Abstract
The effect of cooling rate on microstructure and effective grain size (EGS) of a Ni–Cr–Mo–B high-strength steel has been studied by dilatometer, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and electron backscattered diffraction (EBSD). The results show that the microstructure of the Ni–Cr–Mo–B steel is dependent on cooling rate in the following sequence: lath martensite (LM), mixed LM and lath bainite (LB), mixed LB and granular bainite (GB) and GB. The critical cooling rates for appearance of LB and GB are about 10 °C/s and 0.5 °C/s, respectively. The LM (> 10 °C/s) consists of few blocky regions with a width of several micros. Compared with the lath regions, the blocky regions in LM form at higher actual transformation temperatures during cooling. The blocky region area percentage in LM keeps almost constant about 8% at different cooling rates (> 10 °C/s) due to similar martensite transformation starting temperature (Ms). The LB percentage in mixed LM/LB increases gradually with decreasing cooling rate (10–0.5 °C/s). The EBSD results show that different microstructures have different EGS. The mixed LM/LB exhibits the smallest EGS due to the separation of the prior austenite grains by the pre-formed LB and the refinement of the LM. Meanwhile, the mixed LM/LB at different cooling rates (10–0.5 °C/s) exhibits almost the same EGS because the LB and LM in the mixed LM/LB have a similar high-angle grain boundary density and similar EGS. Because the blocky regions contain few high-angle grain boundaries and have similar area percentages in the LM, the LM at different cooling rates (> 10 °C/s) exhibits almost the same EGS. The ferrite in GB exhibits as a whole with few high-angle grain boundaries; thus, the mixed LB/GB exhibits the largest EGS.
Similar content being viewed by others
References
Q.H. Wang, Q.B. Ye, Z.D. Wang, L.Y. Kan, H.T. Wang, Metals 10, 572 (2020)
B.S. Xie, Q.W. Cai, Y. Yun, G.S. Li, Z. Ning, Mater. Sci. Eng. A 680, 454 (2017)
H.B. Liu, H.Q. Zhang, J.F. Li, Metals 8, 628 (2018)
T. Zhou, H. Yu, S.Y. Wang, Steel Res. Int. 88, 1700132 (2017)
Z.Y. Gao, Dissertation, University of Science and Technology Beijing, 2016
S.Q. Zhang, X.F. Hu, Y.B. Du, H.C. Jiang, H.Y. Pang, L.J. Rong, Acta Metall. Sin. 56, 1227 (2020)
T. Zhou, H. Yu, S.Y. Wang, Mater. Sci. Eng. A 658, 150 (2016)
D.S. Liu, B.G. Cheng, Y.Y. Chen, Metall. Mater. Trans. A 44, 440 (2013)
X.Y. Wang, T. Pan, H. Wang, H. Su, X.Y. Li, X.Z. Cao, Acta Metall. Sin. 48, 401 (2012)
Y. You, C.J. Shang, N. Wenjin, S. Subramanian, Mater. Sci. Eng. A 558, 692 (2012)
Z. Guo, C.S. Lee, J.W. Morris, Acta Mater. 52, 5511 (2004)
G.H. Gao, H. Zhang, B.Z. Bai, Acta Metall. Sin. 47, 513 (2011)
X.H. Xi, J.L. Wang, L.Q. Chen, Z.D. Wang, Acta Metall Sin. -Engl. Lett. 34, 617 (2020)
L. Morsdorf, C.C. Tasan, D. Ponge, D. Raabe, Acta Mater. 95, 366 (2015)
Z.H. Jiang, P. Wang, D.Z. Li, Y.Y. Li, Mater. Sci. Eng. A 699, 165 (2017)
J. Hu, L.X. Du, H. Liu, G.S. Sun, H. Xie, H.L. Yi, R.D.K. Misra, Mater. Sci. Eng. A 647, 144 (2015)
B. Hutchinson, J. Hagström, O. Karlsson, D. Lindell, M. Tornberg, F. Lindberg, M. Thuvander, Acta Mater. 59, 5845 (2011)
S. Morito, X. Huang, T. Furuhara, T. Maki, N. Hansen, Acta Mater. 54, 5323 (2006)
W.T. Zhu, J.J. Cui, Z.Y. Chen, Y. Zhao, L.Q. Chen, Acta Metall. Sin. -Engl. Lett. (2021)
H. Duan, Y.Y. Shan, K. Yang, X.B. Shi, W. Yan, Y. Ren, Acta Metall. Sin. -Engl. Lett. 34, 639 (2020)
J.H. Chen, Y. Kikuta, T. Araki, M. Yoneda, Y. Matsuda, Acta Mater. 32, 1779 (1984)
S. Ramesh Babu, T. Nyyssönen, M. Jaskari, A. Järvenpää, T.P. Davis, S. Pallaspuro, J. Kömi, D. Porter, Metals 9, 1255 (2019)
I.V. Ryaposov, L.M. Kleiner, A.A. Shatsov, E.A. Noskova, Metal Sci. Heat Treat. 50, 435 (2008)
N. Takayama, G. Miyamoto, T. Furuhara, Acta Mater. 145, 154 (2018)
A. Shibata, S. Morito, T. Furuhara, T. Maki, Acta Mater. 57, 483 (2009)
Y.L. Zhou, T. Jia, X.J. Zhang, Z.Y. Liu, R.D.K. Misra, Mater. Sci. Eng. A 626, 352 (2015)
J. Hidalgo, M.J. Santofimia, Metall. Mater. Trans. A 47, 5288 (2016)
J.W. Morris Jr., ISIJ Int. 48, 1063 (2008)
T. Hanamura, S. Torizuka, S. Tamura, S. Enokida, H. Takechi, ISIJ Int. 53, 2218 (2013)
C.Y. Zhang, Q.F. Wang, J.X. Ren, R.X. Li, M.Z. Wang, F.C. Zhang, Z.S. Yan, Mater. Des. 36, 220 (2012)
Y.X. Zheng, F.M. Wang, C.R. Li, Y.L. Li, J. Cheng, R.F. Cao, ISIJ Int. 58, 1126 (2018)
N. Takayama, G. Miyamoto, T. Furuhara, Acta Mater. 60, 2387 (2012)
Acknowledgements
This work is financially supported by the Liaoning Revitalization Talents Program (No. XLYC1907143) and the Strategic Priority Research Program of the Chinese Academy of Sciences (Nos. XDC04000000 and XDA28040200).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors state that there are no conflicts of interest to disclose.
Additional information
Available online at http://link.springer.com/journal/40195.
Rights and permissions
About this article
Cite this article
Zhang, S., Hu, X., Jiang, H. et al. Effect of Cooling Rate on Microstructure and Effective Grain Size for a Ni–Cr–Mo–B High-Strength Steel. Acta Metall. Sin. (Engl. Lett.) 35, 1862–1872 (2022). https://doi.org/10.1007/s40195-022-01422-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-022-01422-6