Abstract
The heterogeneous solar-Fenton process is an ecological and promising strategy for removing hazardous pollutants in aqueous media. Therefore, this study aimed to prepare and characterize a heterogeneous solid iron catalyst supported by zeolite Y to degrade tartrazine yellow (TY) food coloring under natural sunlight. The catalyst was produced by wet ion exchange and characterized by several techniques. The catalyst efficiency was evaluated through the degradation of the TY dye in a batch mode with the evaluation of some of the main operational parameters. The presence of iron in zeolite Y was confirmed by XRD, TEM, and EDX techniques and by reducing specific area and pore volume after ion exchange. The FTIR proved the occurrence of an ion exchange process. The oxidative system formed by the Fe-Y catalyst and natural sunlight was highly efficient, with the removal of approximately 98% in 120 min under the experimental conditions: [TY]0 = 10 mg L−1, [H2O2]0 = 200 g L−1, Dosage of Y-Fe = 1.5 g L−1 and pH = 3.0. It was possible to recover the catalyst and use it in five reuse cycles, showing the stability and application potential in heterogeneous solar-Fenton systems with sunlight. The toxicity reduction was evaluated through the COD and TOC parameters and ecotoxicological tests against the bioindicators Artemia salina and Lactuca sativa, showing the efficiency of the proposed process.
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References
Ahmed B, Limem E, Abdel-Wahab A, Nasr B (2011) Photo-fenton treatment of actual agro-industrial wastewaters. Ind Eng Chem Res 50:6673–6680. https://doi.org/10.1021/IE200266D
Amat AM, Arques A, Bossmann SH et al (2004) Oxidative degradation of 2,4-xylidine by photosensitization with 2,4,6-triphenylpyrylium: homogeneous and heterogeneous catalysis. Chemosphere 57:1123–1130. https://doi.org/10.1016/j.chemosphere.2004.08.029
Ba Mohammed B, Hsini A, Abdellaoui Y et al (2020) Fe-ZSM-5 zeolite for efficient removal of basic Fuchsin dye from aqueous solutions: synthesis, characterization and adsorption process optimization using BBD-RSM modeling. J Environ Chem Eng 8:104419. https://doi.org/10.1016/J.JECE.2020.104419
Ba Mohammed B, Yamni K, Tijani N et al (2021) Enhanced removal efficiency of NaY zeolite toward phenol from aqueous solution by modification with nickel (Ni-NaY). J Saudi Chem Soc 25:101224. https://doi.org/10.1016/J.JSCS.2021.101224
Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. i. computations from nitrogen isotherms. J Am Chem Soc 73:373–380. https://doi.org/10.1021/ja01145a126
Barros TRB, Barbosa TSB, Rodrigues MGF (2021) Adsorption of reactive yellow BF-3R dye by CTABr modified zeolite NaY Research. Soc Dev 10:e323101422147. https://doi.org/10.33448/rsd-v10i14.22147
Brunauer S, Emmett PH, Teller E (1938) Adsorption of gases in multimolecular layers. J Am Chem Soc 60:309–319. https://doi.org/10.1021/ja01269a023
Bu N, Liu X, Song S et al (2020) Synthesis of NaY zeolite from coal gangue and its characterization for lead removal from aqueous solution. Adv Powder Technol 31:2699–2710. https://doi.org/10.1016/J.APT.2020.04.035
Chen S, Shen Y, Guan Z et al (2020) Adsorption properties of SF 6 on zeolite NaY, 13X, activated carbon, and silica gel. Cite This: J Chem Eng Data 65:4051. https://doi.org/10.1021/acs.jced.0c00348
Crittenden JC, Hu S, Hand DW, Green SA (1999) A kinetic model for H2O2/UV process in a completely mixed batch reactor. Water Res 33:2315–2328. https://doi.org/10.1016/S0043-1354(98)00448-5
