Abstract
Ultrasound-assisted Fenton-like was utilized to leaching precious metals from spent automobile catalysts. The effect of different factors including solid to liquid (S/L) ratio, H2O2 percentage and initial Fe2+ concentration was done. Response surface methodology (RSM) was used to optimize the effective factors in the leaching of Al and Ce from the spent automobile catalyst. The optimum conditions for three effective factors were 0.01% (w/v) S/L ratio, 10.3% (v/v) H2O2 and 12.6% (w/v) Fe2+. The recovery efficiencies of Al and Ce in the optimum conditions were 81.7 and 47.2% in 4 h, respectively. In the absence of ultrasound, Al and Ce recoveries decreased to 69.5 and 13.4%, respectively. The residue after leaching was applied for Pt and Pd recovery using aqua regia, which results to 100% recovery. The modified shrinking core modeling results suggested that chemical reaction was the rate controlling step. The characterization methods including scanning electron microscopy (SEM) and X-ray diffraction (XRD) before and after bioleaching were performed.
Similar content being viewed by others
References
Adityosulindro S, Barthe L, González-Labrada K, Haza UJJ, Delmas H, Julcour C (2017) Sonolysis and sono-Fenton oxidation for removal of ibuprofen in (waste) water. Ultrason Sonochem 39:889–896
Ammar HB (2016) Sono-Fenton process for metronidazole degradation in aqueous solution: effect of acoustic cavitation and peroxydisulfate anion. Ultrason Sonochem 33:164–169
Azhdarpoor A, Hoseini R, Dehghani M (2015) Leaching Zn, Cd, Pb, and Cu from wastewater sludge using Fenton process. J Health Sci Surveill Syst 3(4):153–159
Brink A, Sheridan C, Harding K (2018) Combined biological and advance oxidation processes for paper and pulp effluent treatment. S Afr J Chem Eng 25:116–122
Chen A, Wang S, Zhang L, Peng J (2015) Optimization of the microwave roasting extraction of palladium and rhodium from spent automobile catalysts using response surface analysis. Int J Miner Process 143:18–24
Collivignarelli MC, Pedrazzani R, Sorlini S, Abbà A, Bertanza G (2017) H2O2 based oxidation processes for the treatment of real high strength aqueous wastes. Sustainability 9(2):244–257
de Aberasturi DJ, Pinedo R, de Larramendi IR, de Larramendi JR, Rojo T (2011) Recovery by hydrometallurgical extraction of the platinum-group metals from car catalytic converters. Miner Eng 24(6):505–513
Dong H, Zhao J, Chen J, Wu Y, Li B (2015) Recovery of platinum group metals from spent catalysts: a review. Int J Miner Process 145:108–113
Esmaeili M, Rastegar SO, Beigzadeh R, Gu T (2020) Ultrasound-assisted leaching of spent lithium ion batteries by natural organic acids and H2O2. Chemosphere 254:126670–126677
Hammadi MQ, Yassen RS, Abid KN (2017) Recovery of platinum and palladium from scrap automotive catalytic converters. Al Khwarizmi Eng J 13(3):131–141
Hou L, Wang L, Royer S, Zhang H (2016) Ultrasound-assisted heterogeneous Fenton-like degradation of tetracycline over a magnetite catalyst. J Hazard Mater 302:458–467
Jiang F, Chen Y, Ju S, Zhu Q, Zhang L, Peng J, Wang X, Miller JD (2018) Ultrasound-assisted leaching of cobalt and lithium from spent lithium-ion batteries. Ultrason Sonochem 48:88–95
Kim W, Kim B, Choi D, Oki T, Kim S (2010) Selective recovery of catalyst layer from supporting matrix of ceramic-honeycomb-type automobile catalyst. J Hazard Mater 183(1–3):29–34
M’Arimi MM, Mecha CA, Kiprop AK, Ramkat R (2020) Recent trends in applications of advanced oxidation processes (AOPs) in bioenergy production: review. Renew Sustain Energy Rev 121:109669–109686
