Abstract
In this work, the electrochemical behaviors of SAM2X5 Fe-based amorphous alloy coating and hard chromium coating were comparatively studied in 3.5 wt% NaCl solution. In comparison with the hard chromium coating, the SAM2X5 coating exhibited a wider and stable passive region with lower passive current density in the potentiodynamic polarization and showed a considerably lower current density at different anodic potentials in the potentiostatic polarization. In order to understand the passivation mechanism of the Fe-based amorphous coating, the components of the passive films formed at various polarization potentials were examined by X-ray photoelectron spectroscopy. The synergistic effect of Mo, W, Mn and Cr in the passive films was systemically analyzed. It has been revealed that Mo and W facilitate the formation of compact and stable Cr2O3 passive film at lower potentials, and the substantial enrichment of Mn in the passive film enhances the passivation ability at relatively higher potentials. The deep understanding of the passivation characteristics in multicomponent alloy systems could provide a guide for the design of corrosion-resistant amorphous alloy coatings for engineering applications.
Similar content being viewed by others
References
A. Inoue, B.L. Shen, C.T. Chang, Acta Mater. 52, 4093 (2004)
S.J. Pang, T. Zhang, K. Asami, A. Inoue, Acta Mater. 50, 489 (2002)
J.R. Scully, A. Gebert, J.H. Payer, J. Mater. Res. 22, 302 (2007)
C. Suryanarayana, A. Inoue, Int. Mater. Rev. 58, 131 (2013)
H.S. Ni, X.H. Liu, X.C. Chang, W.L. Hou, W. Liu, J.Q. Wang, J. Alloys Compd. 467, 163 (2009)
K.V. Arun, C.S. Venkatesha, J. Mater. Process. Technol. 207, 336 (2008)
S.A. Katz, H. Salem, J. Appl. Toxicol. 13, 217 (1993)
N. Espallargas, J. Berget, J.M. Guilemany, A.V. Benedetti, P.H. Suegama, Surf. Coat. Technol. 202, 1405 (2008)
J.M. Guilemany, N. Espallargas, P.H. Suegama, A.V. Benedetti, J. Fernandez, J. Therm. Spray Technol. 14, 335 (2005)
C. Zhang, K.C. Chan, Y. Wu, L. Liu, Acta Mater. 60, 4152 (2012)
G. Wang, Z. Huang, P. Xiao, X. Zhu, J. Manuf. Process. 22, 34 (2016)
S.D. Zhang, J. Wu, W.B. Qi, J.Q. Wang, Corros. Sci. 110, 57 (2016)
J. Farmer, J.S. Choi, C. Saw, J. Haslam, D. Day, P. Hailey, T. Lian, R. Rebak, J. Perepezko, J. Payer, D. Branagan, B. Beardsley, A. D’Amato, L. Aprigliano, Metall. Mater. Trans. A 40, 1289 (2009)
S.D. Zhang, W.L. Zhang, S.G. Wang, X.J. Gu, J.Q. Wang, Corros. Sci. 93, 211 (2015)
Y. Wang, S.L. Jiang, Y.G. Zheng, W. Ke, W.H. Sun, J.Q. Wang, Corros. Sci. 63, 159 (2012)
J. Farmer, J. Haslam, S. Day, T. Lian, C. Saw, P. Hailey, J. Choi, R. Rebak, N. Yang, J. Payer, J. Mater. Res. 22, 2297 (2007)
K. Hashimoto, Corrosion 58, 715 (2002)
C.O.A. Olsson, D. Landolt, Electrochim. Acta 48, 1093 (2003)
U.R. Evans, G.M. Schmid, N. Hackerman, J. Electrochem. Soc. 109, 544 (1962)
