Microstructure and properties of nano-laminated Y3Si2C2 ceramics fabricated via in situ reaction by spark plasma sintering

Abstract

A nano-laminated Y3Si2C2 ceramic material was successfully synthesized via an in situ reaction between YH2 and SiC using spark plasma sintering technology. A MAX phase-like ternary layered structure of Y3Si2C2 was observed at the atomic-scale by high resolution transmission electron microscopy. The lattice parameters calculated from both X-ray diffraction and selected area electron diffraction patterns are in good agreement with the reported theoretical results. The nano-laminated fracture of kink boundaries, delamination, and slipping were observed at the tip of the Vickers indents. The elastic modulus and Vickers hardness of Y3Si2C2 ceramics (with 5.5 wt% Y2O3) sintered at 1500 °C were 156 and 6.4 GPa, respectively. The corresponding values of thermal and electrical conductivity were 13.7 W·m-1·K-1 and 6.3×105 S·m-1, respectively.

References

  1. [1]

    Gerdes MH, Witte AM, Jeitschko W, et al. Magnetic and electrical properties of a new series of rare earth silicide carbides with the composition R3Si2C2 (R=Y, La-nd, sm, Gd-Tm). J Solid State Chem 1998, 138: 201–206.

    CAS  Article  Google Scholar 

  2. [2]

    Jeitschko W, Gerdes MH, Witte AM, et al. Subcell structure and two different superstructures of the rare earth metal silicide carbides Y3Si2C2, Pr3Si2C2, Tb3Si2C2, and Dy3Si2C2. J Solid State Chem 2001, 156: 1–9.

    CAS  Article  Google Scholar 

  3. [3]

    Zhou YC, Xiang HM, Dai FZ. Y5Si3C and Y3Si2C2: Theoretically predicted MAX phase like damage tolerant ceramics and promising interphase materials for SiCf/SiC composites. J Mater Sci Technol 2019, 35: 313–322.

    Article  Google Scholar 

  4. [4]

    Barsoum MW. The MN+1AXN phases: A new class of solids: Thermodynamically stable nanolaminates. Prog Solid State Chem 2000, 28: 201–281.

    CAS  Article  Google Scholar 

  5. [5]

    Zhang H, Hu T, Wang XH, et al. Structural defects in MAX phases and their derivative MXenes: A look forward. J Mater Sci Technol 2020, 38: 205–220.

    Article  Google Scholar 

  6. [6]

    Xu Q, Zhou YC, Zhang HM, et al. Theoretical prediction, synthesis, and crystal structure determination of new MAX phase compound V2SnC. J Adv Ceram 2020, 9: 481–492.

    CAS  Article  Google Scholar 

  7. [7]

    Zhang H, Wang XH, Wan P, et al. Insights into hightemperature uniaxial compression deformation behavior of Ti3AlC2. J Am Ceram Soc 2015, 98: 3332–3337.

    CAS  Article  Google Scholar 

  8. [8]

    Xu K, Zou HK, Chang KK, et al. Thermodynamic description of the sintering aid system in silicon carbide ceramics with the addition of yttrium. J Eur Ceram Soc 2019, 39: 4510–4519.

    CAS  Article  Google Scholar 

  9. [9]

    Shao JQ, Li M, Chang KK, et al. Fabrication and characterization of SPS sintered SiC-based ceramic from Y3Si2C2-coated SiC powders. J Eur Ceram Soc 2018, 38: 4833–4841.

    CAS  Article  Google Scholar 

  10. [10]

    Liu JW, Zhou XB, Tatarko P, et al. Fabrication, microstructure, and properties of SiC/Al4SiC4 multiphase ceramics via an in situ formed liquid phase sintering. J Adv Ceram 2020, 9: 193–203.

    CAS  Article  Google Scholar 

  11. [11]

    Zhou XB, Liu JW, Zou SR, et al. Almost seamless joining of SiC using an in situ reaction transition phase of Y3Si2C2. J Eur Ceram Soc 2020, 40: 259–266.

    CAS  Article  Google Scholar 

  12. [12]

    Chen H, Zhao B, Zhao ZF, et al. Achieving strong microwave absorption capability and wide absorption bandwidth through a combination of high entropy rare earth silicide carbides/rare earth oxides. J Mater Sci Technol 2020, 47: 216–222.

    Article  Google Scholar 

  13. [13]

    Hrubovčáková M, Múdra E, Bureš R, et al. Microstructure, fracture behaviour and mechanical properties of conductive alumina based composites manufactured by SPS from graphenated Al2O3 powders. J Eur Ceram Soc 2020, 40: 4818–4824.

