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Magnetic and microscopic characterization of anthropogenically produced magnetic particles: a proxy for environmental pollution

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Abstract

The employment of magnetic characterization of anthropogenically produced magnetic particles (APMs) as a proxy for discriminating the pollution sources around Kolaghat thermal power station, West Bengal, India, is complemented by microscopic analysis and elemental composition in the present study. The magnetic measurements such as magnetic susceptibility (χlf), isothermal remanent magnetization, coercivity spectra, hysteresis measurements, and thermomagnetic curves (κ − T) were implemented to evaluate the magnetic gestures of APMs, which are accompanied by scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS) analysis to explore the morphological characteristics. The studied samples illustrated a wide variety of χlf values, which were determined by the concentration of APMs. The magnetic measurements revealed that the studied samples comprised pseudo-single-domain magnetite with minor titanomagnetite (s), maghemite, and hematite/goethite. SEM analysis portrayed varied morphological properties of APMs like spherules (viz. smooth, hollow, and meld-like spherules), which are usually coupled with fossil fuel combustion, and irregular-shaped APMs, which are generated from traffic emission and natural background input. Elemental composition as interpreted by EDS analysis displays varied composition of APMs, which indicates the influence of industrial and traffic emissions in the study area. This study exhibited that magnetic and microscopic characterization of APMs can be used as an appropriate tracer for soil and dust pollution, which provides significant perspectives for further detailed chemical mapping.

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References

  • Aguilar Reyes B, Bautista F, Goguitchaichvili A, Morton O (2011) Magnetic monitoring of top soils of merida (southern mexico). Stud Geophys Geod 55:377–388

    Google Scholar 

  • Basavaiah N (2011) Geomagnetism: solid earth and upper atmosphere perspectives. Springer, Dordrecht

    Google Scholar 

  • Basavaiah N, Blaha U, Das PK, Deenadayalan K, Sadashiv MB, Schulz H (2012) Evaluation of environmental magnetic pollution screening in soils of basaltic origin: results from Nashik Thermal Power Station, Maharashtra, India. Environ Sci Pollut Res 19:3028–3038

    CAS  Google Scholar 

  • Bijaksana S, Huliselan EK (2010) Magnetic properties and heavy metal content of sanitary leachate sludge in two landfill sites near Bandung, Indonesia. Environ Earth Sci 60(2):409–419

    CAS  Google Scholar 

  • Blaha U, Sapkota B, Appel E, Stanjek H, Rösler W (2008) Micro-scale grain-size analysis and magnetic properties of coal-fired power plant fly ash and its relevance for environmental magnetic pollution studies. Atmos Environ 42(36):8359–8370

    CAS  Google Scholar 

  • Blundell A, Hannam JA, Dearing JA, Boyle JF (2009) Detecting atmospheric pollution in surface soils using magnetic measurements: a reappraisal using an England and Wales database. Environ Pollut 157:2878–2890

    CAS  Google Scholar 

  • Boyko T, Scholger R, Stanjek H (2004) Topsoil magnetic susceptibility mapping as a tool for pollution monitoring: repeatability of in situ measurements. J Appl Geophys 55:249–259

    Google Scholar 

  • Bucko MS, Magiera T, Johanson B, Petrovsky E, Pesonen LJ (2011) Identification of magnetic particulates in road dust accumulated on roadside snow using magnetic, geochemical and micro-morphological analyses. Environ Pollut 159:1266–1276

    CAS  Google Scholar 

  • Bućko MS, Magiera T, Pesoen LJ, Janus B (2010) Magnetic, geochemical, and microstructural characteristics of road dust on roadsides with different traffic volumes-case Study from Finland. Water Air Soil Pollut 209:295–306

    Google Scholar 

  • Carraz F, Taylor KG, Stainsby S, Robertson D (2006) Contaminated urban road deposited sediment (RDS), Greater Manchester, UK: a spatial assessment of potential surface water impacts. North West Geogr 6(1):10–19

    Google Scholar 

  • Chaparro MAE, Bidegain JC, Sinito AM, Jurado SS, Gogorza CSG (2004) Relevant magnetic parameters and heavy metals from relatively polluted stream sediments- Vertical and longitudinal distribution along a cross-city stream in Buenos Aires Province, Argentina. Stud Geophys Geod 48(3):615–636