M.J. Duarte, J. Klemm, S.O. Klemm, K.J.J. Mayrhofer, M. Stratmann, S. Borodin, A.H. Romero, M. Madinehei, D. Crespo, J. Serrano, S.S.A. Gerstl, P.P. Choi, D. Raabe, F.U. Renner, Science 341, 372 (2013)
K. Hashimoto, K. Asami, K. Teramoto, Corros. Sci. 19(1), 3–14 (1979)
J.N. Wanklyn, Corros. Sci. 21, 211 (1981)
C.R. Clayton, Y.C. Lu, J. Electrochem. Soc. 133, 2465 (1986)
G.P. Halada, C.R. Clayton, J. Vac. Sci. Technol. A 11, 2342 (1993)
N. Bui, A. Irhzo, F. Dabosi, Y. Limouzin-Maire, Corrosion 39, 491 (1983)
M.P. Ryan, D.E. Williams, R.J. Chater, B.M. Hutton, D.S. McPhail, Nature 415, 770 (2002)
A. Pardo, M.C. Merino, A.E. Coy, F. Viejo, R. Arrabal, E. Matykina, Corros. Sci. 50, 1796 (2008)
J. Zhang, W. Zhang, C. Yan, K. Du, F. Wang, Electrochim. Acta 55, 560 (2009)
H. Fang, X. Hui, G. Chen, J. Alloys Compd. 464, 292 (2008)
Z.B. Zheng, Y.G. Zheng, W.H. Sun, J.Q. Wang, Corros. Sci. 82, 115 (2014)
Z.M. Wang, J. Zhang, X.C. Chang, W.L. Hou, J.Q. Wang, Corros. Sci. 52, 1342 (2010)
T.S. Li, L. Liu, B. Zhang, Y. Li, X.L. Wang, F.H. Wang, Electrochem. Commun. 52, 80 (2015)
N. Wint, A.C.A. de Vooys, H.N. McMurray, Electrochem. Acta 203, 326 (2016)
S.C. Kwon, M. Kim, S.U. Park, D.Y. Kim, D. Kim, K.S. Nam, Y. Choi, Surf. Coat. Technol. 183, 151 (2004)
C.D. Stockbridge, P.B. Sewell, M. Cohen, J. Electrochem. Soc. 108, 928 (1961)
B. Brox, I. Olefjord, Surf. Interface Anal. 13, 3 (1988)
K. Hashimoto, K. Asami, A. Kawashima, H. Habazaki, E. Akiyama, Corros. Sci. 49, 42 (2007)
H.J. Park, H.W. Lee, J. Electrochem. Soc. 9, 6687 (2014)
K. Asami, M. Naka, K. Hashimoto, T. Masumoto, J. Electrochem. Soc. 127, 2130 (1980)
H. Habazaki, A. Kawashima, K. Asami, K. Hashimoto, J. Electrochem. Soc. 138, 76 (1991)
K. Asami, K. Hashimoto, S. Shimodaira, Corros. Sci. 17, 713 (1977)
S.D. Zhang, Z.M. Wang, X.C. Chang, W.L. Hou, J.Q. Wang, Corros. Sci. 53, 3007 (2011)
M.R. Alexander, G.E. Thompson, X. Zhou, G. Beamson, N. Fairley, Surf. Interface Anal. 34, 485 (2002)
M. Bojinov, G. Fabricius, T. Laitinen, T. Saario, J. Electrochem. Soc. 145, 2043 (1998)
R. Goetz, J. Laurent, D. Landolt, Corros. Sci. 25, 1115 (1985)
Z.M. Wang, Y.T. Ma, J. Zhang, W.L. Hou, X.C. Chang, J.Q. Wang, Electrochim. Acta 54, 261 (2008)
Acknowledgements
This work was supported by the National Natural Science Foundation of China (Nos. 51471166, 51131006 and 51171119) and the College Youth Scholar Fostering Program of Liaoning Province (No. LJQ2014015). The authors thank W.H. Sun and B.J. Yang for their assistance in the coating preparation.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Available online at http://link.springer.com/journal/40195
Rights and permissions
About this article
Cite this article
Tian, WP., Yang, HW. & Zhang, SD. Synergistic Effect of Mo, W, Mn and Cr on the Passivation Behavior of a Fe-Based Amorphous Alloy Coating. Acta Metall. Sin. (Engl. Lett.) 31, 308–320 (2018). https://doi.org/10.1007/s40195-017-0604-5
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-017-0604-5