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Eco-friendly smart hydrogels for soil conditioning and sustain release fertilizer

Abstract

In the agricultural industry, biomass waste generated along with the production of food, is transformed into value-added products. Also, the demand for the slow or control release fertilizer is increasing to reduce the cost of maintaining the agricultural land. These issues are tackled by converting biomass waste to a slow fertilizer release vehicle and biodegradable water retention material that could reduce the cost for fertilizer application and simultaneously preserved the soil from dryness. A series of carboxymethyl sago pulp (CMSP) hydrogels were prepared by electron beam irradiation. Slow release systems were evaluated by loading potassium nitrate (KNO3) and ammonium nitrate (NH4NO3) into the CMSP hydrogels. These CMSP hydrogels endow slow release property, biodegradability and a soil moisture preservation property that could find greener application in agricultural industries. The results indicate that CMSP hydrogels have a great potential as an agent for slow release of fertilizers.

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References

  • Amsden B (1998) Solute diffusion in hydrogels.: an examination of the retardation effect. Polym Gels Netw 6:13–43

    CAS  Article  Google Scholar 

  • Bajpai A, Giri A (2002) Swelling dynamics of a macromolecular hydrophilic network and evaluation of its potential for controlled release of agrochemicals. React Funct Polym 53:125–141

    CAS  Article  Google Scholar 

  • Bajpai A, Giri A (2003) Water sorption behaviour of highly swelling (carboxy methylcellulose-g-polyacrylamide) hydrogels and release of potassium nitrate as agrochemical. Carbohydr Polym 53:271–279

    CAS  Article  Google Scholar 

  • Carlos A, da Silva DB, Shepherd Andrew W, Jenane Chakib, Miranda-da-Cruz Sergio (2009) Agro-industries for development. CAB International and Food and Agriculture Organization of United Nations, Rome

    Google Scholar 

  • Chadwick D, Wei J, Yan’an T, Guanghui Y, Qirong S, Qing C (2015) Improving manure nutrient management towards sustainable agricultural intensification in China. Agric Ecosyst Environ 209:34–46

    Article  Google Scholar 

  • Costa-Júnior ES, Barbosa-Stancioli EF, Mansur AA, Vasconcelos WL, Mansur HS (2009) Preparation and characterization of chitosan/poly (vinyl alcohol) chemically crosslinked blends for biomedical applications. Carbohydr Polym 76:472–481

    Article  Google Scholar 

  • Demitri C, Scalera F, Madaghiele M, Sannino A, Maffezzoli A (2013) Potential of cellulose-based superabsorbent hydrogels as water reservoir in agriculture. Int J Polym Sci 2013. doi:10.1155/2013/435073

    Article  Google Scholar 

  • El-Mohdy HA (2007) Water sorption behavior of CMC/PAM hydrogels prepared by γ-irradiation and release of potassium nitrate as agrochemical. React Funct Polym 67:1094–1102

    Article  Google Scholar 

  • Francis S, Kumar M, Varshney L (2004) Radiation synthesis of superabsorbent poly (acrylic acid)–carrageenan hydrogels. Radiat Phys Chem 69:481–486

    CAS  Article  Google Scholar 

  • Global Fertilizers and Agricultural Chemicals (2011) Datamonitor

  • Gupta S, Kumar M, Kumar J, Ahmad V, Pandey R, Chauhan N (2017) Systemic analysis of soil microbiome deciphers anthropogenic influence on soil ecology and ecosystem functioning. Int J Environ Sci Technol pp 1–10

  • Handbook IIHSCE (2015) Controlled and Slow Release Fertilizers. Colorado, United States

  • Huang J, Richard H, Zheng S (2014) Effects of nitrogen fertilization on soil labile carbon fractions of freshwater marsh soil in Northeast China. Int J Environ Sci Technol 11:2009–2014

    CAS  Article  Google Scholar 

  • Islami N, Taib S, Yusoff I, Ghani AA (2011) Time lapse chemical fertilizer monitoring in agriculture sandy soil. Int J Environ Sci Technol 8:765–780

