Abstract
This manuscript reports the study of lanthanum- and cerium-based surface functionalization of activated carbons and chars, prepared from a lignocellulosic-based precursor, for facing the geogenic water pollution caused by fluoride and arsenic (V) ions. The incorporation of these rare elements on the adsorbents increased the adsorption capacities up to 2537% especially for arsenic (V). Chars and activated carbons functionalized with lanthanum and cerium showed adsorption capacities of 1.3–9.2 mg/g and 0.1–9.2 mg/g for fluoride and arsenic (V) ions, respectively. However, the adsorbents with lanthanum functional groups were the best for the removal of these hazardous water pollutants. A detailed physicochemical characterization of the adsorbents was utilized to explain their adsorption properties. Results showed that a ligand exchange of OH− from adsorbent surfaces and the presence of electrostatic forces could be associated to the adsorption mechanism of fluoride and arsenic (V) ions. Simultaneous adsorption of fluoride and arsenic (V) ions was antagonistic using lanthanum-modified adsorbents where fluoride ion reduced significantly the removal of arsenic (V) species. Therefore, new findings are reported for the tailoring of surface chemistry of chars and activated carbons for reducing the risks caused by geo-environmental hazardous chemicals dissolved in water.
Similar content being viewed by others
References
Abbasizadeh S, Karimzadeh R (2018) Effect of framework single and close (pairs and un-pairs) aluminum atoms on phosphorous modification of HZSM-5 in cracking of liquefied petroleum gas to ethylene and propylene. Microporous Mesoporous Mater 266:132–140
Abdolali A, Ngo H, Guo W, Zhou J, Du B, Wei Q (2015) Characterization of a multi-metal binding biosorbent: chemical modification and desorption studies. Bioresour Technol 193:477–487
Arcibar-Orozco JA, Delgado-Balbuena J, Rios-Hurtado JC, Rangel-Mendez JR (2014) Influence of iron content, surface area and charge distribution in the arsenic removal by activated carbons. Chem Eng J 249:201–209
Asere TG, Stevens CV, Laing GD (2019) Use of (modified) natural adsorbents for arsenic remediation: a review. Sci Total Environ 676:706–720
Attinti R, Sarkar D, Barrett KR, Datta R (2015) Adsorption of arsenic(V) from aqueous solutions by goethite/silica nanocomposite. Int J Environ Sci Technol 12:3905–3914
Bektas N, Aydin S, Oncel M (2011) The adsorption of arsenic ions using beidellite, zeolite, and sepiolite clays: a study of kinetic, equilibrium and thermodynamics. Sep Sci Technol 46:1005–1016
Bhatnagar A, Kumar E, Sillanpaa M (2011) Fluoride removal from water by adsorption—a review. Chem Eng J 171:811–840
He R, Peng Z, Lyu H, Huang H, Nan Q, Tang J (2018) Synthesis and characterization of an iron-impregnated biochar for aqueous arsenic removal. Sci Total Environ 612:177–1186
Hidayu AR, Muda N (2016) Preparation and characterization of impregnated activated carbon from palm kernel shell and coconut shell for CO2 capture. Procedia Eng 148:106–113
Karmakar S, Mukherjee J, Mukherjee S (2018) Biosorption of fluoride by water lettuce (Pistia stratiotes) from contaminated water. Int J Environ Sci Technol 15:801–810
Kimambo V, Bhattacharya P, Mtalo F, Mtamba J, Ahmad A (2019) Fluoride occurence in groundwater systems at global scale and status of defluoridation—state of the art. Groundw Sustain Dev 9:100223
Li Z, Qu J, Li H, Lim T, Liu C (2011) Effect of cerium valence on As (V) adsorption by cerium-doped titanium dioxide adsorbents. Chem Eng J 175:207–212
Li W, Ding Y, Zhang W, Shu Y, Zhang L, Yang F, Shen Y (2016) Lignocellulosic biomass for ethanol production and preparation of activated carbon applied for supercapacitor. J Taiwan Inst Chem Eng 64:166–172
Lin J, Wu Y, Khayambashi A, Wang X, Wei Y (2018) Preparation of a novel CeO2/SiO2 adsorbent and its adsorption behavior for fluoride ion. Adsorpt Sci Technol 36:743–761