    Article  Google Scholar 

  14. [14]

    Ehsani M, Zakeri M, Razavi M. The effect of temperature on the physical and mechanical properties of nanostructured boron nitride by spark plasma sintering. J Alloys Compd 2020, 835: 155317.

    CAS  Article  Google Scholar 

  15. [15]

    Jiang RR, Li M, Yao YR, et al. Application of BIB polishing technology in cross-section preparation of porous, layered and powder materials: A review. Front Mater Sci 2019, 13: 107–125.

    Article  Google Scholar 

  16. [16]

    Volz E, Roosen A, Hartung W, et al. Electrical and thermal conductivity of liquid phase sintered SiC. J Eur Ceram Soc 2001, 21: 2089–2093.

    CAS  Article  Google Scholar 

  17. [17]

    Song WJ, Liu J, Dong HP, et al. Microstructural evolution and hydrogen storage proprieties of melt-spun eutectic Mg76.87Ni12.78Y10.35 alloy with low hydrides formation/decomposition enthalpy. Int J Hydrog Energy 2020, 45: 16644–16653.

    CAS  Article  Google Scholar 

  18. [18]

    Zou J, Zhang GJ, Fu ZY. In-situ ZrB2-hBN ceramics with high strength and low elasticity. J Mater Sci Technol 2020, 48: 186–193.

    Article  Google Scholar 

  19. [19]

    Munir ZA, Quach DV, Ohyanagi M. Electric current activation of sintering: A review of the pulsed electric current sintering process. J Am Ceram Soc 2011, 94: 1–19.

    CAS  Article  Google Scholar 

  20. [20]

    Lapauw T, Halim J, Lu J, et al. Synthesis of the novel Zr3AlC2 MAX phase. J Eur Ceram Soc 2016, 36: 943–947.

    CAS  Article  Google Scholar 

  21. [21]

    Zhang L, Feng J, Pan W. Vacuum sintering of transparent Cr:Y2O3 ceramics. Ceram Int 2015, 41: 8755–8760.

    CAS  Article  Google Scholar 

  22. [22]

    Ahmadi B, Reza SR, Ahsanzadeh-Vadeqani M, et al. Mechanical and optical properties of spark plasma sintered transparent Y2O3 ceramics. Ceram Int 2016, 42: 17081–17088.

    CAS  Article  Google Scholar 

  23. [23]

    Yeheskel O, Tevet O. Elastic moduli of transparent yttria. J Am Ceram Soc 1999, 82: 136–144.

    CAS  Article  Google Scholar 

  24. [24]

    Zhou XB, Jing L, Kwon YD, et al. Fabrication of SiCw/Ti3SiC2 composites with improved thermal conductivity and mechanical properties using spark plasma sintering. J Adv Ceram 2020, 9: 462–470.

    CAS  Article  Google Scholar 

  25. [25]

    Zhao GR, Chen JX, Li YM, et al. In situ synthesis, structure, and properties of bulk nanolaminate YAl3C3 ceramic. J Eur Ceram Soc 2017, 37: 83–89.

    CAS  Article  Google Scholar 

  26. [26]

    Tzenov NV, Barsoum MW. Synthesis and characterization of Ti3AlC2. J Am Ceram Soc 2004, 83: 825–832.

    Article  Google Scholar 

  27. [27]

    Tatarko P, Chlup Z, Mahajan A, et al. High temperature properties of the monolithic CVD β-SiC materials joined with a pre-sintered MAX phase Ti3SiC2 interlayer via solid-state diffusion bonding. J Eur Ceram Soc 2017, 37: 1205–1216.

    CAS  Article  Google Scholar 

  28. [28]

    Yi Q, Zhou SM, Teng H, et al. Structural and optical properties of Tm:Y2O3 transparent ceramic with La2O3, ZrO2 as composite sintering aid. J Eur Ceram Soc 2012, 32: 381–388.

    CAS  Article  Google Scholar 

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Acknowledgements

We would like to appreciate the support from the Ningbo 3315 Innovative Teams Program, China (Grant No. 2019A-14-C). This study was supported by the National Natural Science Foundation of China (Grant Nos. 11975296 and 51811540402).

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Correspondence to Xiaobing Zhou or Jian-Qing Dai.

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Shi, LK., Zhou, X., Dai, JQ. et al. Microstructure and properties of nano-laminated Y3Si2C2 ceramics fabricated via in situ reaction by spark plasma sintering. J Adv Ceram 10, 578–586 (2021). https://doi.org/10.1007/s40145-021-0459-0

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Keywords

  • Y3Si2C2
  • rare earth silicide carbides
  • spark plasma sintering (SPS)
  • ternary layered structure ceramic
  • properties