vermeiren W., Gilson J. P., Topics in Catalysis, 2009, 52(9), 1131CrossRefGoogle Scholar
  5. [5]
    Kulprathipanja S., Zeolites in Industrial Separation and Catalysis, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010CrossRefGoogle Scholar
  6. [6]
    Cejka J., Corma A., Zones S., Zeolites and Catalysis: Synthesis, Reactions and Applications, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2010CrossRefGoogle Scholar
  7. [7]
    Yu J. H., Xu R. R., Accounts of Chemical Research, 2003, 36(7), 481CrossRefGoogle Scholar
  8. [8]
    Yu J. H., Xu R. R., Chem. Soc. Rev., 2006, 35(7), 593CrossRefGoogle Scholar
  9. [9]
    Wilson S. T., Lok B. M., Flanigen E. M., Crystalline Metallophos-phate Compositions, USPat. 4310440, 1982Google Scholar
  10. [10]
    Wilson S. T., Lok B. M., Messina C. A., Cannan T. R., Flanigen E. M., J. Am. Chem. Soc., 1982, 104(4), 1146CrossRefGoogle Scholar
  11. [11]
    Cundy C. S., Cox P. A., Micropor. Mesopor. Mater., 2005, 82(1/2), 1CrossRefGoogle Scholar
  12. [12]
    Wilson S. T., Studies in Surface Science and Catalysis, 2001, 137, 229CrossRefGoogle Scholar
  13. [13]
    Lok B. M., Cannan T. R., Messina C. A., Zeolites, 1983, 3(4), 282CrossRefGoogle Scholar
  14. [14]
    Tapp N. J., Milestone N. B., Bibby D. M., Zeolites, 1988, 8(3), 183CrossRefGoogle Scholar
  15. [15]
    Lewis D. W., Freeman C. M., Catlow C. R. A., J. Phys. Chem., 1995, 99(28), 11194CrossRefGoogle Scholar
  16. [16]
    Lewis D. W., Sankar G., Wyles J. K., Thomas J. M., Catlow C. R. A., Willock D. J., Angew. Chem. Int. Ed. Eng., 1997, 36(23), 2675CrossRefGoogle Scholar
  17. [17]
    Nakagawa Y., Lee G. S., Harris T. V., Yuen L. T., Zones S. I., Micro-porous and Mesoporous Mater., 1998, 22(1—3), 69CrossRefGoogle Scholar
  18. [18]
    Fodor D., Beloqui Redondo A., Krumeich F., van Bokhoven J. A., J. Phys. Chem. C, 2015, 119(10), 5447CrossRefGoogle Scholar
  19. [19]
    Li J., Yu J., Yan W., Xu Y., Xu W., Qiu S., Xu R., Chem. Mater., 1999, 11(9), 2600CrossRefGoogle Scholar
  20. [20]
    Tong X. Q., Xu J., Wang C., Lu H. Y., Huang P., Yan W. F., Yu J. H., Deng F., Xu R. R., Microporous and Mesoporous Mater., 2012, 155, 153CrossRefGoogle Scholar
  21. [21]
    Park M. B., Ahn N. H., Broach R. W., Nicholas C. P., Lewis G. J., Hong S. B., Chem. Mater., 2015, 27(5), 1574CrossRefGoogle Scholar
  22. [22]
    Zhang B., Xu J., Fan F. T., Guo Q., Tong X. Q., Yan W. F., Yu J. H., Deng F., Li C., Xu R. R., Microporous and Mesoporous Mater., 2012, 147(1), 212CrossRefGoogle Scholar
  23. [23]
    Wagner P., Nakagawa Y., Lee G. S., Davis M. E., Elomari S., Medrud R. C., Zones S. I., J. Am. Chem. Soc., 2000, 122(2), 263CrossRefGoogle Scholar
  24. [24]
    Tong X. Q., Xu J., Xin L., Huang P., Lu H. Y., Wang C., Yan W. F., Yu J. H., Deng F., Sun H., Xu R. R., Microporous and Mesoporous Mater., 2012, 164, 56CrossRefGoogle Scholar
  25. [25]
    Sastre G., Leiva S., Sabater M. J., Gimenez I., Rey F., Valencia S., Corma A., J. Phys. Chem. B, 2003, 107(23), 5432CrossRefGoogle Scholar
  26. [26]
    Tong X. Q., Xu J., Li X., Li Y., Yan W. F., Yu J. H., Deng F., Sun H., Xu R. R., Microporous and Mesoporous Mater., 2013, 176, 112CrossRefGoogle Scholar
  27. [27]
    Huang P., Xu J., Wang C., Deng F., Yan W. F., RSC Adv., 2014, 4(73), 39011CrossRefGoogle Scholar
  28. [28]