Dhawle R, Frontistis Z, Mantzavinos D, Lianos P (2021) Production of hydrogen peroxide with a photocatalytic fuel cell and its application to UV/H2O2 degradation of dyes. Chem Eng Journal Adv 6:100109. https://doi.org/10.1016/J.CEJA.2021.100109
Donoso G, Dominguez JR, González T et al (2021) Electrochemical and sonochemical advanced oxidation processes applied to tartrazine removal Influence of operational conditions and aqueous matrix. Environ Res. https://doi.org/10.1016/j.envres.2021.111517
Duarte F, Madeira LM (2010) Fenton- and photo-fenton-like degradation of a textile dye by Heterogeneous Processes with Fe/ZSM-5 Zeolite. Sep Sci Technol 45:1512–1520. https://doi.org/10.1080/01496395.2010.487452
Elmorsi TM, Riyad YM, Mohamed ZH, Abd El Bary HMH (2010) Decolorization of mordant red 73 azo dye in water using H2O2/UV and photo-Fenton treatment. J Hazard Mater 174:352–358. https://doi.org/10.1016/J.JHAZMAT.2009.09.057
Fragoso CT, Battisti R, Miranda C, de Jesus PC (2009) Kinetic of the degradation of C.I. Food Yellow 3 and C.I. Food Yellow 4 azo dyes by the oxidation with hydrogen peroxide. J Mol Catal A Chem 301:93–97. https://doi.org/10.1016/J.MOLCATA.2008.11.014
Gautam RK, Gautam PK, Banerjee S et al (2015) Removal of tartrazine by activated carbon biosorbents of Lantana camara: Kinetics, equilibrium modeling and spectroscopic analysis. J Environ Chem Eng 3:79–88. https://doi.org/10.1016/j.jece.2014.11.026
Guo Q, Li G, Liu D, Wei Y (2019) Synthesis of zeolite Y promoted by Fenton’s reagent and its application in photo-Fenton-like oxidation of phenol. Solid State Sci 91:89–95. https://doi.org/10.1016/J.SOLIDSTATESCIENCES.2019.03.016
Guo Q, Zhu W, Yang D et al (2021) A green solar photo-Fenton process for the degradation of carbamazepine using natural pyrite and organic acid with in-situ generated H2O2. Sci Total Environ 784:147187. https://doi.org/10.1016/J.SCITOTENV.2021.147187
Hanim SAM, Malek NANN, Ibrahim Z (2016) Amine-functionalized, silver-exchanged zeolite NaY: Preparation, characterization and antibacterial activity. Appl Surf Sci 360:121–130. https://doi.org/10.1016/J.APSUSC.2015.11.010
Hanim SAM, Malek NANN, Ibrahim Z (2017) Analyses of surface area, porosity, silver release and antibacterial activity of amine-functionalized, silver-exchanged zeolite NaY. Vacuum 143:344–347. https://doi.org/10.1016/J.VACUUM.2017.06.038
Hassan H, Hameed BH (2011) Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4. Chem Eng J 171:912–918. https://doi.org/10.1016/j.cej.2011.04.040
Hernández-Oloño JT, Infantes-Molina A, Vargas-Hernández D et al (2021) A novel heterogeneous photo-Fenton Fe/Al2O3 catalyst for dye degradation. J Photochem Photobiol A Chem 421:113529. https://doi.org/10.1016/J.JPHOTOCHEM.2021.113529
Jiang Z, Wang L, Lei J et al (2019) Photo-Fenton degradation of phenol by CdS/rGO/Fe2+ at natural pH with in situ-generated H2O2. Appl Catal B 241:367–374. https://doi.org/10.1016/J.APCATB.2018.09.049
Kang JK, Seo EJ, Lee CG, Park SJ (2021) Fe-loaded biochar obtained from food waste for enhanced phosphate adsorption and its adsorption mechanism study via spectroscopic and experimental approach. J Environ Chem Eng 9:105751. https://doi.org/10.1016/J.JECE.2021.105751
Kumar S, Kumar B, Baruah A, Shanker V (2013) Synthesis of magnetically separable and recyclable g-C 3 N 4 −Fe 3 O 4 hybrid nanocomposites with enhanced photocatalytic performance under visible-light irradiation. j Phys Chem C. https://doi.org/10.1021/jp409651g
Leichtweis J, Silvestri S, Vieira Y et al (2021) A novel tin ferrite/polymer composite use in photo-Fenton reactions. Int J Environ Sci Technol 18:1537–1548. https://doi.org/10.1007/s13762-020-02944-1
