Abstract
The resistive switching (RS) mechanism of hybrid organic-inorganic perovskites has not been clearly understood until now. A switchable diode-like RS behavior in MAPbBr3 single crystals using Au (or Pt) symmetric electrodes is reported. Both the high resistance state (HRS) and low resistance state (LRS) are electrode-area dependent and light responsive. We propose an electric-field-driven inner p-n junction accompanied by a trap-controlled space-charge-limited conduction (SCLC) conduction mechanism to explain this switchable diode-like RS behavior in MAPbBr3 single crystals.
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (Nos. 11964017, 51972157, 11864022, and 51662028) and the Natural Science Foundation of Jiangxi Province (No. 20192ACB21017).
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Ke, S., Luo, S., Gong, J. et al. Electric modulation of conduction in MAPbBr3 single crystals. J Adv Ceram 10, 320–327 (2021). https://doi.org/10.1007/s40145-020-0442-1
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DOI: https://doi.org/10.1007/s40145-020-0442-1