    CAS  Article  Google Scholar 

  • Kim D-G, Hernandez-Ramirez G, Giltrap D (2013) Linear and nonlinear dependency of direct nitrous oxide emissions on fertilizer nitrogen input: a meta-analysis. Agric Ecosyst Environ 168:53–65

    CAS  Article  Google Scholar 

  • Klinger D, Landfester K (2012) Stimuli-responsive microgels for the loading and release of functional compounds: fundamental concepts and applications. Polymer 53:5209–5231

    CAS  Article  Google Scholar 

  • Li X, He J-Z, Hughes JM, Liu Y-R, Zheng Y-M (2014) Effects of super-absorbent polymers on a soil–wheat (Triticum aestivum L.) system in the field. Appl Soil Ecol 73:58–63

    Article  Google Scholar 

  • Liu G (2013) Brief introduction of slow/controlled release fertilizer industry of China and related standards. In: Third international conference on slow and controlled release and stabilized fertilizers, Rio de Janeiro, Brazil, 2013. International Fertilizer Industry Association (IFA)

  • Mahdy A, Elkhatib E, Balba A, Ahmed G (2017) Speciation and fractionation of phosphorus in biosolids-amended soils: effects of water treatment residual nanoparticles. Int J Environ Sci Technol 14(8):1729–1738

    CAS  Article  Google Scholar 

  • Marcì G, Mele G, Palmisano L, Pulito P, Sannino A (2006) Environmentally sustainable production of cellulose-based superabsorbent hydrogels. Green Chem 8:439–444

    Article  Google Scholar 

  • Nagasawa N, Yagi T, Kume T, Yoshii F (2004) Radiation crosslinking of carboxymethyl starch. Carbohydr Polym 58:109–113

    CAS  Article  Google Scholar 

  • Nie H, Liu M, Zhan F, Guo M (2004) Factors on the preparation of carboxymethylcellulose hydrogel and its degradation behavior in soil. Carbohydr Polym 58:185–189

    CAS  Article  Google Scholar 

  • Nomura H, Koda S, Hattori F (1990) Viscosity of aqueous solutions of polysaccharides and their carboxylate derivatives. J Appl Polym Sci 41:2959–2969

    CAS  Article  Google Scholar 

  • Pincus L, Margenot A, Six J, Scow K (2016) On-farm trial assessing combined organic and mineral fertilizer amendments on vegetable yields in central Uganda. Agric Ecosyst Environ 225:62–71

    Article  Google Scholar 

  • Pourjavadi A, Sadat Afjeh S, Seidi F, Salimi H (2011) Preparation of acrylated agarose-based hydrogels and investigation of their application as fertilizing systems. J Appl Polym Sci 122:2424–2432

    CAS  Article  Google Scholar 

  • Pushpamalar V (2010) Preparation and characterisation of carboxymethyl cellulose and carboxymethyl cellulose hydrogel from sago waste. Monash University Australia, Clayton

    Google Scholar 

  • Pushpamalar V, Langford SJ, Ahmad M, Lim YY (2006) Optimization of reaction conditions for preparing carboxymethyl cellulose from sago waste. Carbohydr Polym 64:312–318

    CAS  Article  Google Scholar 

  • Pushpamalar V, Langford SJ, Ahmad M, Hashim K, Lim YY (2013a) Absorption characterization of Ca2+, Na+, and K+ on irradiation crosslinked carboxymethyl sago pulp hydrogel. J Appl Polym Sci 128:1828–1833

    CAS  Article  Google Scholar 

  • Pushpamalar V, Langford SJ, Ahmad M, Hashim K, Lim YY (2013b) Preparation of carboxymethyl sago pulp hydrogel from sago waste by electron beam irradiation and swelling behavior in water and various pH media. J Appl Polym Sci 128:451–459

    CAS  Article  Google Scholar 

  • Quirós R, Villalba G, Gabarrell X, Muñoz P (2015) Life cycle assessment of organic and mineral fertilizers in a crop sequence of cauliflower and tomato. Int J Environ Sci Technol 12:3299–3316

    Article  Google Scholar 

  • Rahman ZA (2004) Fertilizer use by crop in Malaysia. Food and Agriculture Organization of the United Nations, Rome

