Skip to main content

Advertisement

SpringerLink
Log in

Enhanced Mechanical Properties, Corrosion Behavior and Bioactivity of Ti-based Bulk Metallic Glasses with Minor Addition Elements

  • Published:
Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

In this research, corrosion behavior, mechanical properties and bioactivity of Ti–Zr–Cu–Pd–Sn bulk metallic glasses with minor addition of Au, Pt, Nb or Ta elements were investigated. The results revealed that minor additions of the elements were beneficial to enhancing mechanical properties and corrosion resistance of Ti-based bulk metallic glasses. Minor addition of the element (especially with Nb and Ta addition) results in the improvement in plastic deformation ability due to the existing of nanoparticles with a size smaller than 10 nm in glassy matrix, inhibiting the deformation of the shear bonds. Enrichments of Ti and Zr elements in oxide layer were responsible for high corrosion resistance. The bioactivity of Ti-based bulk metallic glasses was also investigated. The best combination of large plastic deformation ability, good corrosion resistance and bioactivity in Ti40Zr10Cu33Pd14Sn2Ta1 BMG was obtained.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. A. Inoue, Acta Mater. 48, 279 (2000)

    Article  Google Scholar 

  2. D. Cao, Y. Wu, H. Wang, X.J. Liu, Z.P. Lu, Acta Metall. Sin. (Engl. Lett.) 29, 173 (2016)

  3. J.C. Qiao, J.M. Pelletier, J. Mater. Sci. Technol. 30, 523 (2014)

    Article  Google Scholar 

  4. H.B. Ba, L.M. Dong, Z.Q. Zhang, D.S. Xu, R. Yang, Acta Metall. Sin. (Engl. Lett.) 29 (2016). doi: 10.1007/s40195-016-0443-9

