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Syntheses, structures and properties of three transition metal coordination polymers based on semi-rigid 3-pyridylnicotinamide and S/N-containing dicarboxylate mixed ligands

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Abstract

Three new coordination complexes, [Co(L)(ADTZ)]·H2O(1), [Cd(L)(ADTZ)]·H2O(2) and [Zn(L)(ADTZ)]·H2O(3)[L=3-pyridylnicotinamide, H2ADTZ=2,5-(s-acetic acid)dimercapto-1,3,4-thiadiazole], were synthesized under hydrothermal conditions. These complexes were structurally characterized by single-crystal X-ray diffraction analysis and further characterized by infrared spectroscopy(IR), powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). Complexes 1–3 exhibit the similar 2D double-layer networks based on 1D [M-L] n zigzag chains and 1D [M-ADTZ]2n double-chains with different distances between metal ions and with various conformations of ADTZ anions. In complexes 1 and 3, the 2D sheets are extended into a 3D supramolecular frameworks by hydrogen bonding interactions. The subtle effects of the central metal atoms on the structures of the title coordination polymers were discussed. The electrochemical properties of complex 1 and luminescent properties of complexes 2 and 3 were investigated. In addition, complexes 1–3 exhibit photocatalytic activity for dye methylene blue degradation under UV light and show good stability toward photocatalysis.

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Authors and Affiliations

  1. Liaoning Province Silicon Materials Engineering Technology Research Centre, Department of Chemistry, Bohai University, Jinzhou, 121000, P. R. China

    Xiuli Wang, Chunhua Gong, Yun Qu, Guocheng Liu & Juwen Zhang

Authors
  1. Xiuli Wang
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  2. Chunhua Gong
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  3. Yun Qu
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  4. Guocheng Liu
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  5. Juwen Zhang
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Corresponding author

Correspondence to Xiuli Wang.

Additional information

Supported by the National Natural Science Foundation of China(No.21171025), the Project for New Century Excellent Talents in University of China(No.NCET-09-0853), and the Program of Innovative Research Team in University of Liaoning Province of China(No.LT2012020).

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Wang, X., Gong, C., Qu, Y. et al. Syntheses, structures and properties of three transition metal coordination polymers based on semi-rigid 3-pyridylnicotinamide and S/N-containing dicarboxylate mixed ligands. Chem. Res. Chin. Univ. 30, 709–714 (2014). https://doi.org/10.1007/s40242-014-4128-5

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  • DOI: https://doi.org/10.1007/s40242-014-4128-5

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