    Google Scholar 

  • Saraydin D, Karadağ E, Güven O (1995) Adsorptions of some heavy metal ions in aqueous solutions by acrylamide/maleic acid hydrogels. Sep Sci Technol 30:3287–3298

    CAS  Article  Google Scholar 

  • Saraydin D, Karadağ E, Güven O (1996) Behaviors of acrylamide/maleic acid hydrogels in uptake of some cationic dyes from aqueous solutions. Sep Sci Technol 31:2359–2371

    CAS  Article  Google Scholar 

  • Shaviv A, Mikkelsen R (1993) Controlled-release fertilizers to increase efficiency of nutrient use and minimize environmental degradation-a review. Fertil Res 35:1–12

    CAS  Article  Google Scholar 

  • Smith L, Siciliano G (2015) A comprehensive review of constraints to improved management of fertilizers in China and mitigation of diffuse water pollution from agriculture. Agric Ecosyst Environ 209:15–25

    Article  Google Scholar 

  • Smith EA, Prues SL, Oehme FW (1997) Environmental degradation of polyacrylamides. Ecotoxicol Environ Saf 37:76–91

    CAS  Article  Google Scholar 

  • Snyder C, Bruulsema T, Jensen T, Fixen P (2009) Review of greenhouse gas emissions from crop production systems and fertilizer management effects. Agric Ecosyst Environ 133:247–266

    CAS  Article  Google Scholar 

  • Sun G, Chu C-C (2006) Synthesis, characterization of biodegradable dextran–allyl isocyanate–ethylamine/polyethylene glycol–diacrylate hydrogels and their in vitro release of albumin. Carbohydr Polym 65:273–287

    CAS  Article  Google Scholar 

  • van der Weerden T et al (2016) Nitrous oxide emissions from urea fertiliser and effluent with and without inhibitors applied to pasture. Agric Ecosyst Environ 219:58–70

    Article  Google Scholar 

  • Wach RA, Mitomo H, Yoshii F, Kume T (2001) Hydrogel of biodegradable cellulose derivatives. II. Effect of some factors on radiation-induced crosslinking of CMC. J Appl Polym Sci 81:3030–3037

    CAS  Article  Google Scholar 

  • Wang H, Wang Z, Zhu B (2007) Preparation and properties of new non-loading and superhigh ammonium nitrate loading hydrogels. React Funct Polym 67:225–232

    CAS  Article  Google Scholar 

  • Wei W, Yan Y, Cao J, Christie P, Zhang F, Fan M (2016) Effects of combined application of organic amendments and fertilizers on crop yield and soil organic matter: an integrated analysis of long-term experiments. Agric Ecosyst Environ 225:86–92

    Article  Google Scholar 

  • Zeinali M, Lenjannezhadian H (2017) Degradation of urea by entrapped cross-linked urease aggregates: a combinatorial approach to urease stabilization for environmental and industrial applications. Int J Environ Sci Technol. doi:10.1007/s13762-017-1337-8

    Article  Google Scholar 

  • Zhao L, Mitomo H (2009) Hydrogels of dihydroxypropyl chitosan crosslinked with irradiation at paste-like condition. Carbohydr Polym 76:314–319

    CAS  Article  Google Scholar 

  • Zia KM, Bhatti IA, Barikani M, Zuber M, Bhatti HN (2009) XRD studies of polyurethane elastomers based on chitin/1, 4-butane diol blends. Carbohydr Polym 76:183–187

    CAS  Article  Google Scholar 

Download references

Acknowledgements

Financial support from the School of Chemistry at Monash University, Clayton, Australia, is gratefully acknowledged.

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Correspondence to J. Pushpamalar.

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Editorial responsibiility: Tan Yigitcanlar.

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Pushpamalar, J., Langford, S.J., Ahmad, M.B. et al. Eco-friendly smart hydrogels for soil conditioning and sustain release fertilizer. Int. J. Environ. Sci. Technol. 15, 2059–2074 (2018). https://doi.org/10.1007/s13762-017-1598-2

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  • DOI: https://doi.org/10.1007/s13762-017-1598-2

Keywords

  • Carboxymethyl sago pulp
  • Hydrogel
  • Soil preservation
  • Soil biodegradation
  • Slow release fertilizer