Skip to main content
Log in

Brazing of porous copper foam/copper with amorphous Cu-9.7Sn-5.7Ni-7.0P (wt%) filler metal: interfacial microstructure and diffusion behavior

  • Research Paper
  • Published:
Welding in the World Aims and scope Submit manuscript

Abstract

In this work, brazing of porous copper foam (PCF) to copper (Cu) using amorphous Cu-9.7Sn-5.7Ni-7.0P (in weight, wt%) filler metal has been performed. PCF with different pore densities of 15 pore per inch (PPI), 25 PPI, and 50 PPI were sandwiched in between amorphous Cu-9.7Sn-5.7Ni-7.0P filler/Cu based plate. A brazed joint of Cu/Cu using amorphous Cu-9.7Sn-5.7Ni-7.0P filler was prepared for comparison purposes. The interfacial microstructures and mechanical properties of the brazed joint were investigated to study the joint ability after the brazing process. Scanning electron microscope (SEM) confirmed the interfacial microstructure by the formation of the diffusion layer (shown in light shaded area) and filler layer (gray island-shaped) for both Cu/Cu and Cu/PCF/Cu brazed joint. The X-ray diffraction (XRD) patterns identified the brittle phases of Cu3P and Ni3P, Cu and Cu6Sn5 phases at the diffusion layer. In the shear test, the strength value decreases with increase in the pore densities of PCF. The decreasing shear strength observed with an increase in the number of PPI in PCF is due to the formation of more cavities in Cu/PCF as the number of PPI in Cu/PCF increases.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Tatt TK, Muhamad N, Muchtar A, Sulong AB, Cherng NM (2016) Influence of sintering parameters on the compressive yield strength of stainless steel foams produced by the space holder method. Sains Malaysiana 45:653–658

    CAS  Google Scholar 

  2. Xia X, Chen X, Sun C, Li Z, Liu B (2017) International Journal of Heat and Mass Transfer Experiment on the convective heat transfer from airflow to skeleton in open-cell porous foams. Int J Heat Mass Transf 106:83–90

    Article  CAS  Google Scholar 

  3. Mancin S, Zilio C, Diani A, Rossetto L (2012) Experimental air heat transfer and pressure drop through copper foams. Exp Thermal Fluid Sci 36:224–232

    Article  CAS  Google Scholar 

  4. Nawaz K, Bock J, Jacobi AM (2017) Thermal-hydraulic performance of metal foam heat exchangers under dry operating conditions. Appl Therm Eng 119:222–232

    Article  Google Scholar 

  5. Boomsma K, Poulikakos D, Zwick F (2003) Metal foams as compact high performance heat exchangers. Mech Mater 35:1161–1176

    Article  Google Scholar 

  6. Luvata (2006) Brazing handbook (5th ed.). American Welding Society, United States of America

  7. Liu W, Li S, Li X, Gao X (1990) Crystallization of amorphous Cu-6Ni-10Sn-7P alloy ribbons. J Mater Sci 9:904–905

    CAS  Google Scholar 

  8. Zhang J, Yu W, Lu W (2016) Mechanical properties and microstructure of pure copper joints brazed with amorphous Cu68.5Ni15.7Sn9.3P6.5 filler metal. IJSSST 17:15–19

    CAS  Google Scholar 

  9. Weiyuan Y, Wenjiang L, Tiandong X (2013) Formation process of joints brazing with amorphous filler metal. Rare Metal Mater Eng 42:688–691

    Article  Google Scholar 

  10. Zhang PL, Yao S, Ding M, Lu FG, Lou SN (2010) Microstructural analysis in the vacuum brazing of copper to copper using a phosphor–copper brazing filler metal. Int J Mater Res 101:1436–1440

    Article  CAS  Google Scholar 

  11. Jacobson DM, Humpston G (2005) Diffusion brazing. In: Principles of brazing. ASM International, Ohio, pp 207–216

    Google Scholar 

  12. Zhong Z, Zhou J, Shen X, Ling X (2012) Study on vacuum brazing of glass to Kovar ® alloy with Cu-Ni-Sn-P. Weld J 91:237–240