  5. F.X. Qin, X.M. Wang, G.Q. Xie, S.L. Zhu, A. Kawashima, K. Asami, A. Inoue, Mater. Trans. 48, 167 (2007)

    Article  Google Scholar 

  6. S.L. Zhu, X.M. Wang, F.X. Qin, A. Inoue, Mater. Sci. Eng. A 459, 233 (2007)

    Article  Google Scholar 

  7. S.L. Zhu, G.Q. Xie, F.X. Qin, X.M. Wang, A. Inoue, Mater. Trans. 53, 500 (2012)

    Article  Google Scholar 

  8. F.X. Qin, X.M. Wang, A. Inoue, Mater. Trans. 51, 529 (2010)

    Article  Google Scholar 

  9. F.X. Qin, X.M. Wang, G.Q. Xie, A. Inoue, Intermetallics 6, 1026 (2008)

    Article  Google Scholar 

  10. J.J. Oak, D.V. Louzguine-Luzgin, A. Inoue, J. Mater. Res. 22, 1346 (2007)

    Article  Google Scholar 

  11. R. Wang, Y. Wang, J. Yang, J. Sun, L. Xiong, J. Non-Cryst. Solids 411, 45 (2015)

    Article  Google Scholar 

  12. U. Kuhn, J. Eckert, N. Mattern, L. Schultz, Appl. Phys. Lett. 80, 2478 (2002)

    Article  Google Scholar 

  13. C.H. Yim, W.L. Johnson, Appl. Phys. Lett. 71, 3808 (1997)

    Article  Google Scholar 

  14. R. Busch, H.C. Yim, U. Koster, W.L. Johnson, Acta Mater. 47, 2455 (1999)

    Article  Google Scholar 

  15. F.X. Qin, X.M. Wang, A. Inoue, Intermetallics 15, 1377 (2007)

    Article  Google Scholar 

  16. J.C. Qiao, J.M. Pelletier, C. Esnour, Y. Liu, H. Kato, J. Alloy Compd. 607, 139 (2014)

    Article  Google Scholar 

  17. J. Tan, F.S. Pan, Y. Zhang, W. Zhang, M. Stoic, B.A. Sun, U. Kuhn, J. Eckert, Mater. Sci. Eng. A 539, 124 (2012)

    Article  Google Scholar 

  18. T. Kokubo, F. Miyaji, H.M. Kim, T. Nakamura, J. Am. Ceram. Soc. 79, 1127 (1996)

    Article  Google Scholar 

  19. A. Inoue, Mater. Trans., JIM 36, 866 (1995)

    Article  Google Scholar 

  20. Z.P. Lu, H. Tan, Y. Li, S.C. Ng, Scr. Mater. 42, 667 (2000)

    Article  Google Scholar 

  21. Z.P. Lu, C.T. Liu, Acta Mater. 50, 3501 (2002)

    Article  Google Scholar 

  22. S.J. Pang, T. Zhang, K. Asami, A. Inoue, J. Mater. Res. 18, 1652 (2003)

    Article  Google Scholar 

  23. C.L. Qin, W. Zhang, K. Asami, H. Kimura, X.M. Wang, A. Inoue, Acta Mater. 54, 3713 (2006)

    Article  Google Scholar 

  24. J. Li, X. Xu, T.C. Hufnagel, Microsc. Microanal. 9, 509 (2003)

    Article  Google Scholar 

  25. T.C. Hufnagel, S. Brennan, Phys. Rev. B 67, 014203-1-8 (2003)

  26. C. Fan, R.T. Ott, T.C. Hufnagel, Appl. Phys. Lett. 81, 1020 (2002)

    Article  Google Scholar 

  27. J.C. Lee, Y.C. Kim, J.P. Ahn, H.S. Kim, S.H. Lee, B.J. Lee, Acta Mater. 52, 1525 (2004)

    Article  Google Scholar 

  28. G. He, J. Eckert, W. Loser, L. Schultz, Nat. Mater. 2, 33 (2003)

    Article  Google Scholar 

  29. L.Q. Xing, C. Bertrand, J.P. Dallas, M. Cornet, Mater. Lett. 34, 90 (1998)

    Article  Google Scholar 

  30. K. Dasa, A. Bandyopadhyay, Y.M. Gupta, Mater. Sci. Eng. A 394, 302 (2005)

    Article  Google Scholar 

  31. J.S. Langer, Scr. Mater. 54, 375 (2006)

    Article  Google Scholar 

  32. F.X. Qin, X.M. Wang, T. Wada, G.Q. Xie, K. Asami, A. Inoue, Mater. Trans. 50, 605 (2009)

    Article  Google Scholar 

  33. H.B. Wen, J.R. Wijn, F.Z. Cui, K. Groot, J. Biomed. Mater. Res. 41, 227 (1998)

    Article  Google Scholar 

  34. A.H. Heuer, D.J. Fink, V.J. Laraia, J.L. Arias, P.D. Calvert, K. Kendall, G.L. Messing, J. Blackwell, P.C. Rieke, D.H. Thompson, A.P. Wheeler, A. Veis, A.I. Calpan, Science 255, 1098 (1992)

    Article  Google Scholar 

  35. A.K. Shukla, R. Balasubramaniam, Corros. Sci. 48, 1696 (2006)

    Article  Google Scholar 

  36. H.B. Wen, J. Brink, J.R. Wijn, F.Z. Cui, K. Groot, J. Cryst. Growth 186, 616 (1998)

    Article  Google Scholar 

  37. B. Feng, J.Y. Chen, S.K. Qi, L. He, J.Z. Zhao, X.D. Zhang, Biomaterials 23, 173 (2002)

    Article  Google Scholar 

  38. X.J. Yang, R.X. Hu, S.L. Zhu, C.Y. Li, M.F. Chen, L.Y. Zhang, Z.D. Cui, Scr. Mater. 54, 1457 (2006)

    Article  Google Scholar 

  39. S.L. Zhu, X.J. Yang, Z.D. Cui, J. Alloy Compd. 504, S168 (2010)

    Article  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Natural Science Foundation of China (Grant No. 51301091), the Natural Science Foundation of Jiangsu Province (Grant No. BK20151536) and the Fundamental Research Funds for the Central Universities (Grant No. AE16001).

Author information

Authors and Affiliations

  1. School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Feng-Xiang Qin, Yang Zhou, Chuan Ji & Sen Yang

  2. College of Materials Science and Engineering, Nanjing TECH University, Nanjing, 210009, China

    Zhen-Hua Dan

  3. Institute for Materials Research, Tohoku University, Sendai, 980-8577, Japan

    Feng-Xiang Qin & Guo-Qiang Xie

Authors
  1. Feng-Xiang Qin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yang Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chuan Ji
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhen-Hua Dan
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Guo-Qiang Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sen Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Feng-Xiang Qin.

Additional information

Available online at http://link.springer.com/journal/40195

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Qin, FX., Zhou, Y., Ji, C. et al. Enhanced Mechanical Properties, Corrosion Behavior and Bioactivity of Ti-based Bulk Metallic Glasses with Minor Addition Elements. Acta Metall. Sin. (Engl. Lett.) 29, 1011–1018 (2016). https://doi.org/10.1007/s40195-016-0468-0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40195-016-0468-0

Keywords

Search

Navigation