Abstract
The effect of impurity element Fe on corrosion behavior of AZ61 magnesium alloys in various states has been investigated by immersion test and hydrogen evolution measurements in 3.5% sodium chloride solution. The corrosion rate is found to relay on the impurity Fe concentration in the alloys and decreases with decreasing Fe content. When Fe content drops from 150 ppm to 10 ppm, the corresponding corrosion rates under as-cast and solution treatment conditions are reduced from 8.54 mm/a and 8.61 mm/a to 2.54 mm/a and 0.21 mm/a, respectively. The corrosion pattern of the AZ61 alloys is the localized corrosion, and the galvanic couples are formed among the impurity particles, second-phase particles and the matrix. The Fe impurity particles tend to act as main cathodic to form micro-galvanic cell with the α-Mg matrix, which is harmful for corrosion resistance of AZ61 alloy.
Similar content being viewed by others
References
T. Morishige, K. Ueno, M. Okano, T. Goto, E. Nakamura, T. Takenaka, Mater. Trans. 55, 1506 (2014)
M. Rashad, F. Pan, M. Asif, X. Chen, J. Magnes. Alloys 5, 271 (2017)
C. Zhao, X. Chen, F. Pan, J. Wang, S. Gao, T. Tu, C. Liu, J. Yao, A. Atrens, J. Mater. Sci. Technol. 35, 142 (2019)
H. Matsubara, Y. Ichige, K. Fujita, H. Nishiyama, K. Hodouchi, Corros. Sci. 66, 203 (2013)
S. Arthanari, R. Nallaiyan, S.K. Seon, J. Magnes. Alloys 5, 277 (2017)
C. Zhao, X. Chen, F. Pan, S. Gao, D. Zhao, X. Liu, Mater. Sci. Eng. A 713, 244 (2018)
H. Zhao, L.Q. Wang, Y.P. Ren, B. Yang, S. Li, G.W. Qin, Acta Metall. Sin. (Engl. Lett.) 31, 575 (2018)
G.L. Song, A. Atrens, Adv. Eng. Mater. 9, 177 (2007)
S.H. Adsul, K.R.C.S. Raju, B.V. Sarada, S.H. Sonawane, R. Subasri, J. Magnes. Alloys 6, 299 (2018)
L.X. Wang, R.B. Song, C.H. Cai, J.Y. Li, Acta Metall. Sin. (Engl. Lett.) 32, 10 (2019)
G. Song, B. Johannesson, S. Hapugoda, D. St. John, Corros. Sci. 46, 955 (2004)
G. Song, D. St. John, Corros. Sci. 46, 1381 (2004)
Y. Zhang, C. Yan, F. Wang, W. Li, Corros. Sci. 47, 2816 (2005)
J. Moscovici, M. Benzakour, S. Decker, C. Carnes, K. Klabunde, A. Michalowicz, J. Synchrotron Radiat. 8, 925 (2001)
T. Zheng, Y. Hu, S. Yang, J. Magnes. Alloys 5, 404 (2017)
M. Liu, P.J. Uggowitzer, P. Schmutz, A. Atrens, JOM 60, 39 (2008)
H.R. Bakhsheshi-Rad, E. Hamzah, R. Ebrahimi-Kahrizsangi, M. Daroonparvar, M. Medraj, Vacuum 125, 185 (2016)
B.J. Wang, J.Y. Luan, D.K. Xu, J. Sun, C.Q. Li, E.H. Han, Acta Metall. Sin. (Engl. Lett.) 32, 1 (2019)
G.L. Makar, J. Kruger, Int. Mater. Rev. 38, 138 (1993)
G. Song, Adv. Eng. Mater. 7, 563 (2005)
M.C. Zhao, M. Liu, G.L. Song, A. Atrens, Adv. Eng. Mater. 10, 93 (2008)
G. Song, A. Atrens, Adv. Eng. Mater. 5, 837 (2003)
M. Inoue, M. Iwai, K. Matuzawa, S. Kamado, Y. Kojima, J. Jpn. Inst. Light Met. 48, 257 (1998)
M.C. Zhao, M. Liu, A. Atrens, Adv. Eng. Mater. 10, 104 (2008)
M. Zhao, M. Liu, G. Song, A. Atrens, Corros. Sci. 50, 1939 (2008)
M. Zhao, L. Ming, G. Song, A. Atrens, Corros. Sci. 50, 3168 (2008)
G. Song, A. Atrens, D.S. John, X. Wu, J. Nairn, Corros. Sci. 39, 1981 (1997)
