Abstract
In the present research, removal of a common pharmaceutical contaminant from wastewater was studied using micellar-enhanced ultrafiltration (MEUF) process with applying a laboratory-scale system. Sodium dodecyl sulfate surfactant was used in this process. Response surface methodology (RSM) was applied for evaluating the MEUF process performance. The results obtained from the experiments showed that sotalol hydrochloride drug rejection using ultrafiltration membrane was maximum 32.41%, while by adding the surfactant and forming the micelle this amount increased to 96.82%. By using the RSM and investigating the interaction of surfactant concentration, transmembrane pressure (TMP), and pH, it was found that the surfactant concentration had the most impact on the rejection. Moreover, among the studied parameters, TMP and surfactant concentration played an important role in variations of the permeate flux.









Similar content being viewed by others
Explore related subjects
Discover the latest articles and news from researchers in related subjects, suggested using machine learning.References
Afifi M, Golestani HA, Sharifi S, Kiani S (2014) Wastewater treatment of raisins processing factory using micellar-enhanced ultrafiltration. Desalin Water Treat 52:57–64
Azizi Namaghi H, Mousavi SM (2016) Factorial experimental design for treatment of an industrial wastewater using micellar-enhanced ultrafiltration. Desalin Water Treat 57:5416–5424
Bade R, Lee SH (2011) A review of studies on micellar enhanced ultrafiltration for heavy metals removal from wastewater. J Water Sustain 1:85–102
Bruce GM, Pleus RC, Snyder SA (2010) Toxicological relevance of pharmaceuticals in drinking water. Environ Sci Technol 44:5619–5626
Daughton CG, Ternes TA (1999) Pharmaceuticals and personal care products in the environment: agents of subtle change? Environ Health Perspect 107:907–938
Deegan A, Shaik B, Nolan K, Urell K, Oelgemöller M, Tobin J, Morrissey A (2011) Treatment options for wastewater effluents from pharmaceutical companies. Int J Environ Sci Technol 8:649–666
El-Abbassi A, Khayet M, Hafidi A (2011) Micellar enhanced ultrafiltration process for the treatment of olive mill wastewater. Water Res 45:4522–4530
Exall K, Balakrishnan VK, Toito J, McFadyen R (2013) Impact of selected wastewater constituents on the removal of sulfonamide antibiotics via ultrafiltration and micellar enhanced ultrafiltration. Sci Total Environ 461:371–376
Gheshlaghi R (2007) Optimization of recombinant protein production by a fungal host. PhD thesis requirement for degree of doctor philosophy in chemical engineering, University of Waterloo
Hafizi A, Ahmadpour A, Koolivand-Salooki M, Heravi M, Bamoharram F (2013) Comparison of RSM and ANN for the investigation of linear alkylbenzene synthesis over H14 [NaP5W30O110]/SiO2 catalyst. J Ind Eng Chem 19:1981–1989
Häyrynen P, Landaburu-Aguirre J, Pongrácz E, Keiski RL (2012) Study of permeate flux in micellar-enhanced ultrafiltration on a semi-pilot scale: simultaneous removal of heavy metals from phosphorous rich real wastewaters. Sep Purif Technol 93:59–66
Homem V, Santos L (2011) Degradation and removal methods of antibiotics from aqueous matrices—a review. J Environ Manag 92:2304–2347
Huang J-H et al (2010) Micellar-enhanced ultrafiltration of methylene blue from dye wastewater via a polysulfone hollow fiber membrane. J Membr Sci 365:138–144
Husein MM, Deriszadeh A, Harding TG (2011) Experimental and modeling study of MEUF removal of naphthenic acids. Desalination 273:352–358
Jacquet R, Miège C, Bados P, Schiavone S, Coquery M (2012) Evaluating the polar organic chemical integrative sampler for the monitoring of beta-blockers and hormones in wastewater treatment plant effluents and receiving surface waters. Environ Toxicol Chem 31:279–288
Jafari A et al (2017) Application of micellar enhanced ultrafiltration (MEUF) for arsenic (v) removal from aqueous solutions and process optimization. J Dispers Sci Technol 38:1588–1593
Juang R-S, Lin S-H, Peng L-C (2010) Flux decline analysis in micellar-enhanced ultrafiltration of synthetic waste solutions for metal removal. Chem Eng J 161:19–26
Kazemi-Beydokhti A, Namaghi HA, Heris SZ (2013) Identification of the key variables on thermal conductivity of CuO nanofluid by a fractional factorial design approach. Numer Heat Transf Part B Fundam 64:480–495
Krajnik P, Kopac J, Sluga A (2005) Design of grinding factors based on response surface methodology. J Mater Process Technol 162:629–636
Lee J, Yang J-S, Kim H-J, Baek K, Yang J-W (2005) Simultaneous removal of organic and inorganic contaminants by micellar enhanced ultrafiltration with mixed surfactant. Desalination 184:395–407
Li NN, Fane AG, Ho WW, Matsuura T (2011) Advanced membrane technology and applications. Wiley, New York
Liu C-K, Li C-W, Lin C-Y (2004) Micellar-enhanced ultrafiltration process (MEUF) for removing copper from synthetic wastewater containing ligands. Chemosphere 57:629–634
Liu L, Wang X, Zou H, Yu M, Xie W (2017) Optimizing synthesis parameters of short carbon fiber reinforced polysulfonamide composites by using response surface methodology. Polym Test 59:355–361
