Abstract
Dyes from several industry effluents are major concern of environmental pollution. In this study, the efficiency of a cost-effective natural adsorbent Strychnos potatorum Linn (Fam: Loganiaceae) seeds on removing reactive orange-M2R dye from aqueous solution was investigated using batch adsorption isotherms at 30 ± 1 °C and 120 rpm. The efficacy of the adsorbent system was also studied at various parameters viz. contact time, pH, adsorbent dosage and initial dye concentration. Maximum adsorption (q e = 9 mg/g) was observed at pH 2.0, equilibrium time 6 h, initial dye concentration of 100 mg/L and adsorbent dosage of 0.2 g/100 mL. The unit adsorption of dye, q e (mg/g) increased with increase in contact time and initial dye concentration, while it decreased with increase in adsorbent dosage. The adsorption kinetic studies revealed that it follows pseudo-second-order reaction model. Equilibrium adsorption data followed both Langmuir and Freundlich isotherms with good agreement. These investigations suggest that Strychnos potatorum Linn seeds (SPS) could be used as a low-cost adsorbent in treating textile effluents for dye removal applications. The adsorbent (SPS) was also characterized using Fourier transform infrared spectroscopy, powder X-ray diffraction, and scanning electron microscopic technique.





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Annadurai G, Chellapandian M, Krishnan MRV (1999) Adsorption of reactive dye on chitin. Environ Monit Assess 59:111–119
Bello OS, Adelaide OM, Hammed MA, Popoola OAM (2010) Kinetic and Equilibrium studies of methylene blue removal from aqueous solution by adsorption on treated sawdust. Maced J Chem Chem Eng 29:77–85
El-Geundi MS (1991) Colour removal from textile effluents by adsorption techniques. Water Res 25:271–273
Fytianos K, Voudrias E, Kokkalis E (2000) Sorption-desorption behavior of 2, 4-dichlorophenol by marine sediments. Chemosphere 40:3–6
Garg VK, Amita M, Kumar R, Gupta R (2004a) Basic dye (methylene blue) removal from simulated wastewater by adsorption using Indian Rosewood sawdust: a timber industry waste. Dyes Pigments 63:243–250
Garg VK, Kumar R, Gupta R (2004b) Removal of malachite green dye from aqueous solution by adsorption using agro-industry waste: a case study of Prosopis cineraria. Dyes Pigments 62:1–10
Giles C, Huitson A, Smith D (1974) A general treatment and classification of the solute adsorption isotherms. J Colloid Interface Sci 47:755–765
Gregory AR, Elliot S, Kluge P (1991) Ames testing of direct black 3B parallel carcinogenecity. J Appl Toxicol 1:308–313
Hall KR, Eagleton LC, Acrivos A, Vermeulen T (1966) Pore and solid diffusion kinetics in fixed bed adsorption under constant pattern conditions. Ind Eng Chem Fund 5:212–228
Inbaraj BS, Selvarani K, Sulochana N (2002) Evaluation of carbonaceous sorbent prepared from pearl millet husk for its removal of basic dye. J Sci Ind Res 61:971–978
Jagwani JS, Sharma MC, Lakshmi B (2013) COD reduction and biodegradation of textile dye reactive orange M2R by newly isolated bacterial consortium VSS. Int J Environ Ecol Fam Urban Stud 3(2):69–78. ISSN 2250-0065
Ju DJ, Byun IG, Lee CH, An GH, Park TJ (2006) Biosorption characteristics of reactive dye onto dried activated sludge. Water Pract Technol 1(3). doi:10.2166/WPT.2006.066
Khan A, Tabrez Singh V, Kumar D (2004) Removal of some basic dyes from artificial textile wastewater by adsorption on Akash Kinari Coal. J Sci Ind Res 63:355–364
Kirtikar KR, Basu BD (1933) Indian medicinal plants, vol 3. Basu LM Publications, Allahabad, p 1647
Kirtikar KR, Basu BD (2000) Illustrated Indian Medicinal Plants, vol 7. Sir Satguru’s Publications, New Delhi, India, p 2271