    Google Scholar 

  • Chaparro MAE, Gogorza CSG, Irurzun MA, Sinito AM (2006) Review of magnetism and heavy metal pollution studies of various environments in Argentina. Earth Planets Space 58:1411–1422

    CAS  Google Scholar 

  • Crosby CJ (2012) Application of mineral magnetic measurements as a pollution proxy for urban road deposited sediment. Ph.D. thesis, University of Wolverhampton

  • Crosby CJ, Fullen MA, Booth CA, Searle DE (2014) A dynamic approach to urban road deposited sediment pollution monitoring (Marylebone Road, London, UK). J Appl Geophys 105:10–20

    Google Scholar 

  • Day R, Fuller M, Schmidt VA (1977) Hysteresis properties of titanomagnetites: grain-size and compositional dependence. Phys Earth Planet Int 13:260–267

    Google Scholar 

  • Dearing JA, Dann RJL, Hay K, Lees JA, Loveland PJ, Maher BA, O’Grady K (1996) Frequency-dependent susceptibility measurements of environmental materials. Geophys J Int 124:228–240. https://doi.org/10.1111/j.1365-246X.1996.tb06366.x

    Article  Google Scholar 

  • Dekkers MJ, Pietersen HS (1992) Magnetic properties of low-Ca fly ash: A rapid tool for Fe-assessment and a survey for potentially hazardous elements. In: Glasser FP, McCarthy GJ, Young JF, Mason TO, Pratt PL (eds) Advanced cementitious Systems-Materials Res. Soc. Proc 245: 37–47

  • D’Emilio M, Caggiano R, Coppola R, Macchiato M, Ragosta M (2010) Magnetic susceptibility measurements as proxy method to monitor soil pollution: the case study of S. Nicola di Melfi. Environ Monit Assess 169:619–630. https://doi.org/10.1007/s10661-009-1201-5

    Article  Google Scholar 

  • Duan X, Hu S, Yan H, Blaha U, Roesler W, Appel E, Sun W (2010) Relationship between magnetic parameters and heavy element contents of arable soil around a steel company, Nanjing. Sci China Earth Sci 53:411–418. https://doi.org/10.1007/s11430-009-0165-1

    Article  CAS  Google Scholar 

  • Dunlop DJ (2002) Theory and application of the Day plot (Mrs/Ms versus Hcr/Hc) 1. Theoretical curves and tests using titanomagnetite data. J Geophys Res 107:1–22

    Google Scholar 

  • Dunlop DJ, Özdemir Ö (1997) Rock magnetism, fundamentals and frontiers. Cambridge University Press, Cambridge. https://doi.org/10.1017/CBO9780511612794

    Book  Google Scholar 

  • Evans ME, Heller F (2003) Environmental magnetism: principles and applications of enviromagnetics. Academic, San Diego

    Google Scholar 

  • Flanders PJ (1999) Identifying fly ash at a distance from fossil fuel power stations. Environ Sci Technol 33:528–532

    CAS  Google Scholar 

  • Gargiulo JD, Senthil Kumar R, Chaparro MAE, Chaparro MAE, Natal Marcela, Rajkumar P (2016) Magnetic properties of air suspended particles in thirty eight cities from south India. Atmos Pollut Res 7–4:626–637

    Google Scholar 

  • Gautam P, Blaha U, Appel E (2005) Magnetic susceptibility of dust-loaded leaves as a proxy of traffic related heavy metal pollution in Kathmandu city, Nepal. Atmos Environ 39:2201–2211

    CAS  Google Scholar 

  • Goddu SR, Appel E, Jordanova D, Wehland R (2004) Magnetic properties of road dust from Visakhapatnam (India)—relationship to industrial pollution and road traffic. Phys Chem Earth 29(13, 14):985–995

    Google Scholar 

  • Gudadhe SS, Sangode SJ, Patil SK, Chate DM, Meshram DC, Badekar AG (2012) Pre- and post-monsoon variations in the magnetic susceptibilities of soils of Mumbai metropolitan region: implications to surface redistribution of urban soils loaded with anthropogenic particulates. Environ Earth Sci 67:813–831. https://doi.org/10.1007/s12665-012-1528-z

    Article  CAS  Google Scholar 

  • Hoffmann V, Knab M, Appel E (1999) Magnetic susceptibility mapping of roadside pollution. J Geochem Explor 66:313–326

