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Syntheses and supramolecular structures of two nickel(II) compounds based on two thiosemicarbazone ligands

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Abstract

Two new compounds, [Ni2(L1)(Py)6]Py·CH3OH(1) and [Ni3(L2)2(Py)4]·2DMF(2)(H4L1=N,N′-bisalicyl-bisthiocarbamide; H3L2=3-hydroxyl-2-naphthalene thiosemicarbazide; Py=pyridine; DMF=dimethyl fumarate), based upon two thiosemicarbazone ligands have been obtained and characterized by elemental analysis, Fourier transform infrared(FTIR) and X-ray diffraction(XRD). Compound 1 possesses a binuclear cluster, in which the bisalicylbisthiocarbamide acts as a hexadentate bridge. Compound 2 exhibits a linear trinuclear cluster with the triply-deprotonated ligand acting as pentadentate bridge. C—H…O, C—H…π and C—H…S weak interactions further link these molecules to form interesting supramolecular networks.

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Authors and Affiliations

  1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, P. R. China

    Cheng-juan Li, Ze-jing Feng, Xiao-juan Zhao, Su-na Wang & Jian-min Dou

Authors
  1. Cheng-juan Li
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  2. Ze-jing Feng
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  3. Xiao-juan Zhao
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  4. Su-na Wang
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  5. Jian-min Dou
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Corresponding author

Correspondence to Jian-min Dou.

Additional information

Supported by the National Natural Science Foundation of China(No.21141003), the Natural Science Foundation of Shandong Province of China(No.ZR2012BQ023) and the Natural Science Foundation of Liaocheng University of China(No.X09011).

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Li, Cj., Feng, Zj., Zhao, Xj. et al. Syntheses and supramolecular structures of two nickel(II) compounds based on two thiosemicarbazone ligands. Chem. Res. Chin. Univ. 29, 414–418 (2013). https://doi.org/10.1007/s40242-013-2275-8

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  • DOI: https://doi.org/10.1007/s40242-013-2275-8

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