Abstract
Activated carbon is mainly an adsorbent material and for its versatile application in material science, it’s received much attention in recent years. Activated carbon can be prepared using different methods such as physical or chemical activation or physicochemical activation. As a precursor Paper Mill Sludge was used to prepare activated carbon by direct chemical activation where \({\mathrm{H}}_{3}{\mathrm{PO}}_{4}\) was used as an activating agent. Among different activation temperatures (200 °C, 250 °C, 300 °C, 350 °C, and 400 °C), high yield (49.2%) and iodine number (761.4 mg/g) were obtained at 250 °C with 30 min activation time. The decrease in iodine number and yield of activated carbon was observed with increasing temperature due to activation burn off at higher temperature. A higher iodine number indicates higher activation. The obtained product was characterized by using XRD, FTIR, and EDAX-SEM. FTIR indicates the presence of several aliphatic and aromatic carbons and XRD showed the presence of amorphous structure at the produced activated carbon. SEM showed an irregular and highly rough surface of activated carbon. All the studies of characterization reveal that paper mill sludge has been converted into activated carbon successfully. The novelty of this work is that activated carbon can be produced from paper mill sludge by direct chemical activation with less time and energy consumption. The textural properties and potential applications of obtained activated carbon will be done in our future research works.
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References
Abdullah R, Ishak CF, Kadir WR, Bakar RA (2015) Characterization and feasibility assessment of recycled paper mill sludges for land application in relation to the environment. Int J Environ Res Public Health 12:9314–9329. https://doi.org/10.3390/ijerph1208093144
Al-Qodah Z, Shawabkah R (2009) Production and characterization of granular activated carbon from activated sludge. Braz J Chem Eng 26(1):1–10. https://doi.org/10.1590/S0104-66322009000100012
Amit SKS, Islam MR (2016) Application of paper sludge ash in construction industry-a review. In: Proceedings of the 3rd international conference on civil engineering for sustainable development (ICCESD), Khulna University of Engineering and Technology, Khulna
Battaglia A, Calace N, Nardi E, Petronio BM, Pietroletti M (2003) Paper mill sludge–soil mixture: kinetic and thermodynamic tests of cadmium and lead sorption capability. Microchem J 75:97–102. https://doi.org/10.1016/S0026-265X(03)00074-2
Bian Y, Yuan Q, Zhu G, Ren B (2018) Recycling of waste sludge: preparation and application of sludge-based activated carbon. Int J Polym Sci 8320609:1–17. https://doi.org/10.1155/2018/8320609
Calace N, Nardi E, Petronio BM, Pietroletti M, Tosti G (2003) Metal ion removal from water by sorption on paper mill sludge. Chemosphere 51:797–803. https://doi.org/10.1016/S0045-6535(02)00864-0
Campbella AG, Zhanga X, Tripepi RR (1995) Composting and evaluating a pulp and paper sludge for use as a soil amendment/ mulch. Compost Sci Utilization 3(1):84–95
Chen CX, Huang B, Li T, Wu GF (2012) Preparation of phosphoric acid activated carbon from sugarcane bagasse by mechano-chemical processing. Bio-Resources 7(4):5109–5116
Davis E, Shaler SM, Goodell B (2003) The incorporation of paper deinking sludge into fiberboard. Forest Prod J 53(11):46–54
Evwierhoma ET, Madubiko OD, Jaiyeola A (2018) Preparation and characterization of activated carbon from bean husk. Niger J Technol (NIJOTECH) 37(3):674–678. https://doi.org/10.4314/njt.v37i3.17
Feihu Z, Sheng Z, Lei C, Zilei L, Junjie Q (2021) Utilization of bark waste of Acacia mangium: the preparation of activated carbon and adsorption of phenolic waste water. Ind Crops Prod 160:113–157. https://doi.org/10.1016/j.indcrop.2020.113157
Gibril ME, Lekha P, Andrew J, Sithole B, Tesfaye T, Ramjugernath D (2018) Beneficiation of pulp and paper mill sludge: production and characterization of functionalized crystalline nanocellulose. Clean Technol EnvironPolicy 20:1835–1845. https://doi.org/10.1007/s10098-018-1578-3
Gratuito MKB, Panyathanmaporn T, Chumnanklang RA, Sirinuntawittaya N, Dutta A (2008) Production of activated carbon from coconut shell: optimization using response surface methodology. Bioresour Technol 99:4887–4895. https://doi.org/10.1016/j.biortech.2007.09.042
Hanxi W, Jianling X, Xuejun L, Lianxi S (2021) Preparation of straw activated carbon and its application in wastewater treatment: a review. J Clean Prod 283:124–671. https://doi.org/10.1016/j.jclepro.2020.124671