    CAS  Google Scholar 

  • Iordanidis A, Buckman J, Triantafyllou AG, Asvesta A (2008) ESEM-EDX characterisation of airborne particles from an industrialised area of northern Greece. Environ Geochem Health 30:391–405

    CAS  Google Scholar 

  • Jordanova NV, Jordanova DV, Veneva L, Yorova K, Petrovský E (2003) Magnetic response of soils and vegetation to heavy metal pollution—a case study. Environ Sci Technol 37(19):4417–4424

    CAS  Google Scholar 

  • Kanu MO, Basavaiah N, Meludu OC et al (2017) Investigating the potential of using environmental magnetism techniques as pollution proxy in urban road deposited sediment. Int J Environ Sci Technol 14:2745–2758. https://doi.org/10.1007/s13762-017-1356-5

    Article  Google Scholar 

  • Kapicka A, Petrovsky E, Ustjak S, Machackova K (1999) Proxy mapping of fly-ash pollution of soils around a coal burning power plant: a case study in the Czech Republic. J Geochem Explor 66(1–2):291–297

    CAS  Google Scholar 

  • Karimi R, Ayoubi S, Jalalian A, Sheikh-Hosseini AR, Afyuni M (2011) Relationships between magnetic susceptibility and heavy metals in urban topsoils in the arid region of Isfahan, central Iran. J Appl Geophys 74:1–7. https://doi.org/10.1016/j.jappgeo.2011.02.009

    Article  Google Scholar 

  • Kim W, Doh SJ, Park YH, Yun ST (2007) Two-year magnetic monitoring in conjunction with geochemical and electron microscopic data of roadside dust, Seoul, Korea. Atmos Environ 41:7627–7641

    CAS  Google Scholar 

  • Kim W, Dosh SJ, Yui Y (2009) Anthropogenic contribution of magnetic particulates in urban roadside dust. Atmos Environ 43:3137–3144

    CAS  Google Scholar 

  • Liu Q, Roberts AP, Larrasoaña JC, Banarejee SK, Guyodo Y, Tauxe L, Oldfield F (2012) Environmental Magnetism: principles and applications. Rev Geophys 50:RG4002

    Google Scholar 

  • Liu D, Ma J, Sun Y, Li Y (2016) spatial distribution of soil magnetic susceptibility and correlation with heavy metal pollution in Kaifeng City, China. CATENA 139:53–60

    CAS  Google Scholar 

  • Lu SG, Bai SQ (2006) Study on the correlation of magnetic properties and heavy metals content in urban soils of Hangzhou City, China. J Appl Geophys 60:1–12. https://doi.org/10.1016/j.jappgeo.2005.11.002

    Article  Google Scholar 

  • Lu SG, Bai SQ (2008) Magnetic characterization and magnetic mineralogy of the Hangzhou urban soils and its environmental implications. Chin J Geophys 51(3):762–769 (in Chinese)

    CAS  Google Scholar 

  • Lu SG, Bai SQ, Xue QF (2007) Magnetic particles as indicators of heavy metals pollution in urban soils: a case study from the City of Luoyang, China. Geophys J Int 171:603–612

    Google Scholar 

  • Magiera T, Goluchowska B, Jablonska M (2013) Technogenic magnetic particles in alkaline dusts from power and cement plants. Water Air Soil Pollut 224:1389–1406

    Google Scholar 

  • Maher BA, Moore C, Matzka J (2008) Spatial variation in vehicle-derived metal pollution identified by magnetic and elemental analysis of roadside tree leaves. Atmos Environ 42(2):364–373

    CAS  Google Scholar 

  • Matysek D, Raclavska H, Raclavsky K (2008) Correlation Between Magnetic Susceptibility and Heavy Metal Concentrations in Forest Soils of the Eastern Czech Republic. J Environ Eng Geophys 13:13–26

    Google Scholar 

  • Mondal T, Sengupta D, Mandal A (2006) Natural radioactivity of ash and coal in major thermal power plants of West Bengal, India. Curr Sci 91:1387–1393

    CAS  Google Scholar 

  • Morel JL, Heinrich A (2008) SUITMA-soils in urban, industrial, traffic, mining and military areas. J Soils Sediments 8:206–207

