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TZM/graphite interface behavior in high-temperature brazing by Ti-based brazing filler materials

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Abstract

Graphite was successfully brazed to TZM alloy using the Ti-56Ni, Ti-8.5Si, Ti-33Cr and Ti-30V-3Mo brazing filler materials, respectively, and the corresponding brazing temperatures ranged from 1300 to 1700 °C. The results show that the microstructure of TZM/graphite braze metal was composed of NiTi and Ni3Ti compounds when using Ti-56Ni brazing filler, and the discontinuous TiC compounds were found at the Ti-56Ni/graphite side. When using the Ti-8.5Si, Ti-33Cr and Ti-30V-Mo brazing fillers, the metallurgical combination was obtained due to the formation of the Ti-Mo solid solution at the TZM/brazing filler side and the TiC reaction layer at the graphite/brazing filler side. The fracture was occurred at the interface of TiC/graphite during shear test, which indicated the poorer bonding strength between the graphite and granular TiC.

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References

  1. Yamada Y, Yanase M, Miura D, Chikuba K (2016) Novel heatsink for power semiconductor module using high thermal conductivity graphite. Microelectron Reliab 64:484–488

    Article  CAS  Google Scholar 

  2. Ghosh S, Chakraborty R, Dandapat N, Pal KS, Basu D (2012) Characterization of alumina–alumina/graphite/monel superalloy brazed joints. Ceram Int 38(1):663–670

    Article  CAS  Google Scholar 

  3. Dong L, Chen W, Hou L, Wang J, Song J (2017) Metallurgical and mechanical examinations of molybdenum/graphite joints by vacuum arc pressure brazing using Ti-Zr filler materials. J Mater Process Technol 249:39–45

    Article  CAS  Google Scholar 

  4. Mao Y, Peng L, Wang S, Xi L (2017) Microstructural characterization of graphite/CuCrZr joints brazed with CuTiH2Ni-based fillers. J Alloys Compd 716:81–87

    Article  CAS  Google Scholar 

  5. Zhang J, Wang T, Liu C, He Y (2014) Effect of brazing temperature on microstructure and mechanical properties of graphite/copper joints. Mater Sci Eng A 594:26–31

    Article  CAS  Google Scholar 

  6. He Y, Yang J, Shen H, Wang L, Gao Z (2016) Brazing graphite to hastelloy N superalloy using pure-Au filler metal: bonding mechanism and joint properties. Mater Des 104:1–9

    Article  CAS  Google Scholar 

  7. Yu W, Liu S, Liu X, Liu M, Shi W (2015) Interface reaction in ultrasonic vibration-assisted brazing of aluminum to graphite using Sn-Ag-Ti solder foil. J Mater Process Technol 221:285–290

    Article  CAS  Google Scholar 

  8. Leitner DLK, Knabl W, Eidenberger-Schober M, Huber K, Lorich A, Clemens H, Maier-Kiener V (2018) Grain boundary segregation engineering in as-sintered molybdenum for improved ductility. Scr Mater 156:60–63

    Article  CAS  Google Scholar 

  9. Zhang L, Pei J, Zhang L, Long J, Zhang J, JooNa S (2019) Laser seal welding of end plug to thin-walled nanostructured high-strength molybdenum alloy cladding with a zirconium interlayer. J Mater Process Technol 267:338–347

    Article  CAS  Google Scholar 

  10. Song XG, Han GH, Hu SP, Zhao HY, Li Y, Wang MR, Shi B (2019) Evaluation of TZM/ZrCp-W joint brazed with Ti-35Ni filler: microstructure and mechanical properties. Mater Sci Eng A 742:190–200

    Article  CAS  Google Scholar 

  11. Hatami Ramsheh H, Faghihi Sani MA, Kokabi AH (2013) Microstructure and mechanical properties of MoSi2–MoSi2 joints brazed by Ag-Cu-Zr interlayer. Mater Des 49:197–202

    Article  CAS  Google Scholar 

  12. Han G, Bian H, Zhao H, Song X, Li Y, Liu D, Cao J, Feng J (2018) Interfacial microstructure and mechanical properties of TZM alloy and ZrC particle reinforced tungsten composite joint brazed using Ti-61Ni filler. J Alloys Compd 747:266–275

    Article  CAS  Google Scholar 

  13. Tabernig B, Reheis N (2010) Joining of molybdenum and its application. Int J Refract Met Hard Mater 28(6):728–733

    Article  CAS  Google Scholar 

  14. Chan H, Liaw DW, Shiue RK (2004) Microstructural evolution of brazing Ti–6Al–4V and TZM using silver-based braze alloy. Mater Lett 58(7–8):1141–1146

    Article  CAS  Google Scholar 

  15. Han G, Wang Y, Zhao H, Song X, Cao J, Feng J (2017) Vacuum brazing of TZM alloy to ZrC particle reinforced W composite using Ti-28Ni eutectic brazing alloy. Int J Refract Met Hard Mater 69:240–246

    Article  CAS  Google Scholar 

  16. Song X, Tian X, Zhao H, Si X, Han G, Feng J (2016) Interfacial microstructure and joining properties of titanium-zirconium-molybdenum alloy joints brazed using Ti-28Ni eutectic brazing alloy. Mater Sci Eng A 653:115–121

    Article  CAS  Google Scholar 

  17. Wei-Hsing T, Tsung-Te C, Ching-Ti K, Wang S-Y, Biing-Jyh W (2018) Thermal diffusivity of graphite paper and its joint with alumina substrate. J Eur Ceram Soc 38(1):187–191

    Article  Google Scholar 

  18. Zhang L, Zhang B, Sun Z, Tian X, Lei M, Feng J (2019) Tailoring microstructure and mechanical performance of the graphite-Ni based superalloy brazed combination used for molten salt reactors through thermal exposure. J Alloys Compd 782:981–985

    Article  CAS  Google Scholar 

  19. Chen Z, Bian H, Hu S, Song X, Feng J (2018) Surface modification on wetting and vacuum brazing behavior of graphite using AgCu filler metal. Surf Coat Technol 348:104–110

    Article  CAS  Google Scholar 

  20. Mao Y, Yu S, Zhang Y, Guo B, Deng Q (2015) Microstructure analysis of graphite/Cu joints brazed with (Cu-50TiH2)+B composite filler. Fusion Eng Des 100:152–158

    Article  CAS  Google Scholar 

  21. Kimiaki N, Yoshihisa S, Yoshinari M, Kazuhiro N (2012) Characteristics of dissimilar laser-brazed joints of isotropic graphite to WC–Co alloy. Mater Sci Eng B 177(7):520–523

    Article  Google Scholar 

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Funding

This work is supported by Zhongyuan High Level Talents Special Support Plan (Grant No. 204200510031), and Zhengzhou Major Science and Technology Innovation Special Project (Grant No. 2019CXZX0065), and Open Fund of National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials (Grant No. HKDNM2019011).

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Correspondence to Long Weimin.

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Recommended for publication by Commission XVII - Brazing, Soldering and Diffusion Bonding

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Lu, Q., Long, W., Zhong, S. et al. TZM/graphite interface behavior in high-temperature brazing by Ti-based brazing filler materials. Weld World 64, 1877–1885 (2020). https://doi.org/10.1007/s40194-020-00967-3

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  • DOI: https://doi.org/10.1007/s40194-020-00967-3

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