Liu J, Lin H, Dong Y et al (2021) The effective adsorption of tetracycline onto MoS2@Zeolite-5: Adsorption behavior and interfacial mechanism. J Environ Chem Eng 9:105912. https://doi.org/10.1016/J.JECE.2021.105912
Motta CM, Simoniello P, Arena C et al (2019) Effects of four food dyes on development of three model species, Cucumis sativus, Artemia salina and Danio rerio: Assessment of potential risk for the environment. Environ Pollut 253:1126–1135. https://doi.org/10.1016/J.ENVPOL.2019.06.018
Mpountoukas P, Pantazaki A, Kostareli E et al (2010) Cytogenetic evaluation and DNA interaction studies of the food colorants amaranth, erythrosine and tartrazine. Food Chem Toxicol 48:2934–2944. https://doi.org/10.1016/j.fct.2010.07.030
Neamţu M, Zaharia C, Catrinescu C et al (2004) Fe-exchanged Y zeolite as catalyst for wet peroxide oxidation of reactive azo dye Procion Marine H-EXL. Appl Catal B 48:287–294. https://doi.org/10.1016/j.apcatb.2003.11.005
Nezamzadeh-Ejhieh A, Shahriari E (2014) Photocatalytic decolorization of methyl green using Fe(II)-o-phenanthroline as supported onto zeolite Y. J Ind Eng Chem 20:2719–2726. https://doi.org/10.1016/j.jiec.2013.10.060
Nippes RP, Macruz PD, Neves Olsen Scaliante MH (2021) Toxicity reduction of persistent pollutants through the photo-fenton process and radiation/H2O2 using different sources of radiation and neutral pH. J Environ Manage 289:112500. https://doi.org/10.1016/j.jenvman.2021.112500
Noorjahan M, Durga Kumari V, Subrahmanyam M, Panda L (2005) Immobilized Fe(III)-HY: an efficient and stable photo-Fenton catalyst. Appl Catal B 57:291–298. https://doi.org/10.1016/J.APCATB.2004.11.006
Nosaka Y, Nosaka A (2016) Understanding hydroxyl radical ( • OH) generation processes in photocatalysis. ACS Energy Lett 1:356–359. https://doi.org/10.1021/acsenergylett.6b00174
Oancea P, Meltzer V (2013) Photo-Fenton process for the degradation of Tartrazine (E102) in aqueous medium. J Taiwan Inst Chem Eng 44:990–994. https://doi.org/10.1016/J.JTICE.2013.03.014
Oladipo AA, Abureesh MA, Gazi M (2016) Bifunctional composite from spent “Cyprus coffee” for tetracycline removal and phenol degradation: solar-Fenton process and artificial neural network. Int J Biol Macromol 90:89–99. https://doi.org/10.1016/j.ijbiomac.2015.08.054
Oladipo AA, Ifebajo AO, Gazi M (2019) Magnetic LDH-based CoO–NiFe2O4 catalyst with enhanced performance and recyclability for efficient decolorization of azo dye via Fenton-like reactions. Appl Catal B 243:243–252. https://doi.org/10.1016/j.apcatb.2018.10.050
Omri A, Hamza W, Benzina M (2020) Photo-Fenton oxidation and mineralization of methyl orange using Fe-sand as effective heterogeneous catalyst. J Photochem Photobiol A Chem 393:112444. https://doi.org/10.1016/J.JPHOTOCHEM.2020.112444
Palas B, Ersöz G, Atalay S (2017) Photo Fenton-like oxidation of Tartrazine under visible and UV light irradiation in the presence of LaCuO3 perovskite catalyst. Process Saf Environ Prot 111:270–282. https://doi.org/10.1016/j.psep.2017.07.022
Paterlini WC, Nogueira RFP (2005) Multivariate analysis of photo-Fenton degradation of the herbicides tebuthiuron, diuron and 2,4-D. Chemosphere 58:1107–1116. https://doi.org/10.1016/j.chemosphere.2004.09.068
Qin H, Yang Y, Shi W et al (2021) Heterogeneous Fenton degradation of azithromycin antibiotic in water catalyzed by amino/thiol-functionalized MnFe2O4 magnetic nanocatalysts. J Environ Chem Eng 9:106184. https://doi.org/10.1016/j.jece.2021.106184