    Google Scholar 

  • Panaiotu CG, Necula C, Panaiotu CE, Axente V (2005) A magnetic investigation of heavy metals pollution in Bucharest. In: Ionel I (ed) Sustainability for humanity and environment in the extended connection field science-economy-policy, Scientific reunion of the special program of Alexander von Hombold Foundation concerning the reconstruction of the South Eastern Europe, Editura Politehnica, Timisoara (ISBN 973-625-204-3), 83–86

  • Petrovský E, Alcala MD, Criado JM, Grygar T, Kapička A, Subrt J (2000) Magnetic properties of magnetite prepared by ball-milling of hematite with iron. J Magn Magn Mater 210:257–273

    Google Scholar 

  • Ramasamy V, Suresh G, Venkatachalapathy R (2009) Magnetic susceptibility of the ponnaiyar river Sediments, Tamilnadu, India. Glob J Environ Res 3(2):126–131

    Google Scholar 

  • Reis AR, Oliveira AI, Pinto JPM, Parker A (2014) Occurrence and distribution of metals in urban road deposited sediments in a small urban area: preliminary results of a study in Vila Real city, northern Portugal. Comun Geol 101(Especial II):1055–1058

  • Reyes BA, Bautista F, Goguitchaichvili A, Contrras JJM, Owen PQ, Carvallo C, Battu J (2013) Rock magnetic properties of topsoils and urban dust from Morelia (> 800,00 inhabitants), Mexico: implications for anthropogenic pollution monitoring in Mexico’s medium size Cities. Geofis Int 52–2:121–133

    Google Scholar 

  • Sangode SJ, Vhatkar K, Patil SK, Meshram DC, Pawar NJ, Gudadhe SS, Badekar AG, Kumaravel V (2010) Magnetic susceptibility distribution in the soils of Pune Metropolitan Region: implications to soil magnetometry of anthropogenic loading. Curr Sci 98–4:516–527

    Google Scholar 

  • Schmidt A, Yarnold R, Hill M, Ashmore M (2005) Magnetic susceptibility as proxy for heavy metal pollution: a site study. J Geochem Explor 85:109–117. https://doi.org/10.1016/j.gexplo.2004.12.001

    Article  CAS  Google Scholar 

  • Shan HD, Lu SG (2005) Mineral magnetism of power-plant fly ash and its environmental implication. Acta Miner Sin 25:141–146

    Google Scholar 

  • Shenggao L, Xi Y, Chen Y (2016) Magnetic properties, microstructure and mineralogical phases of technogenic magnetic particles (TMPs) in urban soils: their source identification and environmental implications. Sci Total Environ 543:239–247

    Google Scholar 

  • Spassov S, Egli R, Heller F, Nourgaliev DK, Hannam J (2004) Magnetic quantification of urban pollution sources in atmospheric particulate matter. Geophys J Int 159:555–564

    CAS  Google Scholar 

  • Thompson R, Oldfield F (1986) Environmental magnetism. Allen and Unwin, London, pp 1–227

    Google Scholar 

  • Turekian K, Wedepohl H (1961) Distribution of the elements in some major units of the earth’s crust. Geol Soc Am Bull 72:175–192

    CAS  Google Scholar 

  • Vassilev S, Vassileva C (2007) A new approach for the classification of coal fly ashes based on their origin, composition, properties, and behaviour. Fuel 86:1490–1512

    CAS  Google Scholar 

  • Vassilev SV, Vassilev GG, Karayigit AI, Bulut Y, Alastuey A, Querol X (2005) Phase-mineral and chemical composition of fractions separated from composite fly ashes at the Soma power station, Turkey. Int J Coal Geol 61:65–85

    CAS  Google Scholar 

  • Veneva L, Hoffmann V, Jordanova D, Jordanova N, Fehr T (2004) Rock magnetic, mineralogical and microstructural characterization of fly ashes from Bulgarian power plants and the nearby anthropogenic soils. Phys Chem Earth 29(13–14):1011–1023

    Google Scholar 

  • Venkatachalapathy R, Rajeswari V, Basavaiah N, Balasubramanian T (2013) Environmental magnetic studies on surface sediments: a proxy for metal and hydrocarbon contamination. Int J Environ Sci Technol. https://doi.org/10.1007/s13762-013-0355-4

