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Desulfurization of gasoline using acrylonitrile electrospun nanofibers and lead nanoparticles

  • A. R. Allafchian
  • M. Gholamian
  • J. Mohammadi
Original Paper

Abstract

An adsorbent-based acrylonitrile-co-butadiene-co-styrene, polyacrylonitrile and lead nanoparticles blend were prepared using electrospinning process. Its application was investigated for the removal of sulfur from gasoline. The nanofiber was characterized by scanning electron microscopy, X-ray diffraction, BET and Fourier transform infrared spectroscopy. BET analysis indicated that the specific surface areas of lead-loaded nanofibers were increased with adding the content of lead nanoparticles. The results of field emission scanning electron microscopy characterization showed that the lead nanoparticles were successfully loaded on the nanofibers uniformly. Gas chromatography-mass results also revealed that lead-loaded nanofiber was a useful adsorbent for the desulfurization of gasoline. The effects of experimental parameters on the extraction efficiency of the sorbent were investigated too. The removal efficiency and adsorbent capacity were found to be 93.31%, 31.4 mg S/g, respectively, for the removal dibenzothiophene in the 10 mL n-hexane solvent.

Graphical Abstract

Keywords

Electrospinning Adsorption Dibenzothiophene Polyacrylonitrile 

Abbreviation

C0

Sulfur concentration in the primary solution (ppm)

Ce

Sulfur concentration at the equilibrium status (ppm)

m

Adsorbent mass (g)

Qa

Adsorption capacity of DBT on PAN–ABS–Pb and PAN–ABS nanofibers (mg/g adsorbent)

R.E

Removal efficiency of DBT (%)

V

Volume of the utilized solution (L)

Notes

Acknowledgments

The authors wish to thank Isfahan University of Technology (IUT) Research Council (Grant Number 1394) and the Center of Excellency in Applied Nanotechnology for supporting this work.