Lata H, Garg VK, Gupta RK (2007) Removal of a basic dye from aqueous solution by adsorption using Parthenium hysterophorus: an agricultural waste. Dyes Pigments 74:653–658
Lata H, Garg VK, Gupta RK (2008) Adsorptive removal of basic dye by chemically activated Parthenium biomass: equilibrium and kinetic modeling. Desalination 219:250–261
Lee CK, Low KS, Gan PY (1999) Removal of some organic dyes by acid treated spent bleaching earth. Environ Technol 20:99–104
Malik PK (2003) Use of activated carbons prepared from sawdust and rice-husk for adsorption of acid dyes: a case study of Acid Yellow 36. Dyes Pigments 56:239–249
Namasivayam C, Prabha D, Kumutha M (1998) Removal of direct red and acid brilliant blue by adsorption onto banana pith. Bioresour Technol 64:77–79
Namasivayam C, Kumar MD, Selvi K, Ashruffunissa BR, Vanathi T, Yamuna RT (2001) ‘Waste’ coir pith—a potential biomass for the treatment of dyeing waste water. Biomass Bioenergy 21:477–483
Newcombe G, Drikas M (1997) Adsorption of NOM activated carbon: electro-static and non-electrostatic effects. Carbon 35:1239–1250
Ong ST, Lee CK, Zainal Z (2007) Removal of basic and reactive dyes using ethylenediamine modified rice hull. Bioresour Technol 98:2792–2799
Ozacar M, Sengil IA (2003) Adsorption of reactive dyes on calcined alunite from aqueous solution. J Hazard Mater B 98:211–224
Ozcan A, Ozcan AS (2005) Adsorption of Acid Red 57 from aqueous solutions onto surfactant-modified sepiolite. J Hazard Mater 125:252–259
Pavan FA, Mazzocato AC, Gushikem Y (2008) Removal of methylene blue dye from aqueous solutions by adsorption using yellow passion fruit peel as adsorbent. Bioresour Technol 99:3162–3165
Pollard SJT, Fowler GD, Sollars CJ, Perry R (1992) Low cost adsorbents for water and waste water treatment: a review. Sci Total Environ 116:31–52
Poots VJP, McKay G, Healy JJ (1978) Pseudo-Second Order Model for Sorption Processes. J Water Pollut Control Fed 50:926–935
Ramakrishna KR, Viraraghavan T (1997) Dye removal using low cost adsorbents. Water Sci Technol 36:189–196
Sid Kalal H, Hoveidi H, Thagiof M, Pakizevand N, Almasian MR, Firoozzare MA (2012) Pre-concentration and determination of platinum (IV) in water samples using chelating resin by inductively coupled plasma atomic emission spectroscopy (ICP-AES). Int J Environ Res 6(3):739–750
Singh BK, Rawat NS (1994) Comparative sorption kinetic studies of toxic phenols on fly ash and impregnated fly ash. J Chem Technol Biotechonol 61:57–65
Sivaraj R, Namasivayam C, Kadirvelu K (2000) Orange peel as an adsorbent in the removal of acid violet 17 (acid dye) from aqueous solutions. Waste Manag 21:105–110
Stephen JA, McKay G, Khader KYH (1989) Equilibrium adsorption isotherms for basic dyes onto lignite. J Chem Technol Biot 45:29–32
Weber TW, Chakravorti RK (1974) Pore and solid diffusion models for fixed-bed adsorbers. AIChE J 20:228–238
Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. J Sanit Eng Div Am Soc Civ Eng 89:31–60
Yuh-Shan Ho (2004) Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics 59:171–177
Acknowledgments
The authors would like to express their gratitude to the Department of Biotechnology, Bannari Amman Institute of Technology, Sathyamangalam, India for providing infrastructural support to carry out this research work and to Karunya University, Coimbatore, India for lending support in SEM and XRD analysis.
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Kirupa Sankar, M., Muthu Kumar, K. & Ranganathan, B.V. Adsorption of anionic azo dye from aqueous solution using Strychnos potatorum Linn seeds: isotherm and kinetic studies. Int. J. Environ. Sci. Technol. 12, 2957–2964 (2015). https://doi.org/10.1007/s13762-014-0668-y
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DOI: https://doi.org/10.1007/s13762-014-0668-y