    Article  Google Scholar 

  • Wang XS (2014) Mineralogical and chemical composition of magnetic fly ash fraction. Environ Earth Sci 71:1673–1681

    CAS  Google Scholar 

  • Wang XS, Qin Y (2006) Magnetic properties of urban topsoils and correlation with heavy metals: a case study from the city of Xuzhou. China Environ Geol 49(6):897–904

    CAS  Google Scholar 

  • Wang B, Xia DS, Yu Y, Jia J, Xu SJ (2013) Magnetic records of heavy metal pollution in urban topsoil in Lanzhou, China. Chin Sci Bull 158:384–395

    Google Scholar 

  • Wong CSC, Li XD, Thornton I (2006) Urban environmental geochemistry of trace metals. Environ Pollut 142:1–16

    CAS  Google Scholar 

  • Yan Z, ShiHong Z (2008) Magnetic properties of street dust and topsoil in Bejing and its environmental implications. Chin Sci Bull 53:408–417

    Google Scholar 

  • Yang T, Liu Q, Zeng Q, Chan L (2010) Anthropogenic magnetic particles and heavy metals in the road dust: magnetic identification and its implications. Atmos Environ 44:1175–1185

    CAS  Google Scholar 

  • Yang T, Liu Q, Zeng Q, Chan L (2012) Relationship between magnetic properties and heavy metals of urban soils with different soil types and environmental settings: implications for magnetic mapping. Environ Earth Sci 66:409–420. https://doi.org/10.1007/s12665-011-1248-9

    Article  CAS  Google Scholar 

  • Yang JP, Zhao YC, Zyryanov V, Zhang JY, Zheng CG (2014) Physical-chemical characteristics and elements enrichment of magnetospheres from coal fly ashes. Fuel 135:15–26

    CAS  Google Scholar 

  • Zhang C, Huang B, Li Z, Liu H (2006) Magnetic properties of high-road-side pine tree leaves in Beijing and their environmental significance. Chin Sci Bull 51:3041–3052. https://doi.org/10.1007/s11434-006-2189-7

    Article  CAS  Google Scholar 

  • Zhang CX, Huang BC, Liu QS (2009) Magnetic properties of different receptors around steel plants and their environmental significance. Chin J Geophys 52(11):2826–2839

    Google Scholar 

  • Zhang CX, Liu QS, Huang BC, Su YL (2010) Magnetic enhancement upon heating of environmentally polluted samples containing hematite and iron. Geophys J Int 181:1381–1394

    CAS  Google Scholar 

  • Zhang CX, Qiao QQ, Piper JDA, Huang BC (2011) Assessment of heavy metal pollution from a Fe-smelting plant in urban river sediments using environmental magnetic and geochemical methods. Environ Pollut 159:3057–3070

    CAS  Google Scholar 

  • Zhao Y, Zhang J, Sun J, Bai X, Zheng C (2006) Mineralogy, chemical composition, and microstructure of ferrospheres in fly ashes from coal combustion. Energy Fuel 20:1490–1497

    CAS  Google Scholar 

  • Zhu Z, Li Z, Bi X, Han Z, Yu G (2013) Response of magnetic properties to heavy metal pollution in dust from three industrial cities in China. J Hazard Matter 246–247:189–198

    Google Scholar 

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Acknowledgements

We acknowledge the Department of Geological Sciences, Jadavpur University, Kolkata, for scope of research and thank Director, CSIR-NGRI, Hyderabad, for providing the laboratory facilities. S. Mondal thanks the University Grant Commission (UPE II Scheme) for the financial support during field work. R. Maity is grateful to RUSA (Rashtriya Uchchatar Shiksha Abhiyan) 2.0 for fellowship.

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  1. Department of Geological Sciences, Jadavpur University, Kolkata, 700032, India

    R. Maity, S. Mondal, D. Gain & P. Paul

  2. CSIR-National Geophysical Research Institute, Hyderabad, 500007, India

    M. Venkateshwarlu & M. R. Kapawar

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Maity, R., Venkateshwarlu, M., Mondal, S. et al. Magnetic and microscopic characterization of anthropogenically produced magnetic particles: a proxy for environmental pollution. Int. J. Environ. Sci. Technol. 18, 1793–1808 (2021). https://doi.org/10.1007/s13762-020-02902-x

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