References

  1. Adhami S, Atapour M, Allafchian A (2015) Corrosion protection of copper by silane sol–gel coatings. J Sol–Gel Sci Technol 74:800–809CrossRefGoogle Scholar
  2. Ahmed MJ, Ahmaruzzaman M (2015) Adsorptive desulfurization of feed diesel using chemically impregnated coconut coir waste. Int J Environ Sci Technol 12:2847–2856CrossRefGoogle Scholar
  3. Asasian N, Kaghazchi T (2015) Sulfurized activated carbons and their mercury adsorption/desorption behavior in aqueous phase. Int J Environ Sci Technol 12:2511–2522CrossRefGoogle Scholar
  4. Babapoor A, Karimi G, Khorram M (2016) Fabrication and characterization of nanofiber-nanoparticle-composites with phase change materials by electrospinning. Appl Therm Eng 99:1225–1235CrossRefGoogle Scholar
  5. Babich I, Moulijn J (2003) Science and technology of novel processes for deep desulfurization of oil refinery streams: a review. Fuel 82:607–631CrossRefGoogle Scholar
  6. Bakhtiari G, Abdouss M, Bazmi M, Royaee S (2016) Optimization of sulfur adsorption over Ag-zeolite nanoadsorbent by experimental design method. Int J Environ Sci Technol 13:803–812CrossRefGoogle Scholar
  7. Behrouzifar A, Rowshanzamir S, Alipoor Z, Bazmi M (2016) Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel. Int J Environ Sci Technol 13:2883–2892CrossRefGoogle Scholar
  8. Corma A, Chane-Ching J, Airiau M, Martínez C (2004) Synthesis and catalytic properties of thermally and hydrothermally stable, high-surface-area SiO2–CeO2 mesostructured composite materials and their application for the removal of sulfur compounds from gasoline. J Catal 224:441–448CrossRefGoogle Scholar
  9. Dabirian F, Ravandi SH, Pishevar A, Abuzade R (2011) A comparative study of jet formation and nanofiber alignment in electrospinning and electrocentrifugal spinning systems. J Electrost 69:540–546CrossRefGoogle Scholar
  10. Dadvar S, Tavanai H, Morshed M, Ghiaci M (2012) The removal of 2-chloroethyl ethyl sulfide using activated carbon nanofibers embedded with MgO and Al2O3 nanoparticles. J Cheml Eng Data 57:1456–1462CrossRefGoogle Scholar
  11. Davoodi-Dehaghani F, Vosoughi M, Ziaee AA (2010) Biodesulfurization of dibenzothiophene by a newly isolated Rhodococcus erythropolis strain. Bioresour Technol 101:1102–1105CrossRefGoogle Scholar
  12. Demirbas A (2000) Sulfur removal from lignite using alkaline solution from tea waste ash by water extraction. Energy Sources 22:763–770CrossRefGoogle Scholar
  13. Fan Y, Wei Z, Hui-min H, Zhen-yu L, Hong-nan Z, Wei W, Ce W (2010) Decoration of electrospun nanofibers with magnetic nanoparticles via electrospinning and sol-gel process. Chem Res Chin Univ 26:847–850Google Scholar
  14. Homaeigohar SS, Buhr K, Ebert K (2010) Polyethersulfone electrospun nanofibrous composite membrane for liquid filtration. J Membr Sci 365:68–77CrossRefGoogle Scholar
  15. Huang Z-M, Zhang Y-Z, Kotaki M, Ramakrishna S (2003) A review on polymer nanofibers by electrospinning and their applications in nanocomposites. Compos Sci Technol 63:2223–2253CrossRefGoogle Scholar
  16. Huang C, Chen B, Zhang J, Liu Z, Li Y (2004) Desulfurization of gasoline by extraction with new ionic liquids. Energy Fuels 18:1862–1864CrossRefGoogle Scholar
  17. Im JS, Kim MI, Lee Y-S (2008) Preparation of PAN-based electrospun nanofiber webs containing TiO2 for photocatalytic degradation. Mater Lett 62:3652–3655CrossRefGoogle Scholar
  18. Jian-long W, D-s ZHAO, E-p ZHOU, Zhi D (2007) Desulfurization of gasoline by extraction with N-alkyl-pyridinium-based ionic liquids. J Fuel Chem Technol 35:293–296CrossRefGoogle Scholar
  19. Kanafchian M, Valizadeh M, Haghi AK (2011) Electrospun nanofibers with application in nanocomposites. Korean J Chem Eng 28:428–439CrossRefGoogle Scholar
  20. Ko CH, Park JG, Park JC, Song H, Han S-S, Kim J-N (2007) Surface status and size influences of nickel nanoparticles on sulfur compound adsorption. Appl Surface Sci 253:5864–5867CrossRefGoogle Scholar
