Microstructure and mechanical properties of short-carbon-fiber/Ti3SiC2 composites

Abstract

Short-carbon-fibers (Csf) reinforced Ti3SiC2 matrix composites (Csf/Ti3SiC2, the Csf content was 0 vol%, 2 vol%, 5 vol%, and 10 vol%) were fabricated by spark plasma sintering (SPS) using Ti3SiC2 powders and Csf as starting materials at 1300 °C. The effects of Csf addition on the phase compositions, microstructures, and mechanical properties (including hardness, flexural strength (σf), and KIC) of Csf/Ti3SiC2 composites were investigated. The Csf, with bi-layered transition layers, i.e., TiC and SiC layers, were homogeneously distributed in the as-prepared Csf/Ti3SiC2 composites. With the increase of Csf content, the KIC of Csf/Ti3SiC2 composites increased, but the σf decreased, and the Vickers hardness decreased initially and then increased steadily when the Csf content was higher than 2 vol%. These changed performances (hardness, σf, and KIC) could be attributed to the introduction of Csf and the formation of stronger interfacial phases.

References

  1. [1]

    Barsoum MW. The MN+1AXN phases: A new class of solids. Prog Solid State Chem 2000, 28: 201–281.

    CAS  Article  Google Scholar 

  2. [2]

    Barsoum MW, El-Raghy T. Synthesis and characterization of a remarkable ceramic: Ti3SiC2. J Am Ceram Soc 1996, 79: 1953–1956.

    CAS  Article  Google Scholar 

  3. [3]

    El-Raghy T, Zavaliangos A, Barsoum MW, et al. Damage mechanisms around hardness indentations in Ti3SiC2. J Am Ceram Soc 2005, 80: 513–516.

    Article  Google Scholar 

  4. [4]

    Barsoum M, El-Raghy T. A progress report on Ti3SiC2, Ti3GeC2, and the H-phases, M2BX. J Mater Synth Process 1997, 5: 197–216.

    CAS  Google Scholar 

  5. [5]

    Zhou YC, Sun ZM, Chen SQ, et al. In-situ hot pressing/solid-liquid reaction synthesis of dense titanium silicon carbide bulk ceramics. Mater Res Innov 1998, 2: 142–146.

    CAS  Article  Google Scholar 

  6. [6]

    Sun ZM, Zhou YC, Li MS. Oxidation behaviour of Ti3SiC2-based ceramic at 900–1300 °C in air. Corros Sci 2001, 43: 1095–1109.

    CAS  Article  Google Scholar 

  7. [7]

    Gao NF, Miyamoto Y, Zhang D. Dense Ti3SiC2 prepared by reactive HIP. J Mater Sci 1999, 34: 4385–4392.

    CAS  Article  Google Scholar 

  8. [8]

    Ghosh NC, Harimkar SP. Phase analysis and wear behavior of in situ spark plasma sintered Ti3SiC2. Ceram Int 2013, 39: 6777–6786.

    CAS  Article  Google Scholar 

  9. [9]

    Górny G, Rączka M, Stobierski L, et al. Ceramic composite Ti3SiC2-TiB2—Microstructure and mechanical properties. Mater Charact 2009, 60: 1168–1174.

    Article  Google Scholar 

  10. [10]

    Li SB, Xie JX, Zhang LT, et al. Mechanical properties and oxidation resistance of Ti3SiC2/SiC composite synthesized by in situ displacement reaction of Si and TiC. Mater Lett 2003, 57: 3048–3056.

    CAS  Article  Google Scholar 

  11. [11]

    Benko E, Klimczyk P, MacKiewicz S, et al. cBN-Ti3SiC2 composites. Diam Relat Mater 2004, 13: 521–525.

    CAS  Article  Google Scholar 

  12. [12]

    Tian WB, Sun ZM, Hashimoto H, et al. Synthesis, microstructure and mechanical properties of Ti3SiC2-TiC composites pulse discharge sintered from Ti/Si/TiC powder mixture. Mater Sci Eng: A 2009, 526: 16–21.