Mahmoodi V, Sargolzaei J (2014) Optimization of photocatalytic degradation of naphthalene using nano-TiO2/UV system: statistical analysis by a response surface methodology. Desalin Water Treat 52:6664–6672
Masmoudi G, Trabelsi R, Ellouze E, Amar R (2014) New treatment at source approach using combination of microfiltration and nanofiltration for dyeing effluents reuse. Int J Environ Sci Technol 11:1007–1016
Midi H, Sarkar S, Rana S (2010) Collinearity diagnostics of binary logistic regression model. J Interdiscip Math 13:253–267
Misra S, Mahatele A, Tripathi S, Dakshinamoorthy A (2009) Studies on the simultaneous removal of dissolved DBP and TBP as well as uranyl ions from aqueous solutions by using micellar-enhanced ultrafiltration technique. Hydrometallurgy 96:47–51
Monteiro SC, Boxall AB (2010) Occurrence and fate of human pharmaceuticals in the environment. Rev Environ Contam Toxicol 202:53–154
Namaghi HA, Mousavi SM (2014) Micellar-enhanced ultrafiltration of soft drink wastewater using anionic and mixed anionic/nonionic surfactants. J Taiwan Inst Chem Eng 45:1850–1854
Namaghi HA, Asl AH, Chenar MP (2015) Identification and optimization of key parameters in preparation of thin film composite membrane for water desalination using multi-step statistical method. J Ind Eng Chem 31:61–73
Neta NS, Peres AM, Teixeira JA, Rodrigues LR (2011) Maximization of fructose esters synthesis by response surface methodology. New Biotechnol 28:349–355
Ngang H, Ahmad A, Low S, Ooi B (2012) Preparation of mixed-matrix membranes for micellar enhanced ultrafiltration based on response surface methodology. Desalination 293:7–20
Onsekizoglu P, Bahceci KS, Acar J (2010) The use of factorial design for modeling membrane distillation. J Membr Sci 349:225–230
Oosterhuis M, Sacher F, ter Laak TL (2013) Prediction of concentration levels of metformin and other high consumption pharmaceuticals in wastewater and regional surface water based on sales data. Sci Total Environ 442:380–388
Puasa SW, Ruzitah MS, Sharifah ASAK (2011) An overview of micellar-enhanced ultrafiltration in wastewater treatment process. In: Proceedings of international conference on environment and industrial innovation (ICEII 2011), vol 12, pp 167–172
Purkait M, DasGupta S, De S (2004) Removal of dye from wastewater using micellar-enhanced ultrafiltration and recovery of surfactant. Sep Purif Technol 37:81–92
Radjenović J, Petrović M, Ventura F, Barceló D (2008) Rejection of pharmaceuticals in nanofiltration and reverse osmosis membrane drinking water treatment. Water Res 42:3601–3610
Rahmanian B, Pakizeh M, Maskooki A (2010) Micellar-enhanced ultrafiltration of zinc in synthetic wastewater using spiral-wound membrane. J Hazard Mater 184:261–267
Saadat S, Karimi-Jashni A (2011) Optimization of Pb(II) adsorption onto modified walnut shells using factorial design and simplex methodologies. Chem Eng J 173:743–749
Sahu J, Acharya J, Meikap B (2009) Response surface modeling and optimization of chromium (VI) removal from aqueous solution using Tamarind wood activated carbon in batch process. J Hazard Mater 172:818–825
Sharifi S, Golestani HA, Afifi M, Kiani S (2014) Treatment of edible oil processing wastewater using micellar-enhanced ultrafiltration process. Desalin Water Treat 52:2412–2418
Singh KP, Gupta S, Singh AK, Sinha S (2011) Optimizing adsorption of crystal violet dye from water by magnetic nanocomposite using response surface modeling approach. J Hazard Mater 186:1462–1473
Verlicchi P, Al Aukidy M, Zambello E (2012) Occurrence of pharmaceutical compounds in urban wastewater: removal, mass load and environmental risk after a secondary treatment—a review. Sci Total Environ 429:123–155
Vu DH, Muttaqi KM, Agalgaonkar A (2015) A variance inflation factor and backward elimination based robust regression model for forecasting monthly electricity demand using climatic variables. Appl Energy 140:385–394
Yenphan P, Chanachai A, Jiraratananon R (2010) Experimental study on micellar-enhanced ultrafiltration (MEUF) of aqueous solution and wastewater containing lead ion with mixed surfactants. Desalination 253:30–37
Yurlova L, Kryvoruchko A, Kornilovich B (2002) Removal of Ni (II) ions from wastewater by micellar-enhanced ultrafiltration. Desalination 144:255–260
Zaghbani N, Hafiane A, Dhahbi M (2007) Separation of methylene blue from aqueous solution by micellar enhanced ultrafiltration. Sep Purif Technol 55:117–124
Zeng G-M, Xu K, Huang J-H, Li X, Fang Y-Y, Qu Y-H (2008) Micellar enhanced ultrafiltration of phenol in synthetic wastewater using polysulfone spiral membrane. J Membr Sci 310:149–160
Zielińska M, Bułkowska K, Cydzik-Kwiatkowska A, Bernat K, Wojnowska-Baryła I (2016) Removal of bisphenol A (BPA) from biologically treated wastewater by microfiltration and nanofiltration. Int J Environ Sci Technol 13:2239–2248
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Editorial responsibility: Sivakumar Durairaj.
Rights and permissions
About this article
Cite this article
Salehi, R., Mousavi, S.M. & Taherian, M. Assessment of micellar-enhanced ultrafiltration process performance for removal of pharmaceutical contaminant from wastewater using response surface methodology. Int. J. Environ. Sci. Technol. 16, 6199–6206 (2019). https://doi.org/10.1007/s13762-018-2021-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13762-018-2021-3