  21. Leong MF, Chian KS, Mhaisalkar PS, Ong WF, Ratner BD (2009) Effect of electrospun poly (d, l-lactide) fibrous scaffold with nanoporous surface on attachment of porcine esophageal epithelial cells and protein adsorption. J Biomed Mater Res Part A 89:1040–1048CrossRefGoogle Scholar
  22. Ma X, Velu S, Kim JH, Song C (2005) Deep desulfurization of gasoline by selective adsorption over solid adsorbents and impact of analytical methods on ppm-level sulfur quantification for fuel cell applications. Appl Catal B: Environ 56:137–147CrossRefGoogle Scholar
  23. Montazerolghaem M, Seyedeyn-Azad F, Rahimi A (2014) The performance of pelletized Ce-Y and Ni-Y zeolites for removal of thiophene from model gasoline solutions. Korean J Chem Eng 32:328–334CrossRefGoogle Scholar
  24. Moosavi ES, Dastgheib SA, Karimzadeh R (2012) Adsorption of thiophenic compounds from model diesel fuel using copper and nickel impregnated activated carbons. Energies 5:4233–4250CrossRefGoogle Scholar
  25. Neher B, Gafur MA, Al-Mansur MA, Bhuiyan MMR, Qadir MR, Ahmed F (2014) Investigation of the surface morphology and structural characterization of palm fiber reinforced acrylonitrile butadiene styrene (PF-ABS) composites. Mater Sci Appl 5:378–386Google Scholar
  26. Park JG, Ko CH, Yi KB, Park J-H, Han S-S, Cho S-H, Kim J-N (2008) Reactive adsorption of sulfur compounds in diesel on nickel supported on mesoporous silica. Appl Catal B: Environ 81:244–250CrossRefGoogle Scholar
  27. Reneker DH, Chun I (1996) Nanometre diameter fibres of polymer, produced by electrospinning. Nanotechnology 7:216CrossRefGoogle Scholar
  28. Samadi-Maybodi A, Teymouri M, Vahid A, Miranbeigi A (2011) In situ incorporation of nickel nanoparticles into the mesopores of MCM-41 by manipulation of solvent–solute interaction and its activity toward adsorptive desulfurization of gas oil. J Hazard Mater 192:1667–1674CrossRefGoogle Scholar
  29. Selvavathi V, Chidambaram V, Meenakshisundaram A, Sairam B, Sivasankar B (2009) Adsorptive desulfurization of diesel on activated carbon and nickel supported systems. Catal Today 141:99–102CrossRefGoogle Scholar
  30. Shin C, Chase G, Reneker D (2005) Recycled expanded polystyrene nanofibers applied in filter media. Coll Surf A: Phys Eng Aspects 262:211–215CrossRefGoogle Scholar
  31. Sithornkul S, Threepopnatkul P (2010) Control of mechanical properties and permeability of electrospun natural rubber with different composite systems. Adv Mater Res 93:619–622CrossRefGoogle Scholar
  32. Soleimani M, Bassi A, Margaritis A (2007) Biodesulfurization of refractory organic sulfur compounds in fossil fuels. Biotechnol Adv 25:570–596CrossRefGoogle Scholar
  33. Velu S, Ma X, Song C (2003) Selective adsorption for removing sulfur from jet fuel over zeolite-based adsorbents. Ind Eng Chem Res 42:5293–5304CrossRefGoogle Scholar
  34. Xiong J, Zhu W, Li H, Ding W, Chao Y, Wu P, Xun S, Zhang M, Li H (2015) Few-layered graphene-like boron nitride induced a remarkable adsorption capacity for dibenzothiophene in fuels. Green Chem 17:1647–1656CrossRefGoogle Scholar
  35. Yu F, Wang R (2013) Deep oxidative desulfurization of dibenzothiophene in simulated oil and real diesel using heteropolyanion-substituted hydrotalcite-like compounds as catalysts. Molecules 18:13691–13704CrossRefGoogle Scholar
  36. Yu D-G, Zhou J, Chatterton NP, Li Y, Huang J, Wang X (2012) Polyacrylonitrile nanofibers coated with silver nanoparticles using a modified coaxial electrospinning process. Int J Nanomed 7:5725CrossRefGoogle Scholar
  37. Zhao D-S, SUN Z-M, Li F-T, Shan H-D (2009) Optimization of oxidative desulfurization of dibenzothiophene using acidic ionic liquid as catalytic solvent. J Fuel Chem Technol 37:194–198CrossRefGoogle Scholar
  38. Zhou A, Ma X, Song C (2006) Liquid-phase adsorption of multi-ring thiophenic sulfur compounds on carbon materials with different surface properties. J Phys Chem B 110:4699–4707CrossRefGoogle Scholar

Copyright information

© Islamic Azad University (IAU) 2017

Authors and Affiliations

  1. 1.Research Institute for Nanotechnology and Advanced MaterialsIsfahan University of TechnologyIsfahanIran

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