    Google Scholar 

  13. Li YN, Wang CW, Peng ZL, Yan JC, Liu XS (2011) Dissolution behavior of Cu in Cu-Ag and Cu-P brazing alloys using weld brazing. Trans Nonferrous Met Soc 21:394–399

    Article  Google Scholar 

  14. Şerban VA, Codrean C, Uţu D, Opriş C (2009) Amorphous alloys for brazing copper based alloys. J Phys Conf Ser 144:012098

    Article  Google Scholar 

  15. Xihui D, Xiaoqiang L (2016) Study on vacuum brazed MGH956 alloy with Cu-P-Sn-Ni filler research of brazing MGH956 alloy with Cu-Ni-Sn-Ni filler metal in vacuum. Mater Sci Technol 24:14–19

    Google Scholar 

  16. Hasap A, Noraphaiphipaksa N, Kanchanomai C (2015) Torsional strength and failure of copper alloy brazing joint. Enf Fail Anal 48:174–184

    Article  CAS  Google Scholar 

  17. Kalin BA, Suchkov AN, Fedotov VT, Sevryukov ON, Ivannikov AA, Gervash AA (2016) Brazing of Be with CuCrZr-bronze using copper-based filler metal STEMET. Nucl Mater Energy 9:388–393

    Article  Google Scholar 

  18. Lutfi M, Yusof F, Ariga T, Singh R, Abd Shukor MH (2016) Interfacial reaction analysis of Cu-Sn-Ni-P/Cu joint using microwave hybrid heating. Key Eng Mater 701:148–153

    Article  Google Scholar 

  19. Lutfi M, Yusof F, Ramesh S, Ariga T, Hamdi M (2017) A novel method of brazing Cu/Cu-7.0Ni-9.3Sn-6.3P/Cu using microwave hybrid heating. Mater Werkst 48:299–305

    Article  Google Scholar 

  20. Cullity BD (1956) Elements of X-ray diffraction. Addison-Wesly Publishing Company Inc., Massachusetts

    Google Scholar 

  21. Zou J, Jiang Z, Zhao Q, Chen Z (2009) Brazing of Si3N4 with amorphous Ti40Zr25Ni15Cu20 filler. Mater Sci Eng A 507:155–160

    Article  Google Scholar 

  22. Schwartz MM (2003) Brazing, 2nd edn. ASM International, United States of America

    Google Scholar 

  23. Muhamed MN, Omar MZ, Abdullah S, Sajuri Z, Zamri WFHW, Abdullah MF (2018) Brazed joint interface bonding strength of AR500 steel and AA7075 aluminium alloy. Metals 8:668–680

    Article  Google Scholar 

  24. Jamadon NH, Tan AW, Yusof F, Ariga T, Miyashita Y, Hamdi M (2016) Utilization of a porous Cu interlayer for the enhancement of Pb-free Sn-3.0Ag-0.5Cu solder joint. Metals 6:1–15

    Article  Google Scholar 

  25. Hasap A, Noraphaiphipaksa N, Kanchanomai C (2014) The microstructure and strength of copper alloy brazing joints. Weld J 93:116–123

    Google Scholar 

  26. Aminazad AM, Hadian AM, Ghasimakbari F (2015) Investigation on corrosion behaviour of copper brazed joints. Procedia Mater Sci 11:672–678

    Article  CAS  Google Scholar 

  27. Miettinen J (2003) Thermodynamic description of the Cu-Ni-Sn system at the Cu-Ni side. Calphad 27:309–318

    Article  CAS  Google Scholar 

Download references

Funding

This work received financial support from the Fundamental Research Grant Scheme, FRGS University of Malaya under (Project number FP062-2015A), Research Universities, RU University of Malaya under (Project number ST006-2018), and equipments service contribution in Nagaoka University of Technology (Niigata, Japan).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Farazila Yusof.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Recommended for publication by Commission XVII - Brazing, Soldering and Diffusion Bonding

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zahri, N.A.M., Yusof, F., Miyashita, Y. et al. Brazing of porous copper foam/copper with amorphous Cu-9.7Sn-5.7Ni-7.0P (wt%) filler metal: interfacial microstructure and diffusion behavior. Weld World 64, 209–217 (2020). https://doi.org/10.1007/s40194-019-00804-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s40194-019-00804-2

Keywords

Navigation