    Pérez-Pariente J., Gómez-Hortigüela L., Arranz M., Chem. Mater., 2004, 16(17), 3209CrossRefGoogle Scholar
  29. [29]
    Lu H. Y., Yan Y., Tong X. Q., Yan W. F., Yu J. H., Xu R. R., Sci. China Chem., 2013, 57(1), 127CrossRefGoogle Scholar
  30. [30]
    Sastre G., Cantin A., Diaz-Cabañas M. J., Corma A., Chem. Mater., 2005, 17(3), 545CrossRefGoogle Scholar
  31. [31]
    Tong X. Q., Xu J., Wang C., Yan W. F., Yu J. H., Deng F., Xu R. R., Microporous and Mesoporous Mater., 2014, 183, 108CrossRefGoogle Scholar
  32. [32]
    Gómez-Hortigüela L., Márquez-Álvarez C., Corà F., López-Arbeloa F., Pérez-Pariente J., Chem. Mater., 2008, 20(3), 987CrossRefGoogle Scholar
  33. [33]
    Yan W. F., Song X. W., Xu R. R., Microporous and Mesoporous Mater., 2009, 123(1-3), 50CrossRefGoogle Scholar
  34. [34]
    Lu H. Y., Xu J., Gao P., Yan W. F., Deng F., Xu R. R., Microporous and Mesoporous Mater., 2015, 208, 105CrossRefGoogle Scholar
  35. [35]
    Zhang X. Q., Trinh T. T., van Santen R. A., Jansen A. P. J., J. Phys. Chem. C, 2011, 115(19), 9561CrossRefGoogle Scholar
  36. [36]
    Pinar A. B., Gomez-Hortiguela L., Perez-Pariente J., Chem. Mater., 2007, 19(23), 5617CrossRefGoogle Scholar
  37. [37]
    Xin L., Sun H., Xu R. R., Yan W. F., Scientific Reports, 2015, 5, 14940CrossRefGoogle Scholar
  38. [38]
    Huang P., Xu J., Qi G. D., Deng F., Xu R. R., Yan W. F., Scientific Reports, 2016, 6, 22019CrossRefGoogle Scholar
  39. [39]
    Gómez-Hortigüela L., Pérez-Pariente J., Corà F., Chemistry——A European Journal, 2009, 15(6), 1478CrossRefGoogle Scholar
  40. [40]
    Yu J., Li J., Wang K., Xu R., Sugiyama K., Terasaki O., Chem. Mater., 2000, 12(12), 3783CrossRefGoogle Scholar
  41. [41]
    Xu R. S., Shi X. C., Zhang W. P., Xu Y. P., Tian Z. J., Lu X. B., Han X. W., Bao X. H., Phys. Chem. Chem. Phys., 2010, 12(10), 2443CrossRefGoogle Scholar
  42. [42]
    White C. E., Provis J. L., J. Phys. Chem. C, 2012, 116(1), 1619CrossRefGoogle Scholar
  43. [43]
    Lu H. Y., Tong X. Q., Yan Y., Yan W. F., Yu J. H., Xu R. R., Chem. J. Chinese Universities, 2013, 34(7), 1571Google Scholar
  44. [44]
    Chen Y., Feng L., Chem. Res. Chinese Universities, 2016, 32(6), 895CrossRefGoogle Scholar
  45. [45]
    Wang X., Huang Y., Zhang X., Feng X., Huang W., Chem. Res. Chi-nese Universities, 2017, 33(1), 12CrossRefGoogle Scholar
  46. [46]
    Kongshaug K. O., Fjellvåg H., Lillerud K. P., J. Mater. Chem., 1999, 9(7), 1591CrossRefGoogle Scholar
  47. [47]
    Tuel A., Gramlich V., Baerlocher C., Microporous and Mesoporous Mater., 2000, 41(1—3), 217CrossRefGoogle Scholar
  48. [48]
    Maeda K., Tuel A., Baerlocher C., J. Chem. Soc., Dalton Transac-tions, 2000, (14), 2457CrossRefGoogle Scholar
  49. [49]
    Kongshaug K. O., Fjellvåg H., Lillerud K. P., Microporous and Mesoporous Mater., 2000, 38(2/3), 311CrossRefGoogle Scholar

Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  • Aitian Wang
    • 1
  • Jun Xu
    • 2
  • Chao Wang
    • 2
  • Feng Deng
    • 2
  • Ruren Xu
    • 1
  • Wenfu Yan
    • 1
    Email author
  1. 1.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of ChemistryJilin UniversityChangchunP. R. China
  2. 2.State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and MathematicsChinese Academy of SciencesWuhanP. R. China

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