Liu Y, Liu YJ (2008) Biosorption isotherms, kinetics and thermodynamics. Sep Purif Technol 61:229–242
Liu R, Zhu L, He Z, Lan H, Liu H, Qu J (2015) Simultaneous removal of arsenic and fluoride by freshly-prepared aluminum hydroxide. Colloids Surface A 466:147–153
Mafua LD, Neomagus HWJP, Everson RC, Strydoma CA, Carrier M, Okolo GN, Bunt JR (2017) Chemical and structural characterization of char development during lignocellulosic biomass pyrolysis. Bioresour Technol 243:941–948
Mullick A, Neogi S (2018) Acoustic cavitation induced synthesis of zirconium impregnated activated carbon for effective fluoride scavenging from water by adsorption. Ultrason Sonochem 45:65–77
Pandey AK, Negi S (2015) Impact of surfactant assisted acid and alkali pretreatment on lignocellulosic structure of pine foliage and optimization of its saccharification parameters using response surface methodology. Bioresour Technol 192:115–125
Pongener C, Bhomick PC, Supong A, Baruah M, Sinha UB, Sinha D (2018) Adsorption of fluoride onto activated carbon synthesized from Manihot esculenta biomass—equilibrium, kinetic and thermodynamic studies. J Environ Chem Eng 6:2382–2389
Rivera-Utrilla J, Sanchez-Polo M, Gomez-Serrano V, Alvarez PM, Alvim-Ferraz MCM, Dias JM (2011) Activated carbon modifications to enhance its water treatment applications: an overview. J Hazard Mater 187:1–23
Rojas-Mayorga CK, Bonilla-Petriciolet A, Silvestre-Albero J, Aguayo-Villarreal IA, Mendoza-Castillo DI (2015) Physico-chemical characterization of metal-doped bone chars and their adsorption behavior for water defluoridation. Appl Surf Sci 335:748–760
Salomón-Negrete MA, Reynel-Ávila HE, Mendoza-Castillo DI, Bonilla-Petriciolet A, Duran-Valle CJ (2018) Water defluoridation with avocado-based adsorbents: synthesis, physicochemical characterization and thermodynamic studies. J Mol Liq 254:188–197
Singh K, Lataye DH, Wasewar KL (2017) Removal of fluoride from aqueous solution by using Bael (Aegle marmelos) shell activated carbon: kinetic, equilibrium and thermodynamic study. J Fluor Chem 194:23–32
Te B, Wichitsathian B, Yossapol C, Wonglertarak W (2018) Development of low-cost iron mixed porous pellet adsorbent by mixture design approach and its application for arsenate and arsenite adsorption from water. Adsorpt Sci Technol 36:372–392
Tran HN, You SJ, Hosseini-Bandegharaei A, Chao HP (2017) Mistakes and inconsistencies regarding adsorption of contaminants from aqueous solutions: a critical review. Water Res 120:88–116
Velazquez-Jimenez LH, Arcibar-Orozco JA, Rangel-Mendez JR (2018) Overview of As(V) adsorption of Zr-functionalized activated carbon for aqueous streams remediation. J Environ Manag 212:121–130
Vences-Álvarez E, Velázquez-Jiménez LH, Chazaro-Ruiz LF, Díaz-Flores PE, Rangel-Méndez JR (2015) Fluoride removal in water by a hybrid adsorbent lanthanum-carbon. J Colloid Interface Sci 455:194–202
Wu K, Zhang N, Liu T, Ma C, Jin P, Zhang F, Zhang J, Wang X (2017) Competitive adsorption behaviors of arsenite and fluoride onto manganese-aluminum binary adsorbents. Colloids Surf A 529:185–194
Zhang L, Zhu T, Liu X, Zhang W (2016) Simultaneous oxidation and adsorption of As(III) from water by cerium modified chitosan ultrafine nanobiosorbent. J Hazard Mater 308:1–10
Acknowledgements
Authors acknowledge the financial support provided by CONACYT and Instituto Tecnológico de Aguascalientes.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
None.
Additional information
Editorial responsibility: BV Thomas.
Rights and permissions
About this article
Cite this article
Merodio-Morales, E.E., Reynel-Ávila, H.E., Mendoza-Castillo, D.I. et al. Lanthanum- and cerium-based functionalization of chars and activated carbons for the adsorption of fluoride and arsenic ions. Int. J. Environ. Sci. Technol. 17, 115–128 (2020). https://doi.org/10.1007/s13762-019-02437-w
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-019-02437-w