L. Yang, X. Zhou, S.M. Liang, R. Schmid-Fetzer, Z. Fan, G. Scamans, J. Robson, G. Thompson, J. Alloys Compd. 619, 396 (2015)
N.I.Z. Abidin, D. Martin, A. Atrens, Corros. Sci. 53, 862 (2011)
Z. Qiao, Z. Shi, N. Hort, N.I.Z. Abidin, A. Atrens, Corros. Sci. 61, 185 (2012)
F. Cao, Z. Shi, J. Hofstetter, P.J. Uggowitzer, G. Song, M. Liu, A. Atrens, Corros. Sci. 75, 78 (2013)
A. Atrens, G.L. Song, M. Liu, Z. Shi, F. Cao, M.S. Dargusch, Adv. Eng. Mater. 17, 400 (2015)
M. Liu, P.J. Uggowitzer, A.V. Nagasekhar, P. Schmutz, M. Easton, G.L. Song, A. Atrens, Corros. Sci. 51, 602 (2009)
Y. Wang, Foundry 50, 61 (2001)
L. Peng, J. Chang, X. Guo, A. Atrens, W. Ding, Y. Peng, J. Appl. Electrochem. 39, 913 (2009)
N.D. Nam, M.Z. Bian, M. Forsyth, M. Seter, M. Tan, K.S. Shin, Corros. Sci. 64, 263 (2012)
Z. Pu, G.L. Song, S. Yang, J.C. Outeiro, O.W.D. Jr, D.A. Puleo, I.S. Jawahir, Corros. Sci. 57, 192 (2012)
G. Song, A. Atrens, M. Dargusch, Corros. Sci. 41, 249 (1998)
G. Song, A.L. Bowles, D.H. Stjohn, Mater. Sci. Eng. A 366, 74 (2004)
D. Eliezer, P. Uzan, E. Aghion, in Magnesium Alloys 2000, ed. by Y. Kojima, T. Aizawa, K. Higashi, S. Kamado, Materials Science Forum, Osaka, 27–30 Jan 2003
F. Pan, X. Chen, T. Yan, T. Liu, J. Mao, W. Luo, Q. Wang, J. Peng, A. Tang, B. Jiang, J. Magnes. Alloys 4, 8 (2016)
F. Pan, M. Yang, X. Chen, J. Mater. Sci. Technol. 32, 1211 (2016)
Pandat is a software package for calculating phase diagrams and thermodynamic properties of multi-component alloys. CompuTherm LLC. http://www.computherm.com/index.php?route=common/home (2018)
Z. Shi, A. Atrens, Corros. Sci. 53, 226 (2011)
A. Pardo, M.C. Merino, A.E. Coy, R. Arrabal, F. Viejo, E. Matykina, Corros. Sci. 50, 823 (2008)
X. Zhou, Y. Huang, Z. Wei, Q. Chen, F. Gan, Corros. Sci. 48, 4223 (2006)
J.I. Kim, H.N. Nguyen, B.S. You, Y. Kim, Scr. Mater. 162, 355 (2019)
R. Ambat, N. Aung, W. Zhou, Corros. Sci. 42, 1433 (2000)
M.M. Avedesian, H. Baker, Magnesium and Magnesium Alloys ASM Specialty Handbook (ASM International, Ohio, 1999), pp. 56–77
X. Guo, J. Chang, S. He, W. Ding, X. Wang, Electrochim. Acta 52, 2570 (2007)
J.H. Nordlien, S. Ono, N. Masuko, K. Nisancioglu, Corros. Sci. 39, 1397 (1997)
G.L. Song, A. Atrens, Adv. Eng. Mater. 1, 11 (1999)
G.L. Song, Z. Xu, Corros. Sci. 54, 97 (2012)
Acknowledgements
This work was financially supported by the National Key R&D Program of China (No. 2016YFB0301100), the National Natural Science Foundation of China (No. 51571043) and the Fundamental Research Funds for the Central Universities (Nos. 2018CDJDCL0019, cqu2018CDHB1A08 and 2018CDGFCL0005).
Author information
Authors and Affiliations
Corresponding author
Additional information
Available online at http://link.springer.com/journal/40195
Rights and permissions
About this article
Cite this article
Dai, Y., Chen, XH., Yan, T. et al. Improved Corrosion Resistance in AZ61 Magnesium Alloys Induced by Impurity Reduction. Acta Metall. Sin. (Engl. Lett.) 33, 225–232 (2020). https://doi.org/10.1007/s40195-019-00914-2
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-019-00914-2