Hesas RH, Arami-Niya A, Daud WMAW, Sahu JN (2013) Preparation and characterization of activated carbon from apple waste by microwave-assisted phosphoric acid activation: application in methylene blue adsorption. Bio-Resources 8(2):2950–2966
Hong Y, Shichao Z, Yan S, Xin Y (2012) Preparation and characterization of sludge activated carbon. Chin J Environ Eng 6:2138–2142
Jaria G, Calisto V, Silva CP, Gil MV (2019) Obtaining granular activated carbon from paper mill sludge–a challenge for application in the removal of pharmaceuticals from wastewater. Sci Total Environ 653:393–400. https://doi.org/10.1016/j.scitotenv.2018.10.346
Kairyte A (2017) Review on paper waste sludge and feasibility of it and its components to be recycled in polymer-based composites. Inter J Eng Appl Sci (IJEAS) 4(1):10–13
Kang HY, Park SS, Rim YS (2006) Preparation of activated carbon from paper mill sludge by KOH-activation. Korean J Chem Eng 23(6):948–995
KGaA M (2020) IR spectrum table by frequency range. https://www.sigmaaldrich.com/technical-documents/articles/biology/ir-spectrum-table.html
Khalili NR, Vyas JD, Weangkaew W, Westfall SJ, Parulekar SJ, Sherwood R (2002) Synthesis and characterization of activated carbon and bioactive adsorbent produced from paper mill sludge. Sep Purif Technol 26:295–304. https://doi.org/10.1016/S1383-5866(01)00184-8
Khalilia NR, Campbella M, Sandib G, Golas J (2000) Production of micro- and mesoporous activated carbon from paper mill sludge I. Effect zinc chloride activation. Carbon 38:1905–1915. https://doi.org/10.1016/S0008-6223(00)00043-9
Legrouri K, Khouya E, Ezzine M, Hannache H (2005) Production of activated carbon from a new precursor molasses by activation with sulphuric acid. J Hazard Mater 118(1–3):259–263. https://doi.org/10.1016/j.jhazmat.2004.11.004
Liang J, Li X, Yu Z, Zeng G, Luo Y, Jiang L, Yang Z, Qian Y, Wu H (2017) Amorphous MnO2 modified biochar derived from aerobically composted swine manure for adsorption of Pb (II) and Cd (II). ACS Sustain Chem Eng 5(6):5049–5058. https://doi.org/10.1021/acssuschemeng.7b00434
Likon M, Trebse P (2012) Recent advances in paper mill sludge management. Industrial Waste. https://doi.org/10.5772/37043
Lin X, Lin G, Huang B (2019) Synthesis of activated carbon from kenaf rod by physico-chemical coupling activation and its characterization. Mater Rep 33(1):198–202. https://doi.org/10.11896/cldb.201901024
Mao H, Zhou D, Hashisho Z, Wang S, Chen H, Wang H, Lashaki MJ (2015) Microporous activated carbon from pinewood and wheat straw by microwave assisted KOH treatment for the adsorption of toluene and acetone vapors. RSC Adv 5:36051–36058. https://doi.org/10.1039/c5ra01320h
Maulina S, Iriansyah M (2018) Characteristics of activated carbon resulted from pyrolysis of the oil palm fronds powder. IOP Conf Ser Mater Sci Eng 309(1):012072. https://doi.org/10.1088/1757-899X/309/1/012072
Mendesa CVT, Cruzb CHG, Reisa DFN (2016) Integrated bioconversion of pulp and paper primary sludge to second generation bioethanol using saccharomyces cerevisiae ATCC 26602. Bioresour Technol 220:161–167. https://doi.org/10.1016/j.biortech.2016.07.140
Moo-Young HK, Zimmie TF (1997) Waste minimization and re-use of paper sludge in landfill covers. Waste Manag & Res 15:593–605. https://doi.org/10.1177/0734242X9701500605
Moyo M, Nyamhere G, Sebata E, Guyo U (2014) Kinetic and equilibrium modeling of lead sorption from aqueous solution by activated carbon from goat dung. Desalin Water Treat 57:765–775. https://doi.org/10.1080/19443994.2014.968217
Nasr JB, Hamdi N, Elhalouani F (2017) Characterization of activated carbon prepared from sludge paper for methylene blue adsorption. J Mater Environ Sci 8(6):1960–1967
Ng C, Marshall WE, Rao RM, Bansode RR, Losso JN (2003) Activated carbon from pecan shell: process description and economic analysis. Ind Crops Prod 17:209–217. https://doi.org/10.1016/S0926-6690(03)00002-5
Oda TYR, Rezende AAP, Rde-CS S, Silva CM, Pereira AC (2021) Pulp mill sludge-derived carbon activated with an alternative source of chemicals and its application in wastewater treatment-an approach for byproducts valorization. J Environ Manag 298:113–477. https://doi.org/10.1016/j.jenvman.2021.113477
Rahim SS, Chelsea B, Mohamed GED, Junboum P (2021) High efficiency removal of heavy metals using tire-derived activated carbon vs. commercial activated carbon: Insights into the adsorption mechanisms. Chemosphere 2641:28–455. https://doi.org/10.1016/j.chemosphere.2020.128455