Mashayekh-Salehi A, Akbarmojeni K, Roudbari A, van der Hoek JP, Nabizadeh R, Dehghani MH, Yaghmaeian K (2021) Use of mine waste for H2O2-assisted heterogeneous Fenton-like degradation of tetracycline by natural pyrite nanoparticles: catalyst characterization, degradation mechanism, operational parameters and cytotoxicity assessment. J Clean Prod 291:125235–125252
Matavos-Aramyan S, Moussavi M (2017) Advances in Fenton and Fenton based oxidation processes for industrial effluent contaminants control-a review. Int J Environ Sci Nat Resour 2(4):1–18
Motaghed M, Mousavi SM, Rastegar SO, Shojaosadati SA (2014) Platinum and rhenium extraction from a spent refinery catalyst using Bacillus megaterium as a cyanogenic bacterium: statistical modeling and process optimization. Bioresour Technol 171:401–409
Rahimi G, Rastegar SO, Chianeh FR, Gu T (2020) Ultrasound-assisted leaching of vanadium from fly ash using lemon juice organic acids. RSC Adv 10(3):1685–1696
Rastegar SO, Mousavi SM, Shojaosadati SA, Mamoory RS (2015) Bioleaching of V, Ni, and Cu from residual produced in oil fired furnaces using Acidithiobacillus ferrooxidans. Hydrometallurgy 157:50–59
Rzelewska M, Regel-Rosocka M (2018) Wastes generated by automotive industry–Spent automotive catalysts. Phys Sci Rev 3(8):43–80
Saternus M, Fornalczyk A, Gasior W, Debski A, Terlicka S (2020) Modifications and improvements to the collector metal method using an mhd pump for recovering Platinum from used car catalysts. Catalysts 10:880–896
Senthil K, Akiba U, Fujiwara K, Kondo Y (2017) Highly selective separation and recovery of Pd (II) from the automotive catalyst residue with the thiocarbamoyl substituted azothiacalix [4] arene derivative. Sep Sci Technol 52(8):1365–1376
Trinh HB, Lee JC, Srivastava RR, Kim S, Ilyas S (2017) Eco-threat minimization in HCl leaching of PGMs from spent automobile catalysts by formic acid prereduction. ACS Sustain Chem Eng 5(8):7302–7309
Upadhyay AK, Lee JC, Kim EY, Kim MS, Kim BS, Kumar V (2013) Leaching of platinum group metals (PGMs) from spent automotive catalyst using electro-generated chlorine in HCl solution. J Chem Technol Biotechnol 88(11):1991–1999
Vyas S, Ting YP (2018) A review of the application of ultrasound in bioleaching and insights from sonication in (bio) chemical processes. Resources 7(1):3–18
Wahyuni ET, Siswanta D, Kunarti ES, Supraba D, Budiraharjo S (2019) Removal of Pb (II) ions in the aqueous solution by photo-Fenton method. Global NEST J 21:180–186
Wei X, Liu C, Cao H, Ning P, Jin W, Yang Z, Wang H, Sun Z (2019) Understanding the features of PGMs in spent ternary automobile catalysts for development of cleaner recovery technology. J Clean Prod 239:118031–118040
Zhang RL, Zhang XF, Tang SZ, Huang AD (2015) Ultrasound-assisted HCl–NaCl leaching of lead-rich and antimony-rich oxidizing slag. Ultrason Sonochem 27:187–191
Acknowledgements
The authors appreciate the support from the Department of Chemical Engineering at the University of Kurdistan.
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial responsibility: Maryam Shabani.
Rights and permissions
About this article
Cite this article
Hosseinzadeh, F., Rastegar, S.O., Ashengroph, M. et al. Ultrasound-assisted Fenton-like reagent to leach precious metals from spent automotive catalysts: process optimization and kinetic modeling. Int. J. Environ. Sci. Technol. 18, 3449–3458 (2021). https://doi.org/10.1007/s13762-021-03324-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-021-03324-z