    Article  Google Scholar 

  13. [13]

    Wang HJ, Jin ZH, Miyamoto Y. Effect of Al2O3 on mechanical properties of Ti3SiC2/Al2O3 composite. Ceram Int 2002, 28: 931–934.

    CAS  Article  Google Scholar 

  14. [14]

    Shi SL, Pan W. Toughening of Ti3SiC2 with 3Y-TZP addition by spark plasma sintering. Mater Sci Eng: A 2007, 447: 303–306.

    Article  Google Scholar 

  15. [15]

    Hou LG, Wu RZ, Wang XD, et al. Microstructure, mechanical properties and thermal conductivity of the short carbon fiber reinforced magnesium matrix composites. J Alloys compd 2017, 695: 2820–2826.

    CAS  Article  Google Scholar 

  16. [16]

    Li S, Zhang YM, Han JC, et al. Effect of carbon particle and carbon fiber on the microstructure and mechanical properties of short fiber reinforced reaction bonded silicon carbide composite. J Eur Ceram Soc 2013, 33: 887–896.

    CAS  Article  Google Scholar 

  17. [17]

    Hong WH, Gui KX, Hu P, et al. Preparation and characterization of high-performance ZrB2-SiC-Cf composites sintered at 1450 °C. J Adv Ceram 2017, 6: 110–119.

    CAS  Article  Google Scholar 

  18. [18]

    Wang MC, Zhang ZG, Sun ZJ, et al. Effect of fiber type on mechanical properties of short carbon fiber reinforced B4C composites. Ceram Int 2009, 35: 1461–1466.

    CAS  Article  Google Scholar 

  19. [19]

    Yang FY, Zhang XH, Han JC, et al. Characterization of hot-pressed short carbon fiber reinforced ZrB2-SiC ultra-high temperature ceramic composites. J Alloys Compd 2009, 472: 395–399.

    CAS  Article  Google Scholar 

  20. [20]

    Lagos MA, Pellegrini C, Agote I, et al. Ti3SiC2-Cf composites by spark plasma sintering: Processing, microstructure and thermo-mechanical properties. J Eur Ceram Soc 2019, 39: 2824–2830.

    CAS  Article  Google Scholar 

  21. [21]

    Tang C, Li TH, Gao JJ, et al. Microstructure and mechanical behavior of the Cf/Ti3SiC2-SiC composites fabricated by compression molding and pressureless sintering. Ceram Int 2017, 43: 16204–16209.

    CAS  Article  Google Scholar 

  22. [22]

    Zhou XB, Yang H, Chen FY, et al. Joining of carbon fiber reinforced carbon composites with Ti3SiC2 tape film by electric field assisted sintering technique. Carbon 2016, 102: 106–115.

    CAS  Article  Google Scholar 

  23. [23]

    Gui KX, Liu FY, Wang G, et al. Microstructural evolution and performance of carbon fiber-toughened ZrB2 ceramics with SiC or ZrSi2 additive. J Adv Ceram 2018, 7: 343–351.

    CAS  Article  Google Scholar 

  24. [24]

    Qin JQ, He DW. Phase stability of Ti3SiC2 at high pressure and high temperature. Ceram Int 2013, 39: 9361–9367.

    CAS  Article  Google Scholar 

  25. [25]

    Sun Z, Zhou J, Music D, et al. Phase stability of Ti3SiC2 at elevated temperatures. Scr Mater 2006, 54: 105–107.

    CAS  Article  Google Scholar 

  26. [26]

    Racault C, Langlais F, Naslain R. Solid-state synthesis and characterization of the ternary phase Ti3SiC2. J Mater Sci 1994, 29: 3384–3392.

    CAS  Article  Google Scholar 

  27. [27]

    El-Raghy T, Barsoum MW. Diffusion kinetics of the carburization and silicidation of Ti3SiC2. J Appl Phys 1998, 83: 112–119.

