Abstract
A series of Sr-substituted Gd1-x Sr x MnO3(0.1≤x≤0.3) materials was prepared via a standard method involving solid-state reaction. Their crystal structure within the entire doping region was determined to be orthorhombic perovskite type. The magnetic properties of the perovskite Gd1-x Sr x MnO3(0.1≤x≤0.3) were thoroughly investigated. It appears that Mn ions with high valence state can induce stronger magnetization, and negative magnetization is evident in the manganites with x=0.1 and x=0.2, suggesting that valence fluctuation plays an important role in such systems. The result of XPS analysis indicates that the valence state of Mn ions is 3.25 and there seems to be excess amounts of oxygen in the structure of Gd0.8Sr0.2MnO3+δ. In addition, the results of magnetization measurements demonstrate that spin reversal occurs only when the applied field is less than 1.99×105 A/m, which presumably could be due to the negative exchange interaction between Mn sub-lattice and Gd sites.
Similar content being viewed by others
References
Von H. R., Holzapfel B., Schulz L., Samwer K., Phys. Rev. Lett., 1993, 71, 2331
Li Y. X., Xue M., Guo L. J., Huang L., Chen S. R., Qiu S. L., Chem. Res. Chinese Universities, 2013, 29(2), 196
Jin S., Tiefel T. H., McCormack M., Fastnachat R., Ramesh R., Chen L. H., Science, 1994, 264, 413
Zhu L. L., Chen Y., Huang K. K., Zhang G. H., Hu W. W., Yuan H. M., Chang H. B., Feng S. H., Chem. Res. Chinese Universities, 2010, 26(5), 707
Das R., Jaiswal A., Adyanthaya S., Poddar P., J. Phys. Chem., 2010, 114, 12104
Beyreuther E., Grafstrom S., Lukas M. E., Phys. Rev. B, 2006, 73, 155425
Ulyanov A. N., Gusakov G. V., Borodin V. A., Solid State Commun., 2001, 118, 103
Yoshii K., Mater. Res. Bull., 2012, 47, 3243
Su Y. L., Zhang J. C., Feng Z. J., Li L., Li B. Z., Zhou Y., Chen Z. P., Cao S. X., J. Appl. Phys., 2010, 108, 013905
Feyerherm R., Dudzik E., Prokhnenko O., J. Phys.: Conf. Ser., 2010, 200, 012032
Pena O., Bahout M., Ghanimi K., Duran P., Gutierrez D., Moure C., J. Mater. Chem., 2002, 12, 2480
Kostogloudis G. C., Ftikos C., J. Mater. Sci., 1999, 34, 2169
Kimura T., Goto T., Shintani H., Ishizaka K., Arima T., Tokura Y., Nature, 2003, 426, 55
Tokura Y., Seki S., Adv. Mater., 2010, 22, 1554
Carver J. C., Schweitzer G. K., Carlson T. A., J. Chem. Phys., 1972, 57, 973
Beyreuther E., Grafström S., Eng M. L., Phys. Rev. B, 2006, 73, 155425
Zhao L. Z., Young V., J. Electron Spectrosc. Relat. Phenom., 1984, 34, 45
Negi P. G., Dixit H. M., Agrawal R. C., J. Supercond. Nov. Magn., 2013, 26, 1611
Wang X. L., Li D., Cui T. Y., Kharel P., Liu W., Zhang Z. D., J. Appl. Phys., 2010, 107, 09B510
Samantaray S., Mishra D. K., Pradhan S. K., Mishra P., Sekhar B. R., Behera D., Rout P. P., Das S. K., Sahu D. R., Roul B. K., J. Magn. Magn. Mater., 2013, 339, 168
Samantaray B., Ravi S., Das A., Srivastava S. K., J. Appl. Phys., 2011, 110, 093906
Hong F., Cheng Z., Wang J., Wang X., Dou S., Appl. Phys Lett., 2012, 10, 102411
Liu W. R., Huang C. H., Ye C. W., Chi Y. C., Ye Y. T., Liu R. S., RSC Adv., 2013, 3, 9023
Han L. L., Zhao L., Zhang J., Wang Y. Z., Guo L. N., Wang Y. H., RSC Adv., 2013, 3, 21824
Bingder K., Young A. P., Rev. Mod. Phys., 1986, 58, 801
Prado F., Sanchez R. D., Caneiro A., Causa M. T., Tovar M., J. Solid State Chem., 1999, 146, 418
Author information
Authors and Affiliations
Corresponding authors
Additional information
Supported by the National Natural Sciences Foundation of China(Nos.21271082, 21371068).
Rights and permissions
About this article
Cite this article
Zhang, Y., Li, J., Zhang, Z. et al. Negative magnetism in perovskite manganites Gd1-x Sr x MnO3(0.1≤x≤0.3). Chem. Res. Chin. Univ. 31, 699–703 (2015). https://doi.org/10.1007/s40242-015-5196-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-015-5196-x