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Crystal engineering of multiple-component organic compound: Organic co-crystals of the functional groups of carboxyl and amino with persistent hydrogen bonding motifs

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Abstract

Three small organic molecular co-crystal compounds (C3N6H6)·(C6H10O4)·H2O(1), C3H8N2O(3) and (H4btec)2·(4,4′-bipy)(4)(H4btec=1,2,4,5-benzenetetracarboxylic acid, 4,4′-bipy=4,4′-bipyridine) and one coordination supramolecular compound [Mn(C2O4)(H2O)2]·C6H11NO2(2) were synthesized by hydrothermal reaction. They were characterized by elemental analysis, infrared(IR) spectroscopy and single crystal X-ray diffraction(XRD). Structural analyses reveal that these 2D or 3D supramolecular networks of the compounds were formed by \(C---H \cdots O\), \(N---H \cdots O\), \(N---H \cdots N\), \(O---H \cdots O\) and \(O---H \cdots N\) hydrogen bonds. Therein, the functional groups of -COOH, -NH2 and -OH play important roles in constructing supramolecular architectures.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, P. R. China

    Ge Song, Na Xing, Chen Chen, Hui Shan & Yong-heng Xing

  2. College of Life Science, Liaoning Normal University, Dalian, 116029, P. R. China

    Feng-ying Bai

Authors
  1. Ge Song
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  2. Feng-ying Bai
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  3. Na Xing
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  4. Chen Chen
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  5. Hui Shan
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  6. Yong-heng Xing
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Corresponding authors

Correspondence to Feng-ying Bai or Yong-heng Xing.

Additional information

Supported by the National Natural Science Foundation of China(No.21071071) and the Doctor Starting Foundation of Liaoning Province of China(No.20111067).

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Song, G., Bai, Fy., Xing, N. et al. Crystal engineering of multiple-component organic compound: Organic co-crystals of the functional groups of carboxyl and amino with persistent hydrogen bonding motifs. Chem. Res. Chin. Univ. 29, 408–413 (2013). https://doi.org/10.1007/s40242-013-2327-0

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  • DOI: https://doi.org/10.1007/s40242-013-2327-0

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