Abstract
Tertiary and advanced treatment for wastewater effluents introduces a powerful solution for reusing this water and overcoming the water shortage problem. In this work, the natural zeolite rock (NZR) is examined as an adsorbent for tertiary treatment of the secondary treated wastewater effluent. The research relies on an experimental program in a laboratory scale, and many parameters were investigated including the material size and pretreated processes for the rock samples. The pretreated processes included prewashing, socking, drying, and thermal treatment. The chemical analysis for wastewater samples was carried out before and after adding rocks. Furthermore, microstructural investigations by SEM and XRF techniques were adopted for rock samples before and after contact with wastewater. Results showed notable impacts for thermally treated samples in removing nitrite as the removal reached about 96%. Using NZR with wastewater demonstrated a slight reduction in BOD and COD values compared to the original wastewater sample. The SEM and XRF results showed the capability of NZR to exchange the cations with water, which makes NZR a promising material for purify the wastewater especially after applying thermal treatment.
Similar content being viewed by others
References
Belbase S, Urynowicz MA, Vance GF, Dangi MB (2013) Passive remediation of coalbed natural gas co-produced water using zeolite. J Environ Manage. https://doi.org/10.1016/j.jenvman.2013.09.044
Benning LG, Wilkin RT, Barnes HL (2000) Solubility and stability of zeolites in aqueous solution: II. Calcic clinoptilolite and mordenite. Am Mineral. https://doi.org/10.2138/am-2000-0411
Boumaza A, Favaro L, Lédion J, Sattonnay G, Brubach JB, Berthet P, Huntz AM, Roy P, Tétot R (2009) Transition alumina phases induced by heat treatment of boehmite: an X-ray diffraction and infrared spectroscopy study. J Solid State Chem. https://doi.org/10.1016/j.jssc.2009.02.006
Burris LE, Juenger MCG (2016) The effect of acid treatment on the reactivity of natural zeolites used as supplementary cementitious materials. Cem Concr Res 79:185–193. https://doi.org/10.1016/j.cemconres.2015.08.007
Chauhan M (2014) Needle shape morphology of natural Zeolites of Nazert, (Ethiopia). Chem Sci Trans 3(4):1455–1459. https://doi.org/10.7598/cst2014.864
Derbe T, Temesgen S, Bitew M (2021) A short review on synthesis, characterization, and applications of zeolites. Adv Mater Sci Eng. https://doi.org/10.1155/2021/6637898
Do DD (1998) Adsorption analysis: equilibria and kinetics. In Chemical Engineering, Vol. 2, Issue Imperial College Press
Ghadamnan E, Nabavi SR, Abbasi M (2019) Nano LTA zeolite in water softening process: synthesis, characterization, kinetic studies and process optimization by response surface methodology (RSM). J Water Environ Nanotechnol 4(2):119–138
Kanawade SM (2015) Removal of nitrate from groundwater by using natural zeolite as adsorbent. J Water Resour Hydraul Eng 3:125–132
Karapinar N (2009) Application of natural zeolite for phosphorus and ammonium removal from aqueous solutions. J Hazard Mater. https://doi.org/10.1016/j.jhazmat.2009.05.094
Loeb J (1923) The influence of the chemical nature of solid particles on their cataphoretic P.D. in aqueous solutions. J Gen Physiol. https://doi.org/10.1085/jgp.6.2.215
Ma J, Wang Y, Stevens GW, Mumford KA (2020) Hydrocarbon adsorption performance and regeneration stability of diphenyldichlorosilane coated zeolite and its application in permeable reactive barriers: Column studies. Microporous Mesoporous Mater. https://doi.org/10.1016/j.micromeso.2019.109843
Miandad R, Barakat MA, Rehan M, Aburiazaiza AS, Ismail IMI, Nizami AS (2017) Plastic waste to liquid oil through catalytic pyrolysis using natural and synthetic zeolite catalysts. Waste Manage. https://doi.org/10.1016/j.wasman.2017.08.032
Nizami AS, Ouda OKM, Rehan M, El-Maghraby AMO, Gardy J, Hassanpour A, Kumar S, Ismail IMI (2016) The potential of Saudi Arabian natural zeolites in energy recovery technologies. Energy. https://doi.org/10.1016/j.energy.2015.07.030
Rinaldi R, Schuchardt U (2005) On the paradox of transition metal-free alumina-catalyzed epoxidation with aqueous hydrogen peroxide. J Catal. https://doi.org/10.1016/j.jcat.2005.10.007
Rodeghero E, Martucci A, Cruciani G, Bagatin R, Sarti E, Bosi V, Pasti L (2016) Kinetics and dynamic behaviour of toluene desorption from ZSM-5 using in situ high-temperature synchrotron powder X-ray diffraction and chromatographic techniques. Catal Today 277:118–125. https://doi.org/10.1016/j.cattod.2015.11.031
Ruíz-Baltazar A, Esparza R, Gonzalez M, Rosas G, Pérez R (2015) Preparation and characterization of natural zeolite modified with iron nanoparticles. J Nanomater. https://doi.org/10.1155/2015/364763
Saranya R, Arthanareeswaran G, Ismail AF (2019) Enhancement of anti-fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration. J Chem Technol Biotechnol 94(9):2805–2815. https://doi.org/10.1002/jctb.6020
Trombetta M, Busca G, Storaro L, Lenarda M, Casagrande M, Zambon A (2000) Surface acidity modifications induced by thermal treatments and acid leaching on microcrystalline H-BEA zeolite zeolite. A FTIR, XRD and MAS-NMR study. Phys Chem Chem Phys. https://doi.org/10.1039/b001916j
Wang C, Li J, Sun X, Wang L, Sun X (2009) Evaluation of zeolites synthesized from fly ash as potential adsorbents for wastewater containing heavy metals. J Environ Sci. https://doi.org/10.1016/S1001-0742(09)60022-X
Wang S, Peng Y (2010) Natural zeolites as effective adsorbents in water and wastewater treatment. Chem Eng J. https://doi.org/10.1016/j.cej.2009.10.029
Acknowledgements
The authors thank the Deputyship for Research and Innovation, Ministry of Education in Saudi Arabia for funding this research work through the project number (20/8). This work was also supported by Deanship of Research at the Islamic University of Madinah. The authors extend their appreciation to all the associated personnel that have contributed to this study, especially Wastewater Treatment Plant of Al Madinah for proving wastewater samples.
Funding
This work is funded by the Deputyship of Research & Innovation, Ministry of Education in Saudi Arabia, through the project number [20/8].
Author information
Authors and Affiliations
Contributions
Conceptualization was done by A.A.; methodology was done by A.A. and H.A.; formal analysis was carried out by A.A.; investigation was carried out by A.A.; resources were done by A.A.; data curation was done by A.A. and H.A.; writing original draft preparation was done by A.A.; review and editing were performed by H.A.; visualization was done by A.A.; supervision was done by A.A.; project administration was done by A.A.; and funding acquisition was done by A.A.
Corresponding author
Ethics declarations
Conflict of interests
All authors have read and agreed to the published version of the manuscript, and they declare no conflict of interest.
Additional information
Editorial responsibility: Maryam Shabani.
Rights and permissions
About this article
Cite this article
Ahmed, A.T., Almohamadi, H. Chemical and microstructural studies for using natural zeolite in advanced wastewater treatment. Int. J. Environ. Sci. Technol. 20, 6491–6498 (2023). https://doi.org/10.1007/s13762-022-04384-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-022-04384-5