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Ethylene Adsorption Study by Using Various MOFs in the CMC Film for Application in Postharvest of Fruit

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Abstract

Metal–organic frameworks (MOFs), Bio-MOF1, HKUST-1 and Cu(II)@Bio-MOF1 have been prepared and characterization for the study of ethylene adsorption. Cu(II)@Bio-MOF1 was post-synthesis material by the exchange process between DMF cation in the porous of Bio-MOF1 and Cu(II) ion. It was modified because biocompatible anion Bio-MOF1 shows low efficiency of ethylene adsorption while HKUST-1 shows a good one with open metal (Cu2+) active site for attraction of ethylene. MOF films were synthesized by carboxymethyl cellulose biopolymer and cross-link agent, citric acid mixed with the prepared MOFs, Bio-MOF1, HKUST-1 and Cu(II)@Bio-MOF1. These MOFs in the form of powder and MOF films have been studied for ethylene adsorption. Gas chromatography and observing banana peel color change were used to analyze ethylene adsorption. The color change of banana peel from green to yellow represents the ripening. HKUST-1 shows the best ethylene adsorption and the slowest color change to yellow of banana peel. Cu(II)@Bio-MOF1 exhibits better efficiency of ethylene adsorption than Bio-MOF1. In addition, prepared MOF powder provides higher efficiency of ethylene adsorption than the prepared MOF films. It is possible that ethylene gas was obstructed by biopolymer to penetrate the active sites of MOF.

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(Modified from Jihyun An 2011) and (bottom) photograph of Cu(II)@Bio-MOF1 powder after cation exchange

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Acknowledgements

This research was supported from Basis Research Fund (BRF), Faculty of Science, Kasetsart University, the Center of Excellence for Innovation in Chemistry (PERCH-CIC) and the Department of Chemistry, Faculty of Science, Kasetsart University.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kasetsart University, Bangkok, 10900, Thailand

    Tontrakarn Pongpai, Sasina Kerdsiri & Tanwawan Duangthongyou

  2. Department of Chemistry, Faculty of Science, The Center of Excellence for Innovation in Chemistry (PERCH-CIC), Kasetsart University, Bangkok, 10900, Thailand

    Tontrakarn Pongpai & Tanwawan Duangthongyou

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  1. Tontrakarn Pongpai
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Correspondence to Tanwawan Duangthongyou.

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Pongpai, T., Kerdsiri, S. & Duangthongyou, T. Ethylene Adsorption Study by Using Various MOFs in the CMC Film for Application in Postharvest of Fruit. J. Inst. Eng. India Ser. E (2024). https://doi.org/10.1007/s40034-024-00287-x

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