Rache ML, García AR, Zea HR et al (2014) Azo-dye orange II degradation by the heterogeneous Fenton-like process using a zeolite Y-Fe catalyst—Kinetics with a model based on the Fermi’s equation. Appl Catal B 146:192–200. https://doi.org/10.1016/J.APCATB.2013.04.028
Ramos RO, Albuquerque MVC, Lopes WS et al (2020) Degradation of indigo carmine by photo-Fenton, Fenton, H2O2/UV-C and direct UV-C: comparison of pathways, products and kinetics. J Water Process Eng 37:101535. https://doi.org/10.1016/J.JWPE.2020.101535
Regalbuto JR, Robles JO (2004) The Engineering of Pt/Carbon Catalyst Preparation. University of Illinois, Chicago, p 13
Shin J, Bae S, Chon K (2021) Fenton oxidation of synthetic food dyes by Fe-embedded coffee biochar catalysts prepared at different pyrolysis temperatures: a mechanism study. Chem Eng J 421:129943. https://doi.org/10.1016/J.CEJ.2021.129943
Silveira GL, Lima MGF, dos Reis GB et al (2017) Toxic effects of environmental pollutants: Comparative investigation using Allium cepa L. and Lactuca sativa L. Chemosphere 178:359–367. https://doi.org/10.1016/j.chemosphere.2017.03.048
Soufi A, Hajjaoui H, Elmoubarki R et al (2022) Heterogeneous Fenton-like degradation of tartrazine using CuFe2O4 nanoparticles synthesized by sol-gel combustion. Appl Surf Sci Adv 9:100251. https://doi.org/10.1016/j.apsadv.2022.100251
Souza IPAF, Crespo LHS, Spessato L et al (2021) Optimization of thermal conditions of sol-gel method for synthesis of TiO2 using RSM and its influence on photodegradation of tartrazine yellow dye. J Environ Chem Eng 9:104753. https://doi.org/10.1016/J.JECE.2020.104753
Stronati L (2004) Evaluation of chromosome painting to assess the induction and persistence of chromosome aberrations in bone marrow cells of mice treated with benzene. Mutation Res/fundament Mol Mech Mutagenesis 545:1–9. https://doi.org/10.1016/j.mrfmmm.2003.10.004
Tekbaş M, Yatmaz HC, Bektaş N (2008) Heterogeneous photo-Fenton oxidation of reactive azo dye solutions using iron exchanged zeolite as a catalyst. Microporous Mesoporous Mater 115:594–602. https://doi.org/10.1016/J.MICROMESO.2008.03.001
Thomas N, Dionysiou DD, Pillai SC (2021) Heterogeneous Fenton catalysts: A review of recent advances. J Hazard Mater 404:124082. https://doi.org/10.1016/J.JHAZMAT.2020.124082
Xia M, Long M, Yang Y et al (2011) A highly active bimetallic oxides catalyst supported on Al-containing MCM-41 for Fenton oxidation of phenol solution. Appl Catal B 110:118–125. https://doi.org/10.1016/J.APCATB.2011.08.033
Yang X, Cheng X, Elzatahry AA et al (2019) Recyclable Fenton-like catalyst based on zeolite Y supported ultrafine, highly-dispersed Fe2O3 nanoparticles for removal of organics under mild conditions. Chin Chem Lett 30:324–330. https://doi.org/10.1016/J.CCLET.2018.06.026
Zhang J, Tang X, Yi H et al (2022) Synthesis, characterization and application of Fe-zeolite: a review. Appl Catal A Gen 630:118467. https://doi.org/10.1016/J.APCATA.2021.118467
Zhao Y, Kang S, Qin L et al (2020) Self-assembled gels of Fe-chitosan/montmorillonite nanosheets: dye degradation by the synergistic effect of adsorption and photo-Fenton reaction. Chem Eng J 379:122322. https://doi.org/10.1016/J.CEJ.2019.122322
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Nippes, R.P., Macruz, P.D., Molina, L.C.A. et al. Solar-Fenton heterogeneous for removal of tartrazine yellow dye using zeolite Y-Fe as catalyst. Int. J. Environ. Sci. Technol. 21, 3675–3688 (2024). https://doi.org/10.1007/s13762-023-05233-9
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DOI: https://doi.org/10.1007/s13762-023-05233-9