    CAS  Article  Google Scholar 

  28. [28]

    Gao NF, Miyamoto Y, Zhang D. On physical and thermochemical properties of high-purity Ti3SiC2. Mater Lett 2002, 55: 61–66.

    CAS  Article  Google Scholar 

  29. [29]

    Ghosh NC, Harimkar SP. Microstructure and wear behavior of spark plasma sintered Ti3SiC2 and Ti3SiC2-TiC composites. Ceram Int 2013, 39: 4597–4607.

    CAS  Article  Google Scholar 

  30. [30]

    Yin XW, Cheng LF, Zhang LT, et al. Fibre-reinforced multifunctional SiC matrix composite materials. Int Mater Rev 2017, 62: 117–172.

    CAS  Article  Google Scholar 

  31. [31]

    Zhang JF, Wang LJ, Jiang W, et al. Effect of TiC content on the microstructure and properties of Ti3SiC2-TiC composites in situ fabricated by spark plasma sintering. Mater Sci Eng: A 2008, 487: 137–143.

    Article  Google Scholar 

  32. [32]

    Karimirad S, Balak Z. Characteristics of spark plasma sintered ZrB2-SiC-SCFs composites. Ceram Int 2019, 45: 6275–6281.

    CAS  Article  Google Scholar 

  33. [33]

    Shahedi Asl M. Microstructure, hardness and fracture toughness of spark plasma sintered ZrB2-SiC-Cf composites. Ceram Int 2017, 43: 15047–15052.

    CAS  Article  Google Scholar 

  34. [34]

    Brennan JJ, McCarthy G. Interfacial studies of refractory glass-ceramic-matrix/advanced-SiC-fiber-reinforced composites. Mater Sci Eng: A 1993, 162: 53–72.

    Article  Google Scholar 

  35. [35]

    He XL, Guo YK, Yu ZM, et al. Study on microstructures and mechanical properties of short-carbon-fiber-reinforced SiC composites prepared by hot-pressing. Mater Sci Eng: A 2009, 527: 334–338.

    Article  Google Scholar 

  36. [36]

    Arai Y, Inoue R, Goto K, et al. Carbon fiber reinforced ultra-high temperature ceramic matrix composites: A review. Ceram Int 2019, 45: 14481–14489.

    CAS  Article  Google Scholar 

  37. [37]

    Wang CF, Chen L, Li J, et al. Enhancing the interfacial strength of carbon fiber reinforced epoxy composites by green grafting of poly(oxypropylene) diamines. Compos Part A: Appl Sci Manuf 2017, 99: 58–64.

    CAS  Article  Google Scholar 

  38. [38]

    Sun JF, Zhao F, Yao Y, et al. High efficient and continuous surface modification of carbon fibers with improved tensile strength and interfacial adhesion. Appl Surf Sci 2017, 412: 424–435.

    CAS  Article  Google Scholar 

  39. [39]

    Yang WS, Biamino S, Padovano E, et al. Microstructure and mechanical properties of short carbon fibre/SiC multilayer composites prepared by tape casting. Compos Sci Technol 2012, 72: 675–680.

    CAS  Article  Google Scholar 

  40. [40]

    Guo SQ, Hu CF, Gao H, et al. SiC(SCS-6) fiber-reinforced Ti3AlC2 matrix composites: Interfacial characterization and mechanical behavior. J Eur Ceram Soc 2015, 35: 1375–1384.

    CAS  Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the Joint Fund of Liaoning-SYNL (Grant No. 2019JH3/30100035) and the Science and Technology Foundation of National Defense Key Laboratory (Grant No. HTKJ2019KL703006).

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Correspondence to Jingjun Xu or Changsheng Liu.

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He, G., Guo, R., Li, M. et al. Microstructure and mechanical properties of short-carbon-fiber/Ti3SiC2 composites. J Adv Ceram (2020). https://doi.org/10.1007/s40145-020-0408-3

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Keywords

  • Ti3SiC2
  • short-carbon-fibers (Csf)
  • spark plasma sintering (SPS)
  • microstructure
  • mechanical properties