Rangari P, Chavan P (2017) A review on preparation of activated carbon from coconut shell. Int J Innov Res Sci Eng Technol 6(4):5829–5849. https://doi.org/10.15680/IJIRSET.2017.0604197
Reddy KSK, Shoaibi AA, Srinivasakannan C (2012) Activated carbon from date palm seed: process optimization using response surface methodology. Waste Biomass Valoriz 3(2):149–156. https://doi.org/10.1007/s12649-011-9104-4
Rhaman MT, Haque MA, Rouf MA, Siddique MAB, Islam MS (2015) Preparation and characterization of activated carbon & amorphous silica from rice husk. Bangladesh J Sci Ind Res 50(4):263–270. https://doi.org/10.3329/bjsir.v50i4.25835
Saleem J, Shahid UB, Hijab M, Mackey H, McKay G (2018) Production and application of activated carbon as adsorbents from olive stones. Biomass Convers Bio-Refin 9(4):775–802. https://doi.org/10.1007/s13399-019-00473-7
Salman JM (2014) Optimization of preparation conditions for activated carbon from palm oil fronds using response surface methodology on removal of pesticides from aqueous solution. Arab J Chem 7:101–108. https://doi.org/10.1016/j.arabjc.2013.05.033
Simão L, Hotza D, Raupp-Pereira F, Labrincha JA, Montedo ORK (2019) Characterization of pulp and paper mill waste for the production of waste-based cement. Rev Int Contam Ambient 35(1):237–246
Srinivasakannan C, Bakar MZA (2004) Production of activated carbon from rubber wood sawdust. Biomass Bioenergy 27(1):89–96. https://doi.org/10.1016/j.biombioe.2003.11.002
Sun K, Chun J (2010) Preparation and characterization of activated carbon from rubber-seed shell by physical activation with steam. Biomass Bioenerg 34(4):539–544. https://doi.org/10.1016/j.biombioe.2009.12.020
Wang X, Zhu N, Yin B (2008) Preparation of sludge-based activated carbon and its application in dye wastewater treatment. J Hazard Mater 153(1–2):22–27. https://doi.org/10.1016/j.jhazmat.2007.08.011
Wang Z, Ma X, Yao Z, Yu Q, Wang Z, Lin Y (2018) Study of the pyrolysis of municipal sludge in N2/CO2 atmosphere. Appl Therm Eng 128:662–671
Wang S, Nam H, Nam H (2020) Preparation of activated carbon from peanut shell with KOH activation and its application in H2S adsorption: isotherm and kinetic studies. J Environ Chem Eng 8(2):103683. https://doi.org/10.1016/j.jece.2020.103683
Wilson I (2006) Filler and coating pigments for papermakers. Industrial minerals and rocks, 7th edition, Society for mining, metallurgy and exploration, Inc. pp. 1287–1300. https://pdfs.semanticscholar.org/2484/13df9ebee0a690d2cfc36ecd5541a1896b06.pdf
Yakout SM, Sharaf EDG (2016) Characterization of activated carbon prepared by phosphoric acid activation of olive stones. Arab J Chem 9(2):1155–1162. https://doi.org/10.1016/j.arabjc.2011.12.002
Yimin Q (2016) Medical textile products for the control of odor. Med Text Mater 12:161–173. https://doi.org/10.1016/b978-0-08-100618-4.00012-1
Yu P, Wang X, Zhang K, Wu M, Wu Q, Liu J, Yang J, Zhang J (2020) Continuous purification of simulated wastewater based on rice straw composites for oil/ water separation and removal of heavy metal ions. Cellulose 27:5223–5239. https://doi.org/10.1007/s10570-020-03135-4
Yuan G, Qinyan Y, Baoyu G, Aimin L (2020) Insight into activated carbon from different kinds of chemical activating agents: a review. Sci Total Environ 746:141094. https://doi.org/10.1016/j.scitotenv.2020.141094
Zhang H, Shao J, Zhang S, Zhang X, Chen H (2020) Effect of phosphorus modified biochars on immobilization of Cu (II), Cd (II), and as (V) in paddy soil. J Hazard Mater 390:121349. https://doi.org/10.1016/j.jhazmat.2019.121349
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Mohammad Robel Molla and all authors are thankful to the authority of BCSIR for all kind of supports to carry out this research work.
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MHAB: Conceptualization, Investigation, Validation, Project administration, Supervision. ASMAR: Conceptualization, Investigation, Formal analysis, Writing—review & editing. MRM: Investigation, Validation, Formal analysis, Methodology, Writing—original draft, Writing—review & editing. MAR: Validation, Formal analysis, Writing—review & editing.
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Begum, M.H., Rahman, A.S.A., Molla, M.R. et al. Preparation and characterization of activated carbon from paper mill sludge by chemical activation: a waste management approach. Int. J. Environ. Sci. Technol. 20, 2757–2770 (2023). https://doi.org/10.1007/s13762-022-04169-w
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DOI: https://doi.org/10.1007/s13762-022-04169-w